UBND TNH KON TUM K THI CHN I TUYN D THI CHN S GIO DC V O T LP 12 THPT NM HC 2010-2011 Mn: Ho hc Thi gian:

180 pht (khng k thi gian giao ) Ngy thi: 29/10/2010 ( ny gm 8 cu, 3 trang) Cu 1 (3 im) 1. Vit tt c cc ng phn cis-trans ca cc cht c cng thc phn t l C3H4BrCl v =CH-CH=CH-R. 2. Thm dung dch NH3 ti d vo dung dch cha 0,5 mol AgNO3 ta c dung dch M. Cho t X vo dung dch M ti phn ng hon ton, c dung dch N v cht rn 43,2 gam cht rn Q. T dung dch N, thu c 23,5 gam kt ta mu vng v V lt kh Y (ktc). Tm cng thc X v t 3. T metan v cc ho cht v c, xc tc, iu kin cn thit, vit cc phng trnh h Cu 2: (3 im) 1. Hn hp X gm hai cht hu c A, B ch cha chc ancol v anhit. Trong A v B : s cbon c th no hoc c mt lin kt i. Nu ly cng s mol A hoc B phn ng ht vi Na th th cho phn ng ht vi hiro th cn 2V lt. Cho 33,8 gam X phn ng ht vi Na thu c 5 ,8 gam X phn ng ht vi AgNO3 trong NH3, ly Ag sinh ra cho phn ng ht vi HNO3 c th c. a. Tm cng thc phn t, cng thc cu to ca A, B. b. Cn ly A hay B khi phn ng vi dung dch thuc tm thu c ancol a chc? Nu l ,8 gam X th cn bao nhiu ml thuc tm 0,1 M phn ng va vi X to ra ancol a chc. 2. Sp xp cc cht sau theo chiu tng tnh axit: phenol, o-nitrophenol, m-nitrophenol, p-nitrophenol. Gii thch. 3. Mt hp cht hu c A (C,H,O) ch cha mt loi cha nhm chc trong phn t, c phn ,4 gam A tc dng vi 100 ml dung dch NaOH 2M va , thu c hn hp gm mt mui v mt a rong gc hirocarbon bng nhau. a. Lp lun xc nh cng thc cu to ca A. Bit A c mch cacbon khng phn nhnh. b. Vit cc phng trnh phn ng tng hp A t CH4 ( cc cht v c v iu kin cn th Cu 3: (2 im) 1. Dung dch A gm 0,4 mol HCl v 0,05 mol Cu(NO3)2. Cho m gam bt Fe vo dung dch khu u cho n khi phn ng kt thc thu c cht rn X gm hai kim loi, c khi lng 0,8m g NO3 ch c NO duy nht. 2. Cho cc dung dch ring bit mt nhn: Na2SO4, AlCl3, FeSO4, NaHSO4, FeCl3. Ch dng nhn bit cc dung dch trn ngay ln th u tin. Cu 4: (2 im) 1. A l mt phi kim thuc chu k 2 hoc 3. n cht A phn ng vi hidro c xc tc c vi oxi xc tc c kh C; trong khng kh C chuyn thnh D. Cho D vo dung dch KOH thu c kh nng lm mt mu dung dch KMnO4 trong dung dch H2SO-4. H l thnh phn ca thuc n cht trn v vit phn ng xy ra. 2. Ly sn phm ca tng tc hon tom gia 1,17 gam kali v 0,8 gam lu hunh cho vo h duy nht. Pha long dung dch trong sut thu c n th tch 50 ml(dung dch A). Tnh g A v khi lng brom ti a c th phn ng vi A. Cu 5: (2 im) 1. Ho tan sn phm rn ca qu trnh nu chy hn hp bt mt khong cht mu en, kali t, thu c dung dch A c mu lc m. Khi trong khng kh, dung dch A chuyn dn thnh ra nhanh hn nu sc kh clo vo dung dch A hay khi in phn dung dch A. Hy nu tn khon rnh phn ng xy ra trong cc th nghim trn. 2. Cho 10 ml dung dch HA tc dng vi cc th tch khc nhau ca dung dch NaOH a mol/l : - Phn ng xy ra va khi dng 10 ml dung dch NaOH. - Khi dng 5 ml dung dch NaOH thu c dung dch c pH = 4,76 a. Tnh Ka ca axit ni trn. b. Thm 15 ml dung dch NaOH vo 10 ml HA th c dung dch c pH = 12. Tnh a. Cu 6: (3 im) 1. Nung hn hp A gm st v lu hunh sau mt thi gian c hn hp rn B. Cho B tc d hu c V1 lt hn hp kh C. T khi ca C so vi hidro bng 10,6. Nu t chy hon ton B h oxi.

