TYROLIT NORTH AMERICA − D OR B SUPERABRASIVE RESINOID BOND GRINDING WHEELS 2/1/2003

TYROLIT NORTH AMERICA

D OR B SUPERABRASIVE RESINOID BOND GRINDING WHEELS Revised: 2/1/2003

MSDS Contents Item Number:

4A898, 4A899, 4A900, 4A901, 4A902
SECTION I − IDENTIFICATION
SECTION II − HAZARDOUS INGREDIENTS Mfg. Model Number:
SECTION III − PHYSICAL DATA 40280, 40281, 40282, 40283, 40285
SECTION IV − FIRE EXPLOSION HAZARD DATA
SECTION V − HEALTH HAZARD DATA
SECTION VI − REACTIVITY DATA
SECTION VII − SPILL OR LEAK PROCEDURES
SECTION VIII − PERSONAL PROTECTION INFORMATION

MATERIAL SAFETY DATA SHEET

TYROLIT NORTH AMERICA INC.

CONSISTENT WITH NFPA CODE:

HAZARD RATING:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0

SECTION I − IDENTIFICATION

NAME AND ADDRESS:

TYROLIT NORTH AMERICA INC.
12 UNION STREET
WESTBOROUGH, MA 01581

EMERGENCY TELEPHONE NUMBER:

(800) 366−4431
(508) 366−4431

INFORMATION TELEPHONE NUMBER: (508) 366−4431

CONTACT PERSON: EHSMANAGER

REVISION DATE: 2/2003

CHEMICAL NAME AND SYNONYMS:

RESIN BOND DIAMOND OR CUBIC BORON NITRADE ABRASIVE PRODUCTS

TRADE NAME SYNONYMS: D OR B SUPERABRASIVE RESINOID BOND GRINDING WHEELS

CHEMICAL FAMILY FORMULA

CARBON C

CARBIDE SiC

OXIDE CaO,Al2O3,TiO2,
SiO2

ORGANO SILANE ESTER NH2(CH2)3Si(OC2H5)

METAL Cu,Ni,Al

RESIN ORGANIC POLYMERS

GLASS SILICATE BASE OXIDE GLASS

FLUORIDE Na3AlF6,CaF2

NITRIDE BN

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ALDEHYDE C5H4O2

SILICATE CaSiO2

ELEMENT P

SECTION II − HAZARDOUS INGREDIENTS

INGREDIENT CAS # WGT % OSHA TWA

(MG/M3)

DIAMOND 7782−40−3 0−49 NL

BORON NITRIDE 10043−11−5 0−35 15 TOTAL*

ALUMINUM OXIDE 1344−28−1 0−67 10 TOTAL*

TITANIUM DIOXIDE 13463−67−7 0−3 10 TOTAL*

SILICON CARBIDE 409−21−2 0−63 10 TOTAL*

CALCIUM OXIDE 1305−78−8 0−3 5

CALCIUM SILICATE 1344−95−2 0−25 0−7

COPPER 7440−50−8 0−85 1

NICKEL 7440−02−0 0−36 1

PHOSPHORUS 7723−14−0 0−4 0.1

CURED FORMVAR RESIN 63450−15−7 0−5 NAIF

CURED PHENOLIC RESIN 68585−23−9 0−86 NAIF

CURED MELAMINE RESIN 25036−13−9 0−42 NAIF

PTFE RESIN 9002−84−0 0−5 NAIF

CRYOLITE 15096−52−3 0−62 2.5

1−PROPANAMINE,3−(TRIETHOXYSILYL) 919−30−2 0−1 NAIF

FURFURAL 98−01−1 0−7 2 PPM (SKIN_

FRIT 65997−18−4 0 15 TOTAL*

GRAPHITE 7782−42−5 0 2.5

SILICA CYSTALLINE 14808−60−7 0 VARRIABLE**

ALUMINUM 7429−90−5 0 15 TOTAL*

INGREDIENT ACGIH TWA CARCIN. SARA RIM

(MG/M3) 313 CORE

DIAMOND NL NL NO 0

BORON NITRIDE 15 TOTAL* NO NO 0

ALUMINUM OXIDE 10 TOTAL* NO NO 0

TITANIUM DIOXIDE 10 TOTAL* NO NO 0

SILICON CARBIDE 10 TOTAL* NO NO 0−74

CALCIUM OXIDE 2 NO NO 0−5

CALCIUM SILICATE 15 TOTAL* NO NO 0−7

COPPER 1 NO YES 0−90

NICKEL 1 YES YES 0

PHOSPHORUS 0.1 NO YES 0

CURED FORMVAR RESIN NAIF NAIF NO 0

CURED PHENOLIC RESIN NAIF NAIF NAIF 10−27

CURED MELAMINE RESIN NAIF NAIF NAIF 0

PTFE RESIN NAIF NAIF NAIF 0

CRYOLITE 2.5 NO NO 0

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1−PROPANAMINE,3−(TRIETHOXYSILYL) NAIF NAIF NO 0

