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Trng Trung Hc Ph Thng Ph Ct I Page 1 22/11/2010 Bi Tp n Thi i Hc V d 3: Ha tan hon ton 3,22 g hn hp X gm Fe, Mg v Zn bng mt lng va va dung dch H2SO4 lo.ng thu c 1,344 lt kh H2 ( ktc) v dung dch cha m gam mui.Gi tr ca m l:A. 8,98. B.9,52 C. 10,27 D. 7,25 V d 4: t chy hon ton m gam hn hp X gm CH4, C3H6 v C4H10 cn V lit O2 (ktc) thu c 4,4 gam CO2 v 2,52 gam H2O. Tnh m v V? S:3,808 (lt) V d 5: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lit kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l B. C2H5OH v CH2=CH-CH2-OH A. CH3OH v CH2=CH-CH2-OH C. CH3OH v C2H5OH D. C2H5OH v CH3OH V d 6: em nung mt khi lng Cu (NO3)2 sau mt thi gian dng li lm ngui, ri cn thy khi lng gim 0,54 gam. Khi lng mui Cu(NO3)2 . b nhit phn l A. 0,5 gam B. 0,49 gam C. 9,4 gam D. 0,94 gam V d 7: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH,thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gammt mui. Cng thc ca X l A. CH3COOC(CH3)=CH2 B. HCOOC(CH3)=CHCH3 C. HCOOCH2CH=CHCH3 D. HCOOCH=CHCH2CH3 V d 9: X ph.ng ha hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. HCOOCH3 v HCOOC2H5 B. C2H5COOCH3 v C2H5COOC2H5 C. CH3COOC2H5 v CH3COOC3H7 D. CH3COOCH3 v CH3COOC2H5 V d 10: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2 B. 0,1 mol C3H6 v 0,2 mol C3H4 C. 0,2 mol C2H4 v 0,1 mol C2H2 D. 0,2 mol C3H6 v 0,1 mol C3H4 V d 11:Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY ( X;Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX< ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX tronghn hp ban u l A. 58,2% B. 41,8% C. 52,8% D. 47,2% V d 12: Cho18 gam hn hp hai ancol gm mt ancol no n chc v mt ancol n chc c mt lin kt i trong phn t vi s mol bng nhau tc dng ht vi Na d, thu c 4,48 lt H2 ( ktc). CTCT ca hai ancol l A. CH3CH2OH v CH2=CH-CH2OH B. CH3CH2CH2OH v CH2=CH-CH2OH C. CH3OH v CH2=CH-CH2OH D. CH3CH2CH2CH2OH v CH2=CH-CH2OH V d 13: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C2H4O2 v C5H10O2 B. C2H4O2 v C3H6O2 C. C3H4O2 v C4H6O2 D. C3H6O2 v C4H8O2

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V d 14: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca (OH)2 (d) th. khi lng b.nh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l

A. CH3COOH v CH3COOC2H5 B. C2H5COOH v C2H5COOCH3 C. HCOOH v HCOOC2H5 D. HCOOH v HCOOC3H7 V d 15:Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy
hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3:4. Hai ancol l

A. C2H4(OH)2 v C3H6(OH)2 B. C2H5OH v C4H9OH C. C2H4(OH)2 v C4H8(OH)2 D. C3H5(OH)3 v C4H7(OH)3 Vd 16: Hp cht M c to thnh t cation X+ v anion Y 2-, Mi ion u do 5 nguyn t ca hai nguyn t to nn. Tng s proton trong X+ l 11 v tng s electron trong Y 2- l 50.Hai nguyn t trong Y 2- thuc cng mt phn nhm v thuc hai chu k lin tip.Hy xc nh cng thc phn t v gi tn M. Vd 17: Cho 11 gam hn hp hai kim loi Fe, Al tan hon ton trong dung dch HCl thu c 8,96 lt kh H2 ( ktc) v dung dch ca hai mui clorua. Tng khi lng hai mui clorua (khan) l: A. 40,1 gam B. 39,4 gam C. 34,9 gam D. 64,8 gam Vd 18: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10% thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l: A.101,48 gam B. 101,68 gam C. 97,80 gam D. 88,20 gam V d 19: Cho 27,2 gam hn hp gm hai ancol tc dng va vi Na thu c hn hp hai mui v 6,72 lt kh H2 ( ktc). Tng khi lng hai mui thu c l: A. 40,5 gam B. 45,2 gam C. 40,4 gam D. 44,0 gam V d 20: Trung h.a m gam hn hp hai axit cacboxilic cn 300 ml dung dch NaOH1M thu c 23,1 gam hn hp hai mui. Gi tr ca m l A. 18,2 B, 20,1 C. 15,6 D. 16,5 V d 21: Cn thm bao nhiu gam KCl vo 450 gam dung dch KCl 8% thu c dung dch 12%. V d 22: Cn thm bao nhiu lt nc ct vo 10 lt dung dch HCl c pH = 3 c dung dch c pH = 4. V d 23: ng trong t nhin gm hai ng v 63Cu v 65Cu. Khi lng nguyn t trung bnh l 63,54. T l % khi lng ca 63Cu trong CuCl2 l A. 31,34% B. 34,18% C. 73,00% D. 31,48% V d 24: Cho 41,2 gam hn hp gm C2H5COOH v C2H5COOCH3 tc dng va vi dung dch NaOH thu c 48,0 gam mui C2H5COONa. Thnh phn % theo s mol v % theo khi lng ca C2H5COOH trong hn hp u ln lt l A. 35,92% v 40% B. 40% v 35,92% C. 36,85%v 50% . D. 60% v 64,08% Vd 25: Ha tan hon ton 12 gam hn hp Fe, Cu ( t l mol 1 : 1) bng axit HNO3, thu c V lt (ktc) hn hp kh X (gm NO v NO2) v dung dich Y (ch cha hai mui v axit d).T khi ca X i vi H2 bng 19. Gi tr ca V l:A.3,36 B.2,24 C 4,48 D. 5,60 Vd 26: Ha tan hon ton 12,42 gam Al bng dung dch HNO3 lo.ng (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l A. 97,98. B. 106,38. C. 38,34. D. 34,08. V d 27: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 lo.ng, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (

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Trng Trung Hc Ph Thng Ph Ct I Page 3 22/11/2010 sn phm kh duy nht, ktc), dung dch Y v c.n li 2,4 gam kim loi.. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l A. 151,5 B. 137,1. C. 97,5. D. 108,9 V d 28: Mt dung dch cha 0,02 mol Cu2+; 0,03 mol K+; x mol Cl v y mol SO4 2 - . Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x,y ln lt l A. 0,01 v 0,03 B. 0,02 v 0,05 C. 0,05 v 0,01 D. 0,03 v 0,02 V d 29: Mt dung dch c cha 0,02 mol NH4+ , x mol Fe3+; 0,01 mol Cl -; 0,02 mol SO4 2- ,Khi c cn dung dch ny thu c lng mui khan l A. 2,635 gam B. 3,195 gam C. 4,315 gam D. 4,875 gam V d 30: Cho m gam bt Fe vo 800 ml dung dch gm Cu(NO3)2 0,2M v H2SO4 0,25 M. Saukhi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO(sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 10,8 v 4,48. B. 10,8 v 2,24. C. 17,8 v 2,24 D. 17,8 v 4,48 V d 31: Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch(gm H2SO4 0,0375M v HCl 0,0125M) thu c dung dch X. Gi tr pH ca dung dch X l: A. 2. B.1. C.6. D. 7. V d 32: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l: A. 13,0. B. 1,2. . C. 1,0. D. 12,8. Vd 33:Oxi ha hon ton m gam bt Fe thu c hn hp ba oxit st. Ha tan hon ton hn hp ba oxit st bng dung dch HCl d, tip tc cho dung dch thu c phn ng hon ton vi NaOH d, thu c kt ta X. Ly kt ta X, ra sch, ri em nung ngoi khng kh n khi lng khng i cn nng 16 gam.Gi tr ca m l: A.5,6. B.11,2. C 8,4. D.16,8. BI TP T GII: 1/ Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung h.a 0,3 mol X th. cn dng 500ml dung dch NaOh 1M. Hai axit l A. HCOOH, HOOC CH2 COOH. B. HCOOH, CH3COOH. C. HCOOH, C2H5COOH D. HCOOH, HOOC COOH 2/ X ph.ng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 1400C, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 18,00. B. 8,10. C. 16,20. D. 4,05. 3/ Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a, V l: A. m = a V/5,6 . B. m = 2a V/11,2 . C. m = 2a V/22,4 . D. m = a +V/5,6 . 4/ Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm ammr chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch z thu c m gam mui khan. Gi tr ca m l A. 8,2 B.10,8 C.9,4 D.9,6. 5/ t chy hon ton 0,2 mol mt ancol X no, mch h, cn va 17,92 lt kh O2 ( ktc).Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th. to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 4,9 v propan-1,2- iol. B. 9,8 v propan-1,2-iol. C. 4,9 v glixerol. D. 4,9 v propan-1,3- iol. 6/ Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong d.y ng ng. Oxi

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Trng Trung Hc Ph Thng Ph Ct I Page 4 22/11/2010 ha hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 tronh A. 15,3. B. 13,5. C. 8,1. D. 8,5. NH3, thu c 54 gam Ag. Gi tr ca m l: 7/ Este X ( c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc ( c t l khi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng va ht vi 300ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 27,75. B. 24,25. C. 26,25. D. 29,75. 8/ Hiro ha hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th. cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 17,8. B. 24,8. C. 10,5. D. 8,8. 9/ Cho 0,02 mol amino axit X tc dng va vi 200ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l: A. H2NC2H3(COOH)2 B. H2NC3H5(COOH)2 C. (H2N)2C3H5COOH. D. H2NC3H6COOH. 10/ Hn hp X gm axit Y n chc v axit Z hai chc ( Y,Z c cng s nguyn t C ). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l: A. HOOC CH2 COOH v 70,87%. B. HOOC CH2 COOH v 54,88%. C. HOOC COOH v 60,00%. D. HOOC COOH v 42,86%. 11/ Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO ( sn phm kh duy nht ). Cho V ml dung dch NaOH 1M vo dung dch X thu lng kt ta thu c l ln nht. Gi tr ti thiu ca V l: A. 240. B. 120. C. 360. D. 400. 12/ Nung 6,58 gam Cu(NO3)2 trong b.nh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH bng: A. 2 B. 3. C. 4. D. 1. 13/ Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 lo.ng, thu c 940,8 ml kh NxOy ( sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l: A. NO v Mg. B. N2O v Al. C. N2O v Fe. D. NO2 v Al. 14/ Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO ( sn phm kh duy nht) v dung dch X. Dung dch X c th h.a tan ti a m gam Cu. Gi tr ca m l: A. 1,92. B. 0,64. C. 3,84. D. 3,20. 15/ Cho 2,24 gam bt st vo 200ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l A. 2,80. B. 2,16. C. 4,08. D. 0,64. 16/ Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta.Gi tr ca m l:A. 45,6. B. 48,3. C.36,7. D. 57,0.

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