PAPER-2

21. (B) A(s )

P( g ) 2Q( g ) Kp x (2 x 2 y ) pP
1

p 2Q (Total)

B(s )
Kp
1 KP x 2y

2Q( g ) R( g ) (2 x 2 y ) y
x y 9 10 3 4.5 10 3

Kp

pR

p 2Q(Total)

Kp

x( 2 x 2 y ) 2
9 10
3

9 10
3

2 y (6 y ) 2

72 y 3

9 10

(2 y )3 (10 1 )3 2 y 0.1 y 0.05 atm x 0.1atm Total pressure of gases = PP PQ PR x 2( x y) y 0.1 0.3 0.05 0.45 atm

22. 23.

(A) (A)
t
2.303 Initial no. of moles x log t no. of moles of x left

age of rock

Let initial no. of moles of x = 8 No. of moles of x left = 1 at time t

0.693 6.93 109

2.303 log 8 t

1 1010
t

2.303 0.3 3 t

2.0727 1010 year

24. (B) 25. (D)

CH = O HO H CH2NH2 NOBr HO CH = O H CH2 N + O N HO CH = O H CH2 Br NaOH/H2O + .. NaO CH = O H CH2OH

H
CH = O Br2 + H2O HO H CH2OH

O+ 3

C OH

HO

=
H CH2OH

26.

Br2 + H2O oxidises glyceraldehyde into glyceric acid and reaction takes place with retention of configuration. (B) Given method is Van Arkel Process and used for obtaining ultrapure metals. The

impure metal is converted into volatile compounds which is then decomposed electrically to get pure metal. Ti, Zr, Hf, Si etc. IIT ians PACE Education Pvt. Ltd. : Andheri / Dadar / Chembur / Thane / Churchgate / Nerul / Powai

27. (D) 28. (A)

Arrhenius equation, log10 K AgCl Ag+ + e AgCl + e Ag+ + Cl Ag Ag + Cl

log A
o G1

Ea 2.303RT RT ln 2 10

10

Go 2 o G3

F(0.799) FE

o o G3 G1 Go 2 FE = RT ln (2 1010) 0.799 F

E = 0.0591 log (2 1010) + 0.799 = 0.225 AgCl + e E = 0.225 Ag + Cl

K sp 0.0591 = 0.68 log [Cl ] = 0.225 0.0591 log [ Ag ] 1

29.

(A, B, C, D)

30. (A, B, C)

31. (A, C)

(a) A small amount of Na2SnO3 is formed and sol adsorb the SnO32- ions. [SnO2] SnO32- | 2Na+ (b) Addition of KI to slight excess of AgNO3 gives a positively charged sol, due to adsorption of Ag+. [AgI] Ag+ | NO 3 (c) In the preparation of gold sol, the sol particles preferentially adsorb OH ions and gets a negative charge. (d) Fe(OH)3 sol particles preferentially adsorb Fe3+ ions and gets positive charge [Fe(OH)3] Fe3+| 3Cl

32. 33. 34. 35. 3 3 3

(A, B, C)

Be Ac Ac Be Ac Be O Ac Ac Be
Ac acetate

Ac

36. 39. 40.

3 A A P, R, T P,Q,S,T

37.

4 B B Q, S P,R

38. C C

6 Q, R P,Q,T D D Q, S P,T

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