1

2
3
4
5
6
7
8
9
10

Time(sec)

Trial
Moles of S2O3 2(mol I3-) produced
(mol I3-) produced/t
log((mol I3-) produced/t)
Volume KI (mL)
[I-]0 (mol/L)
log [I-]0
Volume of H2O2 (mL)
[H202]0 (mol/L)
log [H202]0
K'

Trial 1

Time (sec)
Average K'
Standard Deviation

Trial 3

Trial 4

Trial 5

Trial 7

0.00002
0.00001
0.00000029
-6.54
3.0
0.090
-1.05
3.0
0.030
-1.52
0.00011

0.00002
0.00001
0.00000040
-6.40
4.0
0.12
-0.92
3.0
0.030
-1.52
0.00011

0.00002
0.00001
0.00000018
-6.74
1.0
0.030
-1.52
5.0
0.050
-1.30
0.00012

0.00002
0.00001
0.00000024
-6.61
1.0
0.030
-1.52
7.0
0.070
-1.15
0.00012

0.00002
0.00001
0.000000066
-7.18
1.0
0.030
-1.52
2.0
0.020
-1.70
0.00011

106.19

49.6

34.31

25.25

54.72

41.09

150.91

Time for Color change Reaction Rate

Calc. k'
25.25
0.0000003960
46.62
0.0000000085
9.41
0.0000010627

ln k'
0.000110011
0.0000023597
0.000295194

Temperature
-9.11
-12.96
-8.13

y
-1.52
-1.22
-1.05
-0.92
-1.52
-1.52
-1.52

Trial 6

0.00002
0.00001
0.00000020
-6.70
2.0
0.060
-1.22
3.0
0.030
-1.52
0.00011

0.000111823
0.0000056

Trial 4
Cold
Warm

Trial 2
0.00002
0.00001
0.000000094
-7.03
1.0
0.030
-1.52
3.0
0.030
-1.52
0.00010

-7.03
-6.7
-6.54
-6.4
-6.74
-6.61
-7.18

Y
0.003367003
0.003508772
0.003164557

-9.114930187
-12.95695982
-8.127876985

1/T (K)
297
285
316

0.00337
0.00351
0.00316

log((mol I3-) produced/t) vs. log[ I-]0

-6.3
-1.6

-1.4

-1.2

-1

-0.8

-0.6

y = 1.0446x - 5.4375
R = 0.9991

-0.4

-0.2

0
-6.4

-6.5

-6.6

-6.7

-6.8

-6.9

-7

-7.1

Y
-1.52
-1.3
-1.15
-1.7

-7.03
-6.74
-6.61
-7.18

#NUM!

#NUM!

log((mol I3-) produced/t) vs. log[ H2O2]0

-6.5
-1.8

-1.6

-1.4

-1.2

y = 1.0747x - 5.3666
R = 0.9917

-1

-6.61

-0.8

-0.6

-0.4

-0.2

0
-6.6

-6.7

-6.74
-6.8

-6.9

-7
-7.03

-7.1

-7.18

-7.2

-7.3

Y
Linear (Y)

ln k' versus 1/T (K)

0
0.0031

0.00315

0.0032

0.00325

0.0033

0.00335

0.0034

0.00345

0.0035

0.00355

-2

-4

-6
Y

Linear (Y)
-8

-8.127876985
-9.114930187

-10

-12

y = -13403x + 34.791
R = 0.8259
-12.95695982

-14