12

th
ABCD (Date: 12-06-2011) Review Test-2
PAPER-2
Code-A
ANSWER KEY
CHEMISTRY
SECTION-2
PART-A
Q.1 A
Q.2 B
Q.3 B
Q.4 C
Q.5 B
Q.6 D
Q.7 C
Q.8 B
Q.9 C
PART-B
Q.1 (A) Q,R
(B) P
(C) P,S
Q.2 (A) Q
(B) P,Q,R
(C) S
(D) T
PART-C
Q.1 3036
[Marks will be awarded for
0690 or 2146 or 3039 also]
Q.2 0003
Q.3 0002 or 0004
Q.4 0008
Q.5 0040
Q.6 10
Note : (b option)
will not be checked
PHYSICS
SECTION-1
PART-A
Q.1 B
Q.2 A
Q.3 C
Q.4 D
Q.5 A
Q.6 A
Q.7 B
Q.8 D
Q.9 C
PART-B
Q.1 (A) S
(B) P
(C) Q
Q.2 (A) R
(B) Q
(C) S,T
(D) P
PART-C
Q.1 0040
Q.2 0021
Q.3 0001
Q.4 0180
Q.5 0008
Q.6 0001
MATHS
SECTION-3
PART-A
Q.1 B
Q.2 C
Q.3 C
Q.4 C
Q.5 A
Q.6 A
Q.7 B
Q.8 B
Q.9 D
PART-B
Q.1 (A) P or S
(B) Q,
(C) P
Q.2 (A) T,
(B) R,
(C) P,
(D) Q
PART-C
Q.1 0003
Q.2 0007
Q.3 0002
Q.4 0008
Q.5 0542
Q.6 0002
PHYSICS
Code A Page # 1
PART-A
Q.1
[Sol. I =
2
r 4
P
t
=
Pv 2
p
2
0
2
0
p =
2
r 4
vP 2
t

=
330 4
50 330 1 2
t
t
= 5 N/m
2
]
Q.2
[Sol. V
A
=
t
d 2
v
B
=
t 2
d
V
B
V
BW
V
W
V
A
V
AW
V
W
]
Q.3
[Sol. T = 2t
g

T = 2t
2
mg
3
m
2

= 2t
g 3
2
]
Q.4
[Sol. I
1
= 4I
I
2
= I
min
max
I
I
=
( )
( )
2
2 1
2
2 1
I I
I I

+
=
1
9
]
Q.5
[Sol. Coherence condition. ]
Q.6
[Sol. t =
10 u
d

d = (10 5)t =
10 u
d 5

u 10 = 5 u = 15 m/s ]
PHYSICS
Code A Page # 2
Q.7
[Sol.
Q.8
[Sol.
2cm
x
50 x
O
1cm
2
1
=
x 50
x

x =
3
50
50 x =
3
100
3
50
1
3
100
1
+
=
f
1
f =
9
100
cm ]
Q.9 Line passing through centre passes undeviated
3
50
30
=
3
40
]
PART-B
Q.2
[Sol. (B) T = 2p
. eff
g

g
eff.
| T +
(C) T =
v
L
=
T

(T) t =
m
v
d
remains same.
PART-C
Q.1
[Sol. g = Ae
2
A =
2
) 5 . 0 (
10
= 40 cm
PHYSICS
Code A Page # 3
Q.2
[Sol.
v 3
4

30
1

=
5
1
3
4

v 3
4
=
15
1

30
1
=
30
1
v = 40" u = 35"
v
1

30
3 / 4
+
=
5
3 / 4 1

v
1

90
6
+
90
4
v = 9"
distance from observer = 21" ]
Q.3
[Sol. A =
k
QE
=
3
4
10
100 10
= 10
5
m
V
max
= Ae =
A
m
k