FURFURAL 2 PPM (SKIN) NO NO 0−1

FRIT 10 NO NO 0−50

GRAPHITE 2 RESPIRABLE NO NO 0−27

SILICA CYSTALLINE 0.1 RESPIRABLE YES NO 0−24

ALUMINUM 10 NO YES 0−65

*5 MG/M3 RESPIRABLE DUST

NL=NOT LISTED
NAIF=NO AVAILABLE INFORMATION FOUND
NA=NOT APPLICABLE

**REFER TO 29 CFR 1910.1000 TABLE Z−3 FOR EXPOSURE LIMIT CALCULATION

SECTION III − PHYSICAL DATA

BOILING POINT (DEG F): NAIF

VAPOR PRESSURE (MM HG): NAIF

VAPOR DENSITY (AIR=1): NA

SOLUBILITY IN WATER: SLIGHT

SPECIFIC GRAVITY (H2O=1): 1.5−3.5

% VOLATILES BY VOL (%): NAIF

EVAPORATION RATE: NA

MELTING POINT: NA

APPEARANCE AND ODOR:

SLIGHT, OFTEN WITH A RIM AND CORE. BROWN, GRAY, BLACK ALUMINUM OR COPPER
COLOR. WHEN IN USE

SECTION IV − FIRE EXPLOSION HAZARD DATA

FLASH POINT: NA

FLAMMABILITY LIMITS:
LEL: NA
UEL: NA

EXTINGUISHING MEDIA: WATER

SPECIAL FIRE FIGHTING PROCEDURES: NONE

UNUSUAL FIRE EXPLOSION HAZARD: NONE

SECTION V − HEALTH HAZARD DATA

PRIMARY ROUTES ACUTE AND CHRONIC HEALTH EFFECTS FIRST AID MEDICAL
OF ENTRY INFORMATION

INHALATION PULMONARY EFFECTS SUCH AS COUGHING, FRESH AIR, ARTIFICIAL

(DUST) SHORTNESS OF BREATH AND LOSS OF RESPIRATION. SEEK
BREATHING CAPACITY. MEDICAL ASSISTANCE.

EYE (DUST AND DUST MAY IRRITATE EYES. PARTICLES WASH WITH LARGE

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PARTICLES) MAY CUT, BURN OR OTHERWISE DAMAGE AMOUNTS OF WATER.

EYES. SEEK MEDICAL
ATTENTION.

SKIN (DUST AND HOT PARTICLES FROM GRINDING MAY CLEAN WITH SOAP AND
PARTICLES) PRODUCE MINOR BURNS. DUST MAY WATER. OBTAIN
IRRITATE SKIN. MEDICAL ASSISTANCE.

INGESTION NAIF SEEK MEDICAL

ASSISTANCE.

OTHER HEALTH GRINDING MAY CREATE SOUND AND OBTAIN MEDICAL

RISKS VIBRATION LEVELS THAT COULD EVALUATION AND USE
AFFECT HEARING AND AGGRAVATE PROPER PROTECTION.
CIRCULATORY PROBLEMS IN THE HANDS.

SECTION VI − REACTIVITY DATA

STABILITY:
(X) STABLE
( ) UNSTABLE

POLYMERIZATION:
( ) MAY OCCUR
(X) MAY NOT OCCUR

INCOMPATIBILITY (MATERIALS TO AVOID): NONE KNOWN

DECOMPOSITION PRODUCTS:
UNKNOWN, BUT DUSTS AND FUMES ARE GENERATED DURING THE GRINDING PROCESS.
THESE ARE PRODUCED FROM THE ABRASIVE PRODUCT, THE WORKPIECE AND COOLANT (IF
USED).

CONDITIONS TO BE AVOIDED: EXPOSURE TO EXTREMES OF TEMPERATURES AND MOISTURE

SECTION VII − SPILL OR LEAK PROCEDURES

STORAGE AND HANDLING:

SEE ANSI STANDARD B7.1 SAFETY REQUIREMENTS FOR THE USE, CARE AND PROTECTION
OF ABRASIVE WHEELS.

STEPS TO BE TAKEN IN CASE OF LEAKS OR SPILLS:

COLLECT THE MATERIAL IN THE MOST CONVENIENT AND SAFE MANNER POSSIBLE FOR
RECLAMATION OR DISPOSAL.

WASTE DISPOSAL METHOD:

SECURED SANITARY LANDFILL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS AND LAWS.

SECTION VIII − PERSONAL PROTECTION INFORMATION

RESPIRATOR PROTECTION (SPECIFY TYPE):

AS REQUIRED. SEE OSHA REGULATION 29 CFR 1910.94 FOR APPROVED DUST
RESPIRATORS.

VENTILATION LOCAL GENERAL:

RECOMMENDED. SEE OSHA 29 CFR 1910.94 FOR VENTILATION AND OSHA 29 CFR
1910.1000 FOR AIR CONTAMINATES.

OTHER: AS REQUIRED TO KEEP DUSTS AND FUMES BELOW TLV.

EYE PROTECTION: REQUIRED. REFER TO OSHA 29 CFR 1910.133

PROTECTIVE GLOVES:
AS NEEDED IN MOST OPERATIONS. RECOMMENDED IN PORTABLE GRINDING OPERATIONS
OR IN OPERATIONS WHERE SUBSTANTIAL VIBRATIONS ARE TRANSMITTED TO THE HANDS

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OR ARMS. SPECIAL PROTECTIVE GLOVES SHALL BE USED IN THE LATTER CASE.

HEARING:
AS NEEDED EXCEPT IN OPERATIONS WITH NOISE LEVEL EXCEEDING STATUTORY LIMITS.
SEE OSHA 29 CFR 1910.95 FOR HEARING PROTECTION.