a. Tm tng quan gi tr V1 v V2 (o cng iu kin). b. Tnh hm lng phn trm cc cht trong B theo V1 v V2. c. Hiu sut thp nht ca phn ng nung trn l bao nhiu? d. Nu hiu sut ca phn ng nung trn l 75%, tnh hm lng phn trm cc cht tron 2. Ho tan hon ton hn hp MgCl2, FeCl3, CuCl2 vo nc, c dung dch A. Cho t t d n d th thu c lng kt ta nh hn 2,51 ln lng kt ta to ra khi cho dung dch Na FeCl3 trong A bng FeCl2 vi khi lng nh nhau( c dung dch B) th lng kt ta thu 3,36 ln lng kt ta to ra khi cho dung dch Na2S vo B. Vit cc phn ng v xc nh th trong hn hp ban u. Cu 7: (3 im) 1. Hn hp bt A gm 3 kim loi Mg, Zn, Al. Khi ho tan ht 7,5g A vo 1 lt dung dch H c 1 lt dung dch B v hn hp kh D gm NO v N2O. Thu kh D vo bnh dung tch 3,20 lt atm th nhit trong bnh tng thm 3,72 gam. Nu cho 7,5g A vo 1 lt dung dch KOH 2M th thc phn ng khi lng dung dch tng thm 5,7g. Tnh % khi lng mi kim loi trong A. 2. C 3 nguyn t A, B v C. A tc dng vi B nhit cao sinh ra D. Cht D b thu p a kh chy c v c mi trng thi. B v C tc dng vi nhau cho kh E, kh ny tan c tr ca A vi C c trong t nhin v thuc loi cht cng nht. Hp cht ca 3 nguyn t A, B, C rong nc v b thu phn. a. Xc nh tn gi ca A, B, C v vit cc phng trnh phn ng nu trn. b. kho st s ph thuc thnh phn hi ca B theo nhit , ngi ta tin hnh th n Ly 3,2 gam n cht B cho vo mt bnh kn khng c khng kh, dung tch 1 lt. un nng bn it v p sut bnh c ghi li trong bng sau: Nhit (0C) p sut (atm) 444,6 0,73544 450 0,88929 500 1,26772 900 4,80930 1500 14,53860 Xc nh thnh phn nh tnh hi n cht B ti cc nhit trn v gii thch. Cho: R=0,082 L.atm.K-1.mol-1. Cu 8: (2 im). 1. Mt hirocarbon X c cha 88,235% cacbon v khi lng. Xc nh cng thc phn t v X l hirocarbon no c ba v ng, mi v ng u c 6 nguyn t cacbon. 2. Ngi ta phn lp c mt tetrapeptit (peptit A) t prothrombin ngi. Cu to ca p nh sau: -Bng phng php Edman th nhn c trnh t aminoaxit ca peptit A l Leu-Glu-Glu-Val. - tip tc xc nh cu to, ngi ta tin hnh in di trn giy pH 6,5 peptit A v mt noaxit l Leu-Glu-Glu-Val) th li nhn c qung ng di chuyn khng ging nhau, c th n

- Khi thu phn hai peptit A v B bng HCl 6N 1100C, th c A v B u cho Leu(1), Glu(2), nhng khi thu phn bng kim th peptit B cho Leu(1), Glu(2), Val(1) c n peptit A cho Leu(1 , X(2), Val(1). Hy gii thch cc kt qu thc nghim xc nh cu to ca X v gi tn X theo danh php -----HT-----Th sinh c s dng bng tun hon v my tnh b ti. -Gim th khng gii thch g thm.

NM HC 2010-2011 Mn: Ho hc Thi gian: 180 pht (khng k thi gian giao ) Ngy thi: 29/10/2010 fs