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7

7.1

(also available as a Mathcad worksheet)


(a) G = H TS at P = 2.5 MPa and T = 22399
. C = 49714
. K
equal with
G V = H V TS V = 28031
. 49714
. 6.2575 = 307.8 J g
the accuracy
G L = H L TS L = 96211
. 49714
. 2.5547 = 307.9 J g
of tables
(b) T ( C) T (K)
HV

TS V
GL

|UV
|W

225

49815
2806.3 49815
.
. 6.2639 =

3141
. J g

250

52315
28801
.
. 52315
. 6.4085 =

472.5

300

57315
30088
.
. 57315
. 6.6438 =

7991
.

350

62315
3126.3
.

62315
=
. 68403
.

1136.2

400 67315
3239.3 67315
.
. 7.0148 = 1482.7
(Note: All Gibbs free energies are relative to the internal energy and entropy of the liquid phase
being zero at the triple point. Since H L ~ U L , and G L = H L TS L , we have that G L = 0 at
the triple point.)
(c) T ( C) T (K)
HL

TS L
GV
43315
= 1659
.
.
. 19427
.
. J g
160 43315
67555
.
. 2.0419 = 1857
.
170 44315
719.21 44315
45315
= 206.3
.
.
. 21396
.
180 45315
76322
.
. 2.2359 = 227.9
190 46315
807.62 46315
.
. 2.3309 = 250.4
200 47315
852.45 47315
.
. 2.4248 = 2738
.
210 48315
897.76 48315
RESULTS
(d)
T ( C)
150
160
180
200
220
224
3
V m kg 0.001091 0.001102 0.001127 0.001157 0.001190 0.001197

to
0.07998
T ( C)

V m kg

225

250

300

350

400

0.08027 0.08700 0.09890 010976


.
012010
.

(e) Will compute CP from CP ~

FG H IJ
H T K

=
P

H (T + T ) H (T )
T

T ( C)

150

CP kJ kg K

170

180

190

200

210

4.328 4.392 4.430 4.472 4.518 4.572

224
4.6225
to
3.200

T ( C)

250

300

350

400

CP kJ kg K 2.952 2.574 2.350 2.260


These results are plotted below.

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