Received:
16thInternational
Symposium
on
~olycyclic
romatic
ompounds
November
4 7
p
1997Charlotte North
Carolina
US
Jan
15
2009
:45Dm
Presentation
Session:
Nov
7
0950-1010
Mackerer
Mutagenicityand
P content
ofsealcoatings
for
asphaltpavement
MUTAGENICITY
AND
PAC
CONTENT
OF
SEAL
COATINGS
FOR
ASPHALT
PAVEl\.1ENT.C.R.
MACKERER
1•
T.
A
ROyl
and
G.
R.
BLACKBURN
2
lproduct
StewardshipandToxicology,MobilBu.ciness
Resources
Corporation,Paulsboro,
08066
and
2PetroLabs,
Inc-
7
IvYland,
PA
18974
We
have
evaluatedthe
mutagenicityand
polycyclic
aromaticcompound
PAC)
comem:
of
12
water
emulsionproductsavailable
to
cOl1SUIIlersfOT
the
sealing
of
asphalt
pavemtom.
Smallpails
of
product
5-6gallonseach)were
pun:hased
at
local
department
storcs_
According
to
the
labelson
the
pailsthere
were
11
coal
tM
emulsions
samples
1-
10
and
12)andoneasphaltemulsion
sample11).
Theemulsions
were
broken
by
cc:posing
the
pails
to
multiplefreeze-thaw
y l s~
and
the
ceDlIill
portion
of
the
solidsfraction
was
sampled
and
blotteddry.
ppro~m tpjy
20
g
of
each
product
was
for
PAC
analysisandtesting
in
themodifiedAmesmutagenicity
assay
ASTM
E1687J9S
For
samples1-
l2,
the
level
of
solids i.e.DCMinsoluble
mnerial)
rangedfrom
56
to
91
mean,
72.5 ).
The
DCM
solublematerial
was
tested
in
ASTM
E1681J95
where
samples1-10
and
12
produced
very
high
mutagenicity
index
Ml)
values
rangingfrom
75
to
657
mean,445);sample
11
produced
an
MI
of.only0.6.
The
DCM
solublefractions
of
sampiE3
1-10
and
12
contained
s m l r
amounts
of
3-7
ring
P
ranging
from
43
to
57
mean,
50.9 );
sample
11
contained
an
estimated
3-7
ring
PAC
level
of
2.6 _
GeMS
n lys ~
indicated
that
samples
1-
10
and12containedcoal
tar
obtained
from
the
samesource,butalso,thatsample
11
containeda
low
level
of
the
same
~o l
tar.
In.
addition.,sample
II
did
not
comain
pentane
insoluble
componentssuchas
asphaltenes
that
wouldindicatethepresence
of
asphalt.
The
very
high
MI
values
seen
fo[
samples1-10
and
J
2
suggest
that
individuals
who
may
have
prolongedandrepeated
dennal
contact
with
productssuch
as
these
may
alsohave
an
elevated
risk
for
skincancer.
E
a.
l l
CompDsition
Labellnformation
Sample
ProductName·
omponent
CASNo
Toxicology
First
AidNo.
t
Blacktop
Driveway
Relined
coal
tu
65996·9 ·9
ay
caUBe
skin
irritation.
Coating
Clay
1312·58-7
Silica
14808-60-1
Water7732-18-5
I1
Polymer
Fortified
Asphalt
8052-42-4
DrivewaySealerlFiHer
Clay
1332-58-7
No
skin
irritants.
-
Silica
J4808-60
7
Ecologically
safe.
Ethylene-vinyl
25067·10-0·
Acetate
opo~ym r
Water
7732-18-5
2
Dri\leway
Sealer
Premium-
Contains
no
solventsMay
causeirritation.
In
caseof
skin
contact
Rubberized
Co
a]
ter
based
tinse
with
water.
4
Driveway
Contairts
no
solvents
May
cause
irritation.
In
case
of
skin
contact
Sealer/Resurfacer.
Coal
tar
based
rinsethoroughly
with
PolymerFortified
Sealer
water.
Rubberized
-
Te.l lurized
3
RubberizedBlacktop
Contains
coallar
pit.ch
May
cause
skin
irritation.
In
case
of
contact
with
Sealer
Coal
tar
8007-45-2
Harmful
if
swaJlowed.eyes
orskrn
flush
withK.aolin
clay
1332
58-7
water.
Amorphous
silica
7631
86-9
7
DrivewaySealer Blacktop
Contains
coal
tarpitch
Eye
and
skinirritant.
[n
case
of
contact
with
Tar
Emulsion
Coal
t r
8007-45-2
Harmfullfswallowed.
eyesorskin.
flush
whhKaolin
clay
1332-58-7
water.
5
Drive\vay
Sealer
Filler.
Latex
finely
graded
...
flusI1
with
water
[i.e.
Rubberized.
Latex
aggratales
and
mineral
eyes
and
mouth]
.
formula.coal
tar
Refined
coal
tar
65996-90-9
_
Cla.y
1332-58-7
Silica
14808-60-7
i\
I
er
7732-J8-5
Page
1
prd.doc
o
n
o
o
N
Lon
c
('tI
.
Composition
Label
Infonnation
Samplf~
Product
Name
Component
CAS
No.
Toxicology
First
Aid
No
B
Coal
Tar-
Sealer
Filler.
Coal
tar
...
flush
with
water
Le.
Driveway
Sealer
with
Sand
eyes
and
mouth]
...
Sand
Added
12
Coal
TarDriveway
SealerRefined
coal
tar
55996·90
9
If
substance
gets
in
eyes
Clay
1332-58-7
or
mauth
flush
with
Smca14808
60-7
water
...
Water
7732
18-5
6
RubberizedDriveway
Coal
tar
M~y
cat:ne
s kin
irritation
f
swallowed.
do
notSealer
lnduce
vomiting.
10
Rubberized
Driveway
Coal
tar
May
cause
skin
irritatIon.
f
swallowed,
do
not
Sealer
inducevomitjng.
9
Driveway
Sealer
LatexCoal
tar
pilch
8007-45-1
Harmful
or
fatal
if
,..if
swallowed
induceRubber
Formula
Pilch
Refine ~
coal
tar
swallowed.
~e
skin
vomiting.Incaseofeye
Base)
Clay
1332-58
7
respiratoryirritant.contact
~
flush
with
Water
_
-
1732: Y 8~
-p1enty1Jfwann-wat
er.
Sand
14808-60-1
Irregu~
or
stopped
brealhing
-
administer
oxygen
start
resuscitation.
Sources
of
products:Hecltinger
l
Ox.ford
Valley
PA;
SearsRoebuck,
TrenLon
J
NJ~
Channel
Lumber.
Lawren:Jeville
J
NJ;
and
Gros ;man,
Lawrenceville)
NJ.
Page
2
prd.doG
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