=
1 . 0
1000
10
6
m/s = 10
3
m/s = 1 mm/s ]
Q.4
[Sol. Ax = ( 1) t d sin u = ( 1) t
D
dy
A| =

t 2
(

D
dy
t ) 1 (
=

t 2

(

8 . 1
10 10 9 . 0
10 6 . 1 5 . 0
3 3
6
=

t 2
[0.3 10
6
] =
7
10 6
2

t
[3 10
7
] = t 180 ]
Q.5
[Sol. d =
2 2
x y +
d
2
= u
2
t
2
cos
2
o + (ut sin o
2
1
gt
2
)
2
dt
dd
2
> 0
PHYSICS
Code A Page # 4
2u
2
t cos
2
h + 2(et sin o
2
1
gt
2
) (u sin o gt) > 0
2u
2
t cos
2
d + 2u
2
t sin
2
o + g
2
t
3
gu sin ot
2
2ut
2
g sin o > 0
2u
2
+ g
2
t
2
(3ug sin o) t > 0
Quad in t always > 0
D < 0
9u
2
g
2
sin
2
o 8u
2
g
2
< 0
sin2 a <
9
8
9 sin
2
o s 8 ]
Q.6
[Sol. The path difference at point P,
Ax = (SS
2
SS
1
) + (S
2
P S
1
P)
=
2 1
D
) 2 d ( d
D
dy
+
For constructive interference,
Ax =
2
2
1
D 2
d
D
dy
+
= n
2 2
) 10 (
1
10 ) t sin 5 . 0 )( 10 (
2 3 3 3

+
t

= n
(0.5 sin
|
.
|

\
| t
6
t) 10
6
+ 0.25 10
6
= (5000 10
10
)n = 0.5 10
6
n
sin
|
.
|

\
| t
6
t =
5 . 0
25 . 0 5 . 0 n
For the minimum value of t, n = 1.
sin
|
.
|

\
| t
6
t =
2
1

|
.
|

\
| t
6
t =
6
t
or t = 1 sec. ]
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. n
eq
Na
2
S
2
O
3
= n
eq
Na
2
S
2
O
8
or,
|
.
|

\
|
=

2
238
9 . 11
1000
) 1 25 . 0 ( V
V = 400 ml ]
Q.2
[Sol. B.P. of N(Me)
3
> NF
3
due to more dipoledipole interaction
CHCl
3
is more acidic than CHF
3
because stability of conjugate is higher due to back bonding in CCl
3

O
2
F
2
is polar molecule. ]
Q.3
[Sol. Rate of dehydration o stability of carbocation
Stability B > A > C ]
Q.4
[Sol. C
v,m
= 3
2
1
R + 3
2
1
R + (3N 6) R = (3N 3) R
C
p,m
= (3N 2) R
AH = n (3N 2)R AT
|w| = nR AT

H
| w |
A
=
2 N 3
1

]
Q.5
[Sol. N
2
(14) ;
+
2
N (13);

2
N (15);
2
2
N
+
(12)
Bond order 3 2.5 2.5 2
B.D.E. o Bond order
If Bond order is same
B.D.E. o
electron g antibondin of . no
1
O
2
2+
(14) O
2
+

(15) O
2

(17) O
2
2


(18)
Bond order 3 2.5 1.5 1.0
In O
2
electron removes from antibonding orbital which have higher energy in comparision of atomic 2p
orbital of oxygen atom. ]
CHEMISTRY
Code-A Page # 2
Q.6
[Sol. (A) Odd number of double bonds, both the ends are parallel to each other POS present.
(B) Free rotation due to smaller groups POS present.
(C) POS present.
(D) Even number of rings perpendicular to other no POS, no COS Chiral. ]
Paragraph for question nos. 7 to 9
[Sol.
Cl /h
2
v
Cl
+
Cl
+
Cl
*
(+)
]
PART-B
Q.2
[Sol.(A) BCl
3
does not dimerise, it is sp
2
hybridised so planar on hydrolysis it gives H
3
BO
3
whose basicity is
one.
(B) sp hybridised planar BeCl
2
dimerise give Be
2
Cl
4
in which Be is sp
2
hybridised and hydrolysis product is
Be(OH)
2
.
(C) sp
3
hybridised pyramidal in shape PCl
3
, does not dimerise on hydrolysis it gives H
3
PO
3
which show
tautomerism and product basicity is 2, HPO(OH)
2
.
(D) sp
3
hybridised AsCl
3
is pyramidal in shape which gives H
3
AsO
3
which does not show tautomerism due
to large size of As and basicity of H
3
AsO
3
is three. ]
PART-C
Q.1
[Sol. C
6
H
6
(l) +
2
15
O
2
6CO
2
+ 3H
2
O(l) + 150
AH
com.
= (50 + 6 410 + 3 330 + 3 600 +
2
15
500) (12 710 + 3 40 + 6 460)
= 3040
AG = AE + An
g
RT
3040 = AE 1.5 8.3 10
3
300
AE = 3036 Ans. ]
Q.2
[Sol.
D D D
D
D
Equivalent
+
]
Q.3
[Sol. Compound which hydrolysed by SN
2
mechanism increase hybridisation by one in transition state during
hydrolysis so all sp
3
hybridised central atoms have sp
3
d hybridisation in transition state PCl
3
, SiCl
4
]
CHEMISTRY
Code-A Page # 3
Q.4
[Sol.
(1) (1) (3) (3) ]
Q.5
[Sol. Mole of octane taken =
114
14 . 1 1000 10
= 100
C
8
H
18
+
2
25
O
2
8CO
2
+ 9H
2
O
x mole 8x mole 9x mole
C
8
H
18
+
2
17
O
2
8CO + 9H
2
O
(100 x) mole 8(100 x) mole 9(100 x) mole
from question : 8x 44 + 8(100 x) 28 + [9x + 9(100 x)] 18 = 43.72 10
3
x = 40 ]
Q.6
[Sol.(a) O.P. =
100
25
100
100
30 70
mix

