740

Pesticides

Synthesis

Handbook

THIOPHENES THIOPYRANES TRITHIANES

Dimethenamid

Uses:

herbicide,

maize,

soyabeans

Trade names: Type:

Frontier amide

(Sandoz)

thiophene,

Synthesis :

%/
g
-C-

OH

--C--C--

I I I I
S
I

SH

I
, - C =.

, I
9 ---.C----C

//
"---C

0 9 4-,--- C ~ , , , C , - - - C

\
OH

OH

>

--c--c--c

I
acid

# \

Oil

thiolactic acid

metacrylic

I I
I I I

I I I I I --C--O--C--C--C-+ I I I I N /\ I methoxy 2 amino propane I

S

i
_

2.4 dimethyl tetrahydro 3 thiophenone

SOCl

I
-- C,.=.

-el
O~C

CI I

I
--C--

-'~---,,- ~. -~-~'-o-~'~S /
"I--

Cl---c---c

i
I

#
\
Cl

>

-T~--~-~-o-~-o-~IL I w I
I I I ~ j

S7

~-dimethenamid

chloro acetyl chloride