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Remazol Ultra RGB and RGB dyes

The new generation of

Reactive dyestuffs
for medium to deep shades
Remazol Ultra Yellow RGBN Remazol Ultra Orange RGB Remazol Ultra Red RGB Remazol Ultra Carmine RGB Remazol Navy RGB

Warm reactive dye technology The Market for Reactive Dyes:

Levafix CA Levafix E/EA/EN/ Remazol Specialities

Fastness Dyeing performance Procedure cost

Remazol Ultra RGB

Warm reactive dyes

Fastness Dyeing performance Procedure cost Fastness Dyeing performance Dyes cost Procedure cost

Remazol Remazol A

Exhaust CPB Continuous

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Remazol Ultra RGB - August 2007

The Remazol Ultra RGB dyes at a glance


Remazol Ultra Yellow RGBN
Strong non phototropic Yellow component for deep ternary shade wit good Fastness properties Strong build-up Orange for orange, bordeaux, dark brown and olive shades. Dischargeable
1% 3% 6%

Remazol Ultra Orange RGB

Remazol Ultra Red RGB

Cost effective and tinctorially strong Red with excellent build-up behaviour for medium to deep shades. Perfect wash-off properties. Very homogenous dyeing behaviour in combination with Remazol UltraYellow RGBN and Navy RGB.

Remazol Ultra Carmine RGB

Tinctorial strong Red. Highest possible build-up for deepest red and brown shades. Outstanding wash-off properties. Dischargeable.

Remazol Navy RGB 150%

Cost effective Navy with very good build-up behaviour for medium to deep shades. Basis for colour constant recipes. Dischargeable.

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The Remazol Ultra RGB supplementary dyes


1% 3% 6%

Remazol Golden Yellow RGB conc.


Cost-effective yellow for trichromatic shades. Dischargeable.

Blue component with higher lightfastness when small quantities of blue shading components are required. Dischargeable.
New

Remazol Blue RGB

2%

4%

7%

Remazol Sapphire RGB

Remazol Sapphire RGB is a greenish blue dye with std fastnesses to expand the coverage of shades in combination with our exisiting Remazol RGB dyes.

Remazol Royal RGB

New

Remazol Royal RGB is a new dye developed to cover a wider gamut of shades of the color space.

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The Remazol Ultra RGB supplementary dyes


New

1%

3%

6%

Deeper black with a reddish cast to minimize the cost impact when a red shading component is needed. Economical dye with good fastness properties. Dischargeable.

Remazol Night Black RGB

Remazol Deep Black GWF


Remazol Deep Black GWF combines flexibility in application with highest fastness performance. The new dischargeable Deep Black meets the most stringent fastness specifications to fulfill the highest retailer/brand and market requirements. It can be used in exhaust, CPB and in all continuous application processes. Dischargeable.

2%

4%

7%

1%

3%

6%

Remazol Deep Black RGB


Economical strong build up Black with good Fastness properties. Dischargeable.

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Remazol Ultra RGB

Offers tangible benefits


Reduced costs
Less dyestuff Less water Less energy Reduced stock costs Shorter production cycles Right-First-Time performance Robustness

Cost

Higher productivity

Speed

Standardisation limits

Security

Shade reproducibility Standard fastness requirements Eco-compliance

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Remazol Ultra RGB: Flexibility in shading


Ultra Yellow RGBN

Ultra Orange RGB

Further components in the Remazol RGB range:


Ultra Red RGB

Remazol Golden Yellow RGB Remazol Red RGB Remazol Ultra Carmine RGB Remazol Blue RGB Remazol Deep Black RGB

Navy RGB 150%

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Remazol Ultra RGB - August 2007

Remazol RGB: Economical selection for all deep ternary shades


Golden Yellow Forest Green Dark Brown

Dark Olive

Bordeaux

Orange

Navy

Red

Remazol Ultra Yellow RGBN

Remazol Ultra Orange RGB

Remazol Ultra Red RGB

Remazol Ultra Carmine RGB

Remazol Navy RGB 150%

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Remazol Ultra RGB - August 2007

The Black Offer DyStars Offer: Is this the right strategy? YES
Two main options to have flexibility in shade and cost
Remazol Night Black RGB

Remazol Deep Black RGB

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Remazol Ultra RGB - August 2007