o
=

; o
mix
= 10
(b) O.P. =
100
25
5 . 12

= 50%
Racemic mixture = 50% ( total 'd' form = 75%)
= 1075 Ans. ]
MATHEMATICS
Code A Page # 1
PART-A
Q.1
[Sol. f(x) = 19 x e Q
As, f(x) is continuous, so
f(x) = 19 x e R (f(x) is constant)
g(f(x)) =
) x ( f 39
2
+
=
361 39+
= 20 x e R. Ans.]
Q.2
[Sol. a
n
= tan
1

|
|
.
|

\
|
+ + + ) 2 n )( 3 n ( 1
1
= tan
1

|
|
.
|

\
|
+ + +
+ +
) 2 n )( 3 n ( 1
) 2 n ( ) 3 n (
= tan
1
(n + 3) tan
1
(n + 2)
s
n
= f(n) f(1) = tan
1
(n + 3) tan
1
3 s

=
2
t
tan
1
3 = cot
1
3 = sin
1

10
1
. Ans.]
Q.3
[Sol.
dy
dx
=
dt dy
dt dx
=
3
2
t 12
t 12
=
t
1
Now,
2
2
dy
x d
=
|
|
.
|

\
|
dy
dx
dy
d
=
|
.
|

\
|
t
1
dt
d
dy
dt
=
5 3 2
t 12
1
t 12
1
t
1
=
|
.
|

\
|

n
2
2
dy
dx
dy
x d
|
|
.
|

\
|
=
|
.
|

\
|
|
.
|

\
|
n
5
t
1
t 12
1
=
12
t
5 n

= constant
Hence, n = 5. Ans.]
Q.4
[Sol. Single element subsets
7
C
1
(1 cannot be taken)
Two element subsets
7
C
2
(2 cannot be taken)
Three element subsets
7
C
3
(3 cannot be taken)
Four element subsets
7
C
4
(4 cannot be taken)
Five element subsets
7
C
5
(5 cannot be taken)
Six element subsets
7
C
6
(6 cannot be taken)
Seven element subsets
7
C
7
(7 cannot be taken)
Total number of non-empty subsets are
7
C
1
+
7
C
2
+
7
C
3
+ .......+
7
C
7
= 127. Ans.]
Q.5
[Sol. Let I =
( )
}
+ +
11
nx ) 1 x ( n ) x 1 ( x
dx
l l
Put ln (x + 1) ln x = t
) x 1 ( x
dx
+
= dt
So, I =
} 11
t
dt
=
|
.
|

