Beruflich Dokumente
Kultur Dokumente
P r i n t e d i n G r e a t B r i t a i n .
1 9 8 6 I U P A C
I n d u s t r i a l a p p l i c a t i o n s o f p h a s e t r a n s f e r c a t a l y s i s
( P T C ) : p a s t , p r e s e n t a n d f u t u r e
H .
. - . - -
' 7 0
8 5 8 H . H . F R E E D M A N
T h e
Q C l
' N a C 1
Q X
. J
( 1 )
Q C l
Q X
q u a t e r n a r y
0 . 2 1
I n d u s t r i a l a p p l i c a t i o n s o f p h a s e t r a n s f e r c a t a l y s i s 8 5 9
T A B L E 3 . U s e o f P E G ' s a s P T C a t a l y s t s
a q u e o u s e x t r a c t i o n o f t h e o r g a n i c l a y e r a n d r e e x t r a c t i o n o f t h e Q +
s o l v e n t .
+ +
B u 3 N ( C H 2 ) 1 0 N B u 3
C H R '
R , R ' = v a r i o u s a l k y l ' s
[ R R ' N _ Z
R , R ' = a l k y l s
Z e 1 k y 1 e t i e , P E G
R e f e r e n c e
# o f
n i t r i t e
W i l l i a m s o n e t h e r D i B u P E G 6 0 0 5 9 0 2 1
s y n t h .
A l d o l r x n P E G 6 0 0
5 0 2 2
N p r o t e c t i o n
P E G 6 0 0 4
2 3
O C H
O - C H
3
x
1
2
2
8 6 0 H . H . F R E E D M A N
M E T H O D O L O G Y
T e c h n i q u e s
T h e
g a s l i q u i d
c a t a l y s t s
W h e n
A P P L I C A T I O N S
P o l y m e r s
T h e p o l y m e r c h e m i s t s h a v e e n t h u s i a s t i c a l l y a d o p t e d P T C a n d c o n t i n u e t o
I n d u s t r i a l a p p l i c a t i o n s o f p h a s e t r a n s f e r c a t a l y s i s
8 6 1
s a l t s ,
s u b s t i t u t i o n
R e c e n t
9
1
4
W i t h
8 6 2 H . H . F R E E D M A N
E p o x i d a t i o n
T h i s
A n
B P
I n d u s t r i a l a p p l i c a t i o n s o f p h a s e t r a n s f e r c a t a l y s i s
8 6 3
A
G E N E R A L I N D U S T R I A L A P P L I C A T I O N S
P h a r m a c e u t i c a l
A l k o x y p y r i d a z i n o n e s
1 3 6
H 2 N C H 2 C O O E t
N H 2 ? H C O O H
( 2 )
R
8 6 4 H . H . F R E E D M A N
e x a m p l e s ,
R 3 c ' 7 ( ) f l
C H C 0 0 C H
T h e m a t u r a t i o n o f P T C
a r e a s , s o m e q u i t e u n e x p e c t e d . I n t h i s
R X
C H C 1 3
C H 3 X
C O 2
( 3 )
K 2 C 0 3 ,
I n d u s t r i a l a p p l i c a t i o n s o f p h a s e t r a n s f e r c a t a l y s i s
8 6 5
F i n a l l y ,
a f f o r d s
y i e l d s
F U T U R E F O R P T C
I n
1 .
C h e m , ,
_______________
( i 8 6 T )
[
' i i a
_____________ ___________________
.
( Z8 6 T )
D E 9 i O 8
( E 8 6 1 )
' u a s s n t u s a
( E 8 6 T )
a
' ( 1 9 6 1 )
' ' i i n
' 9 6
' c c
' p S
' 9 1 7
' ( Z8 6 1 )
' 5
' 1 4
' ' 1 o d
' S ' 1 1 7
' ( c 86 1 )
c c c i
' 5 1 0
' 71 ' ' u n L u L u o 3 ' q i u s
' ( Z 86 1 )
' u a q 3 ' f
' j1 786 1 )
' i u V
' ' 3 o
[
________________
. f
' ( 1 786 1 )
H Z 6 1 9
p i . w
' V ' a
' q 2 o i x
' f
p u
H
9 9 8
!
( Z8 6 T )
' i js q y
______________
______________
.
(
*
c ;
S
_____________ ________
S
( i 8 6 T )
______________ _________________
( 8 6 T )
' Z& Z1 P
________________
[
a
!
' B
p u e
' 8 1 1
s u r ) I l a d
' 9 0 1
S A O B 1
!
[
[
________________
_______________
' ( 1 8 6 1
' ' i s q V
' 4 B
' f
[
' ) I
' a
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
' A N ' SSa m d
3 i u 1 3 p e Z )
1 "' d
U T U O P B p T XO U T
' ' I
' 0
' ' P S ' L u d l o d
' I '
' H
"I ' 1 ' ' 6 8
' i a
' m a U q z ) SI B H
' H
e s e q d jo S U O ! W 3 . I /d d e
je u s n p u j
8 6 8
H . H . F R E E D M A N
1 4 3 .
1 4 7 .
C h e w .
1 2 3 3 4 0 P
1 83 .