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SEPARACION DE BENCENO

1. Esquema de proceso

VAP1
COOL
FEED

FL1

VAP2

COOL
FL2
LIQ1

LIQ2

2. Resultados
ASPEN PLUS IS A TRADEMARK OF
ASPEN TECHNOLOGY, INC.
TEN CANAL PARK
CAMBRIDGE, MASSACHUSETTS 02141
617/949-1000
PLATFORM: WIN32
2003
VERSION: 11.1
Build 193 Patchlevel 1
INSTALLATION: AspenTech
ASPEN PLUS
PLAT: WIN32
VER: 11.1
PAGE

HOTLINE:
U.S.A. 888/996-7001
EUROPE (32) 2/724-0100

SEPTEMBER 30,
TUESDAY
11:30:20 A.M.
09/30/2003

I
SIMULACION DEL PROCESO DE SEPARACION DE BENCENO

ASPEN PLUS (R) IS A PROPRIETARY PRODUCT OF ASPEN TECHNOLOGY, INC.


(ASPENTECH), AND MAY BE USED ONLY UNDER AGREEMENT WITH ASPENTECH.
RESTRICTED RIGHTS LEGEND: USE, REPRODUCTION, OR DISCLOSURE BY THE
U.S. GOVERNMENT IS SUBJECT TO RESTRICTIONS SET FORTH IN
(i) FAR 52.227-14, Alt. III, (ii) FAR 52.227-19, (iii) DFARS
252.227-7013(c)(1)(ii), or (iv) THE ACCOMPANYING LICENSE AGREEMENT,
AS APPLICABLE. FOR PURPOSES OF THE FAR, THIS SOFTWARE SHALL BE
DEEMED
TO BE "UNPUBLISHED" AND LICENSED WITH DISCLOSURE PROHIBITIONS.
CONTRACTOR/SUBCONTRACTOR: ASPEN TECHNOLOGY, INC. TEN CANAL PARK,
CAMBRIDGE, MA 02141.
TABLE OF CONTENTS

RUN CONTROL SECTION....................................


RUN CONTROL INFORMATION...........................

1
1

FLOWSHEET SECTION......................................
FLOWSHEET CONNECTIVITY BY STREAMS.................

2
2

ASPEN PLUS
PAGE 1

FLOWSHEET CONNECTIVITY BY BLOCKS..................


COMPUTATIONAL SEQUENCE............................
OVERALL FLOWSHEET BALANCE.........................

2
2
2

PHYSICAL PROPERTIES SECTION............................


COMPONENTS........................................

3
3

U-O-S BLOCK SECTION....................................


BLOCK: COOL
MODEL: HEATER....................
BLOCK: FL1
MODEL: FLASH2....................
BLOCK: FL2
MODEL: FLASH2....................

4
4
4
5

STREAM SECTION.........................................
COOL FEED LIQ1 LIQ2 VAP1..........................
VAP2..............................................

7
7
8

PROBLEM STATUS SECTION.................................


BLOCK STATUS......................................

9
9

PLAT: WIN32

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


RUN CONTROL SECTION
RUN CONTROL INFORMATION
-----------------------

THIS COPY OF ASPEN PLUS LICENSED TO UNIV. IBEROA


TYPE OF RUN: NEW
INPUT FILE NAME: _4957xta.inm
OUTPUT PROBLEM DATA FILE NAME: _4957xta VERSION NO.
LOCATED IN:

PDF SIZE USED FOR INPUT TRANSLATION:


NUMBER OF FILE RECORDS (PSIZE) =
0
NUMBER OF IN-CORE RECORDS
=
256
PSIZE NEEDED FOR SIMULATION
=
256
CALLING PROGRAM NAME:
apmain
LOCATED IN:
C:\ARCHIV~1\ASPENT~1\ASPENP~2.1\Engine\xeq