\
| 1
10
t 10
1
=
( )
10
x n ) 1 x ( n 10
1
l l +
+ C Ans.]
MATHEMATICS
Code A Page # 2
Q.6
[Sol. x
2x
2x
x
cot y 1 = 0 .........(1)
Now, differentiating equation (1) w.r.t. x, we get
2x
2x
(1 + ln x) 2 ( ) ( )

|
.
|

\
|
+ + x n 1 x y cot
dx
dy
y cosec x
x 2 x
l = 0
Now, at
|
.
|

\
| t
2
, 1
2(1 + ln 1) 2
( )
|
|
.
|

\
|
+
|
.
|

\
| t
0
dx
dy
1 1
2
, 1
= 0 1
dx
dy
2
, 1
= |
.
|

\
|
|
.
|

\
| t
. Ans.]
Paragraph for question nos. 7 to 9
[Sol. We have, f
n
(x) =
( )
}


1 n
2 n 2 2 n 2
2
1
dx x cos x sin x 2 sin n
=
( )
}


1 n
1 n 2 1 n 2
2
1
dx x cos x sin x sin x cos n 2
=
C
2
1
n 2
x cos
n 2
x sin
n 2
1 n
n 2 n 2
+
|
|
.
|

\
|
+
= sin
2n
x + cos
2n
x
1 n
2
1

+ C
As,
|
.
|

\
| t
4
f
n
=
1 n
2
1

C
2
1
2
1
2
1
1 n n n
+ +

=
1 n
2
1

C =
1 n
2
1

f
n
(x) = sin
2n
x + cos
2n
x
(i) We have, f
2
(x) = sin
4
x + cos
4
x = 1
2
1
sin
2
2x
f '
2
(x) = sin 4x
f '
2
|
.
|

\
| t
3
= |
.
|

\
| t
3
4
sin =
2
3
(ii) We have, g(x) = ( )
|
|
.
|

\
|
+

=

n
1 n
n 2 n 2
n
x cos x sin Lim
= (sin
2
x + sin
4
x + sin
6
x + ...........) + (cos
2
x + cos
4
x + cos
6
x + ........... )
=
x sin 1
x sin
2
2

+
x cos 1
x cos
2
2

= tan
2
x + cot
2
x = (tan x cot x)
2
+ 2
Hence minimum value of g(x) is 2.
(iii) Clearly, n =
| | 3 t cot Lim
1
t
=

Now,
}
dx
x cos x sin
) x ( f
2 2
3
=
}
+
dx
x cos x sin
x cos x sin
2 2
6 6
= dx
x cos x sin
x cos x sin 3 1
2 2
2 2
}

= ( )dx 3 x cosec x sec
2 2
}
= ( )dx 3 x cosec x sec
2 2
}
+ = tan x cot x 3x + C. Ans.]
MATHEMATICS
Code A Page # 3
PART-B
Q.1
[Sol.
(A) We have
2 1
2
x x
/\
0 1 x x = + o +
Now, x
1
+ x
2
= o, x
1
x
2
= 1

2 1
x x =
( )
2 1
2
2 1
x x 4 x x +

2 1
x x =
4
2
o
As 4
2
o <
5
o
2
4 < 5 o
2
9 < 0
o e ( 3, 3). ........(1)
Also roots must be real
D > 0 o
2
> 4
o e ( , 2] [2, ) ........(2)
(1) and (2)
o = 2 and 2
only 2 integral values of o P. Ans.
(B) We have f(x) = max. ( ) t

x ), x (cos cos
1
=

t s <
t
t
t
s < t t
t s s
t
t
< < t
2 x
2
3
, x
2
3
x , x 2
x
2
, x
2
x 0 , x
Clearly, f(x) is non-derivable at x =
2
3
, ,
2
t
t
t
. Ans.
x
y
t
y

=

x
O
(0, 0)
y = x t
y = 2t x y = t x / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / / /
2t t
2
3t
2
(C) Let e
sin x
= t,
then 1 t t t 3 t 2
2 2
= 1 t t 3 t 2 t
2 2
+ = +
As t
2
2t + 3 > 0 and t
2
t + 1 > 0 t e R
So, t
2
2t + 3 = t
2
t + 1 t = 2 e
sin x
= 2
sin x = ln 2 x = sin
1
(ln 2) or t sin
1
(ln 2). Ans. ]
Q.2
[Sol.
(A) D > 0, b < 0, c > 0, a > 0
roots different b < 0 Sum of roots > 0, c > 0 Product of roots > 0 both positive roots
Number of points = 5.
O
(0, 0)
x
y
MATHEMATICS
Code A Page # 4
(B) D > 0, b < 0, c < 0 one positive and one negative root 3 points.
y
x
O
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(C) D < 0, b = 0 ; c > 0 1 point.
O
y
x
(D) D > 0, b = 0, c < 0
y
x
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O
vertex on y-axis 2 points. ]
PART-C
Q.1
[Sol. (a 1)x
2
= x(2b + 3)
The above equation is satisfied by three distinct values of x therefore it is an identity
2 2a = 0 a = 1 and 2b + 3 = 0 b =
2
3
Now, f (x) = 2x + 1,
Let g (x) = px + q g ' (x) = p
( ) ) x ( g f = 6x 7 2(px + q) + 1 = 6x 7 2px + 2q + 1 = 6x 7
2p = 6 p = 3 and q = 4
g ' (2012) = 3 Ans.]
Q.2
[Sol.
n n
n
Lim
n l
[Using L'Hospital's Rule];
0
n
n n
Lim
n

