t (min

T
0
2
4.3
6.2
8.1
10.2
12
13
13.5
13.6
13.7
13.8
14

299
303
309
314
321
329
344
361
386
403
439
438
435

1/T
0.00334448
0.00330033
0.00323625
0.00318471
0.00311526
0.00303951
0.00290698
0.00277008
0.00259067
0.00248139
0.0022779
0.00228311
0.00229885

500
450
400
350
300
250
200
150
100
50
0
0

T
y = 9.1859x + 272.17

10

12

14

16

velocidad de
calentamiento

2 C/min
dT/dt
0
2
4.3
6.2
8.1
10.2
12
13
13.5
13.6
13.7
13.8
14
14.1333333
14.2833333
14.4333333
14.5833333
14.7333333
14.8833333
15.0333333
15.1833333

CA0

CB0
6.7

0.2

In dT/dt
T
-2831143.4
299
-2866920.2
303
-2920585.4
309
-2965306.4
314
-3027915.8
321
-3099469.4
329
-3233632.4
344
-3385683.8
361
-3609288.8
386
-3761340.2
403
-4083331.4
439
-4074387.2
438
-4047554.6
435
-4628927.6
500
-5523347.6
600
-6417767.6
700
-7312187.6
800
-8206607.6
900
-9101027.6
1000
-3925317.2 421.333333
-3907428.8 419.333333

1/T
0.00334448
0.00330033
0.00323625
0.00318471
0.00311526
0.00303951
0.00290698
0.00277008
0.00259067
0.00248139
0.0022779
0.00228311
0.00229885
0.002
0.00166667
0.00142857
0.00125
0.00111111
0.001
0.00237342
0.00238474

0
0
-1000000
-2000000
-3000000
-4000000
-5000000
-6000000
-7000000
-8000000
-9000000
-10000000

200

400

600

800

1000

y = -8944.2x - 156828

1200

1/T
0.00334448
0.00330033
0.00323625
0.00318471
0.00311526
0.00303951
0.00290698
0.00277008
0.00259067
0.00248139
0.0022779
0.00228311
0.00229885
0.002
0.00166667
0.00142857
0.00125
0.00111111
0.001

10

0
0
dT/dt

In dT/dt
-12.4437124
-12.0488119
-11.4756311
-11.0147134
-10.3935514
-9.71601824
-8.5305814
-7.30617729
-5.70150259
-4.72404467
-2.90403189
-2.95054795
-3.09137931
-0.4184
2.563
4.69257143
6.28975
7.532
8.5258

-5

-10

-15

-20

0.001

Jmol
0.002

0.003

y = -8944.2x + 17.47

1/T (K)

0.004

8.314

Jmol
K