SIMULATION REQUESTED FOR ENTIRE FLOWSHEET

ASPEN PLUS
PAGE 2

PLAT: WIN32

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


FLOWSHEET SECTION
FLOWSHEET CONNECTIVITY BY STREAMS
--------------------------------STREAM
FEED
VAP1
VAP2

SOURCE
---FL1
FL2

DEST
COOL
-------

STREAM
COOL
LIQ1
LIQ2

SOURCE
COOL
FL1
FL2

DEST
FL1
FL2
----

FLOWSHEET CONNECTIVITY BY BLOCKS


-------------------------------BLOCK
COOL
FL1
FL2

INLETS
FEED
COOL
LIQ1

OUTLETS
COOL
VAP1 LIQ1
VAP2 LIQ2

COMPUTATIONAL SEQUENCE
---------------------SEQUENCE USED WAS:
COOL FL1 FL2
OVERALL FLOWSHEET BALANCE
------------------------***

MASS AND ENERGY BALANCE


IN

DIFF.
CONVENTIONAL COMPONENTS (LBMOL/HR)
H2
405.000
0.401289E-09
CH4
95.0000
0.366217E-09
C6H6
95.0000
0.196981E-08
TOLUENE
5.00000
0.203621E-08
TOTAL BALANCE
MOLE(LBMOL/HR)
600.000
0.000000E+00
MASS(LB/HR
)
10222.0
0.143513E-08
ENTHALPY(BTU/HR )
0.736075E+07

***
OUT

RELATIVE

405.000

95.0000

95.0000
5.00000

600.000
10222.0
-761076.

1.10340

ASPEN PLUS
PAGE 3

PLAT: WIN32

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


PHYSICAL PROPERTIES SECTION
COMPONENTS
---------ID
TYPE
NAME
H2
C
CH4
C
C6H6
C
TOLUENE C
TOLUENE
ASPEN PLUS
PAGE 4

FORMULA

NAME OR ALIAS

H2
CH4
C6H6
C7H8

REPORT

H2
CH4
C6H6
C7H8

PLAT: WIN32

H2
CH4
C6H6

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


U-O-S BLOCK SECTION
BLOCK: COOL
MODEL: HEATER
-----------------------------INLET STREAM:
FEED
OUTLET STREAM:
COOL
PROPERTY OPTION SET:
PENG-ROB
***
DIFF.
TOTAL BALANCE
MOLE(LBMOL/HR)
0.000000E+00
MASS(LB/HR
)
0.000000E+00
ENTHALPY(BTU/HR

STANDARD PR EQUATION OF STATE

MASS AND ENERGY BALANCE


IN

600.000

600.000

10222.0

10222.0

0.736075E+07
***

***
OUT

INPUT DATA

TWO
PHASE TP FLASH
SPECIFIED TEMPERATURE
PRESSURE DROP
MAXIMUM NO. ITERATIONS
CONVERGENCE TOLERANCE
0.00010000

*** RESULTS
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSI
HEAT DUTY
BTU/HR
OUTLET VAPOR FRACTION
PRESSURE-DROP CORRELATION PARAMETER

170444.

RELATIVE

0.976844

***

F
PSI

200.000
0.0
30

***
200.00
550.00
-0.71903E+07
0.86932
0.00000E+00

V-L PHASE EQUILIBRIUM :


COMP
H2

F(I)
0.67500

X(I)
0.11324E-01

Y(I)
0.77476

K(I)

68.422
CH4
0.15833
0.14355E-01
0.17998
12.538
C6H6
0.15833
0.91825
0.44103E-01
0.48033E-01
TOLUENE
0.83333E-02
0.56073E-01
0.11572E-02
0.20639E-01
ASPEN PLUS
PLAT: WIN32
VER: 11.1
09/30/2003
PAGE 5
SIMULACION DEL PROCESO DE SEPARACION DE BENCENO
U-O-S BLOCK SECTION
BLOCK: FL1
MODEL: FLASH2
-----------------------------INLET STREAM:
COOL
OUTLET VAPOR STREAM:
VAP1
OUTLET LIQUID STREAM: LIQ1
PROPERTY OPTION SET:
PENG-ROB
***
DIFF.
TOTAL BALANCE
MOLE(LBMOL/HR)
0.000000E+00
MASS(LB/HR
)
0.143513E-08
ENTHALPY(BTU/HR

MASS AND ENERGY BALANCE


IN

***
TWO
PHASE TP FLASH
SPECIFIED TEMPERATURE F
SPECIFIED PRESSURE
PSI
MAXIMUM NO. ITERATIONS
CONVERGENCE TOLERANCE

OUTLET TEMPERATURE
OUTLET PRESSURE
HEAT DUTY
VAPOR FRACTION

STANDARD PR EQUATION OF STATE


***
OUT

600.000

600.000

10222.0

10222.0

170444.