l
or
n
1
n
n Lim


0
n
1
n
n Lim

=
n
n n
n
e Lim
l

e
0
1
MATHEMATICS
Code A Page # 5
Hence ( )
n n
n
n
n
b n a Lim
l
+

is of the form of 1

In order that the limit may exist and non zero (a + b) = 1 .......(1)
Hence L = ( )
n n
n
n
n
a 1 n a Lim
l
+

=
( ) | | 1 n a
n n
n
Lim
n 1
n
e

l
.
Now consider
( )
n
n n
1 n a
Lim
n 1
n
l

|
.
|

\
|
0
0
a
|
.
|

\
|
|
|
.
|

\
|

n
n n
1 e
Lim
n
n n
n l
l
Let
n
n n l
= y so that as n ,
n
n n l
= y 0
hence we have,
|
|
.
|

\
|

y
1 e
a Lim
y
0 y
= a
Hence L = e
a
= e
3
(given)
a = 3 ; using (a + b) = 1
b = 1 a = 4
Hence, (4b + 3a) = 16 9 = 7. Ans.]
Q.3
[Sol. Since [x] is an integer
x + 1 = 2k ; k e I

+
2
1 ) 1 k 2 ( 2 ) 1 k 2 ( 3
2
= k
(

+ + +
2
1 2 k 4 3 k 12 k 12
2
= k
[6k
2
8k + 3] = k 6k
2
8k + 3 = k
6k
2
9k + 3 = 0 2k
2
3k + 1 = 0 (k 1) (2k 1) = 0
k = 1 ; k =
2
1
(reject as k e I) k = 1
x = 1 so, n = 1
Hence 2
4 4 2
1
= |
.
|

\
| t
+ t +
t
+
t
t
. Ans.]
Q.4
[Sol. b
2
= ac + a
2
sin
2
B sin
2
A = sinA sin C
or sin (B + A) sin (B A) = sin A sin C
sin (B A) = sin A
B = 2A
again c
2
= ab + b
2
sin
2
C sin
2
B = sinA sin B
sin (C + B) sin (C B) = sinA sin B
C = 2B
Hence A + 2A + 4A = t A =
7
t
MATHEMATICS
Code A Page # 6
A =
7
t
; =
7
2t
; C =
7
4t
[
A cos =
7
cos
t

7
2
cos
t

7
4
cos
t
=
8
1
Hence absolute value of sec A sec B sec C = 8 Ans.]
Q.5
[Sol. S
2012
=
r 1
) r 1 ( a
2012

= 200 ......(1) and S

4024
=
r 1
) r 1 ( a
4024

= 380 .....(2)
(2)

(1)
2012
4024
r 1
r 1

=
200
380
=
10
19
1 + r
2012
=
10
19
r
2012
=
10
9
.....(3)
Using (3) in (1)
|
.
|

\
|

10
9
1
r 1
a
= 200
r 1
a

= 2000
S
6036
=
r 1
a

(1 r
6036
) = 2000
|
|
.
|

\
|
|
.
|

\
|

3
10
9
1
=
1000
) 729 1000 ( 2000
S
6036
= 2(271) = 542 Ans.]
Q.6
[Sol.
dx
d
(x
2
y) = x 1
Integrating both sides
x
2
y =
}
dx ) 1 x ( =
2
x
2
x + C
If x = 1, y = 0
0 =
2
1
1 + C C =
2
1
x
2
y =
2
x
2
x +
2
1
y =
2
1

2
x 2
1
x
1
+
3 3 2
x
1 x
x
1
x
1
dx
dy
= =

3
x
1 x
> 0
x e ( , 0) (1, ) ]