Flexibility: Our Black strategy

Navy GG Blue RGB / Navy RGB

The DyStar Offer Our black strategy:


More flexibility for shading

Deep Black RGB/ Night Black RGB

One greenish and one reddish black Any of them can be used as

Ultra Yellow RGB/ Ultra Orange RGB

Ultra Carmine RGB/ Ultra Red RGB

self shade

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Remazol Ultra RGB - August 2007

Cost

Significant less dye is needed to achieve the required depth of shade


dye conc. [% ] 10 9 8 7 6 5 4 3 2 1 0 1/3 SD 1/1 SD 2/1 SD
0.9 % 4.0 %

dye conc. [% ] C. I. Reactive Yellow 176 (133% ) Remazol UltraYellow RGBN Remazol Ultra Orange RGB 10 9

C. I. Reactive Red 239 (140% ) Remazol UltraRed RGB Remazol UltraCarmine RGB
8.3%

not achievable

8
6.0 %

7 6 5 4
3.8% 3.2% 1.9% 1.0% 1.3% 0.7% 0.6% 2.1%

2.5 %

2,28

3 2 1 0 1/3 SD 1/1 SD

1,24
0.7 %0,47

2/1 SD

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Remazol Ultra RGB - August 2007

Exhaust application

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Remazol Ultra RGB - August 2007

Remazol Ultra RGB: Flexible in Exhaust application


Salt Auxiliaries 60 C 10
Salt Auxiliaries Dyes 25 - 30 C 10 15 Salt Auxiliaries 10 1. Soda addition 20 10

Standard Process (e.g. Cotton Knit)

Dyes

Alkali

20

10

45

10-30
2. Alkali addition

Temperatur Rise (e.g. no dosing equipment)

50/60 C

10 30

Fixing time

1 C/min

Dyes
10 20` alkali 1,5 C/min 60 C 10 45 15 - 30

Migration Process (100% Viscose, yarn package)

80 C

pH 5-6

10

20

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Remazol Ultra RGB - August 2007

Cost Speed

Homogeneous on-tone build-up


NaCl Dye 25 C 20 M1 Soda ash 10 M2 10 10 10 10 10 10 10 10 60 C

M3

M4

M5

M6

M7

M8

M9

M10

on-tone build-up
Remazol Ultra Yellow RGBN Remazol UltraRed RGB Remazol Navy RGB 150%

Reactive Yellow S-3R Reactive Red S-2B Reactive Navy S-G

off-tone build-up
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Cost Speed

Remazol Ultra RGB


Up to 25% reduction in dyeing time Standard
competitor recommendation

Salt Auxiliaries 60 C

Dyes

Mixed alkali

10

80 min

45'
time timesaving saving

Remazol Ultra RGB


DyStar recommendation homogeneous dye combination rapid process

Salt Mixed Auxiliaries Dyes alkali 60 C

30 30 min! min!

10

50 min

45'

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Cost Speed

Remazol Ultra RGB


Excellent wash-off properties can increase productivity
optical density at 525 nm
700 600 500 400 300 200 100 0 1st rinsing (50C) neutralisation (50C) 1st soaping bath (95C) 2nd soaping bath (95C) rinsing (80C) rinsing cold

4% Remazol UltraCarmine RGB C. I. Reactive Red 239

1soaping soapingbath bath 1


1 2 3 4 5

Saving: Saving:

Rinsing baths of bulk trials with Remazol UltraCarmine RGB

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Cost Speed

Remazol Ultra RGB


The reduced dyeing time leads to potential cost savings of high productivity Benefits from reduced processing time per batch
Example
Production with commodities
3 batches *6 h 10' ;**5 h 40' Savings Savings

Production with Remazol RGB 17 h/day** 1 h 30' /day

18 h 30' /day*

240 working days/year

4,440 h/year*

4,080 h/year**

360 h/year

360 h : 5 h 40' /per batch

63 batches more/year

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Continuous application

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Remazol Ultra RGB - August 2007

Remazol Ultra RGB: Flexible in Padding application


Application Process Basic Recipe

Basic recipe:

Cold pad Batch (CPB)

fabric

alkali dyestuff winding and dwelling Washing off

x g/l 2 g/l

Remazol Ultra RGB Sera Wet C-AS

Alkali system according climate conditions and/or preference

padding

Pad Dry Pad Steam (PDPS)

x g/l 10 g/l 2 g/l 5 - 10 g/l Chemical pad: 250 g/l 20 g/l 3-6 ml/l Basic recipe: x g/l 10 g/l 2 g/l 5 - 10 g/l 20 g/l 10 - 14 ml/l

Basic recipe:

Remazol Ultra RGB Sera Gal M-IP Sera Wet C-AS Sera CON M-LU salt soda ash caustic soda 50% Remazol Ultra RGB Sera Gal M-IP Sera Wet C-AS Sera CON M-LU soda ash caustic soda 50%

Econtrol

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Remazol Ultra RGB - August 2007

Cost

Significant less dye is needed to achieve the required shade


Dark Brown
84.3 g/l
-39% -39%

51.8 g/l
C. I. Reactive Yellow 176 (133%) C. I. Reactive Red 239 (140%) C. I. Reactive Black 005 (133%) 54.0 g/l 19.3 g/l 11.0 g/l Remazol Ultra Yellow RGBN Remazol UltraRed RGB Remazol Navy RGB 150% 22.0 g/l 22.0 g/l 7.8 g/l

C. I. Reactive
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Remazol Ultra RGB

Remazol Ultra RGB - August 2007

Fastness

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Remazol Ultra RGB - August 2007

Security

(1) (2) (3) (4)

Light fastness (B02) Light fastness (M&S, C9A) Wash fastness (M&S C10A) Fastness to Chlorine 10 ppm

3.0% Remazol Ultra Yellow RGBN

(1) (2) (3) (4)


0.6% 2.4%

4-5 pass 4-5 4


2.4% 0.6%

(1) (2) (3) (4)


1.2% 1.8%

3-4 pass 3-4 4


0.6% 1.8% 0.6%

(1) (2) (3) (4)

4-5 pass 4-5 4


1.8% 1.2%

(1) (2) (3) (4)


1.8% 1.2%

3-4 pass 4 4
1.2% 1.2% 0.6%

(1) (2) (3) (4)

3-4 pass 4 3-4


0.6% 1.2% 1.2%

(1) (2) (3) (4)

4-5 pass 4-5 4-5


1.2% 1.8%

(1) (2) (3) (4)


2.4% 0.6%

3-4 pass 4 4
1.8% 0.6% 0.6%

(1) (2) (3) (4)

3-4 pass 4 4
1.2% 0.6% 1.2%

(1) (2) (3) (4)

3-4 pass 4 3-4


0.6% 0.6% 1.8%

(1) (2) (3) (4)

4-5 pass 4-5 4-5


0.6% 2.4%

(1) (2) (3) (4)

4 pass 4 4
2.4% 0.6%

(1) (2) (3) (4)

3-4 pass 4 4
1.8% 1.2%

(1) (2) (3) (4)

3-4 pass 4 4
1.2% 1.8%

(1) (2) (3) (4)

4 pass 4 4
0.6% 2.4%

(1) (2) (3) (4)

4-5 pass 4-5 4-5


3.0% Remazol UltraRed RGB

3.0% Remazol Navy RGB 150%

(1) (2) (3) (4)

4 pass 4 4

(1) (2) (3) (4)

4 pass 4 4

(1) (2) (3) (4)

4 pass 4 4

(1) (2) (3) (4)

4 pass 4 4

(1) (2) (3) (4)

4 pass 4-5 4-5

(1) (2) (3) (4)

4 pass 4-5 4

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Security

Fastness comparison
Commodities
Yellow 176/Red 239/Black 005
1 1-2 2 2-3 3

Light fastness (B02) Alkali Wet Light fastness (M&S, C9A) Multiple Wash fastness (M&S, C10A) Fastness to chlorine 10 ppm

Ultra Yellow RGBN/Ultra Red RGB/Navy RGB 150%


3-4 3-4
4 4-5 5 M &S C9A pass pass pass pass pass pass fail fail fail fail fail fail fail fail fail fail fail fail fail fail fail 1 1-2 2 2-3 3 3-4 3-4 4 4-5 5 M &S C9A pass pass pass pass pass pass pass pass pass pass pass pass pass pass pass pass pass pass pass pass pass

Remazol Ultra RGB

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