-761076.

INPUT DATA

RELATIVE

1.22395

***
100.000
500.000
30
0.00010000

*** RESULTS
F
PSI
BTU/HR

***
100.00
500.00
-0.93152E+06
0.83621

V-L PHASE EQUILIBRIUM :


COMP
H2
104.00
CH4
12.023
C6H6
0.84647E-02

F(I)
0.67500

X(I)
0.77470E-02

Y(I)
0.80570

0.15833

0.15497E-01

0.18631

0.15833

0.92662

0.78435E-02

K(I)

TOLUENE
0.29089E-02

0.83333E-02

BLOCK: FL2
MODEL: FLASH2
-----------------------------INLET STREAM:
LIQ1
OUTLET VAPOR STREAM:
VAP2
OUTLET LIQUID STREAM: LIQ2
PROPERTY OPTION SET:
PENG-ROB
ASPEN PLUS
PAGE 6

PLAT: WIN32

0.50133E-01

0.14583E-03

STANDARD PR EQUATION OF STATE

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


U-O-S BLOCK SECTION
BLOCK:

FL2

MODEL: FLASH2 (CONTINUED)


***

DIFF.
TOTAL BALANCE
MOLE(LBMOL/HR)
0.000000E+00
MASS(LB/HR
)
0.119776E-15
ENTHALPY(BTU/HR
0.336374E-07

MASS AND ENERGY BALANCE


IN

98.2758

98.2758

7593.32

7593.32

0.201482E+07

*** INPUT DATA


TWO
PHASE PQ FLASH
SPECIFIED PRESSURE
PSI
SPECIFIED HEAT DUTY
BTU/HR
MAXIMUM NO. ITERATIONS
CONVERGENCE TOLERANCE

OUTLET TEMPERATURE
OUTLET PRESSURE
VAPOR FRACTION

***
F
PSI

***
OUT

RESULTS

0.201482E+07

RELATIVE

***
14.6959
0.0
30
0.00010000
***
99.830
14.696
0.28106E-01

V-L PHASE EQUILIBRIUM :


COMP
H2

F(I)
0.77470E-02

X(I)
0.77800E-04

Y(I)
0.27295

CH4

0.15497E-01

0.13129E-02

0.50597

0.92662

0.94713

0.21735

0.50133E-01

0.51474E-01

0.37344E-02

3508.4
385.39
C6H6
0.22948
TOLUENE
0.72548E-01

K(I)

ASPEN PLUS
PAGE 7

PLAT: WIN32

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


STREAM SECTION
COOL FEED LIQ1 LIQ2 VAP1
-----------------------STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
PHASE:
VAPOR
COMPONENTS: LBMOL/HR
H2
404.2387
CH4
93.4770
C6H6
3.9353
TOLUENE
7.3168-02
TOTAL FLOW:
LBMOL/HR
501.7242
LB/HR
2628.6684
CUFT/HR
6098.2479
STATE VARIABLES:
TEMP
F
100.0000
PRES
PSI
500.0000
VFRAC
1.0000
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
5532.7110
BTU/LB
1056.0080
BTU/HR
2.7759+06
ENTROPY:
BTU/LBMOL-R
9.5890
BTU/LB-R
1.8302
DENSITY:
LBMOL/CUFT
8.2273-02
LB/CUFT
0.4311

COOL
COOL
FL1

FEED
---COOL

LIQ1
FL1
FL2

LIQ2
FL2
----

MIXED

VAPOR

LIQUID

LIQUID

405.0000

405.0000

0.7613

7.4310-03

95.0000

95.0000

1.5230

0.1254

95.0000

95.0000

91.0647

90.4644

5.0000

5.0000

4.9268

4.9165

600.0000

600.0000

98.2758

95.5137

1.0222+04

1.0222+04

7593.3236

7521.5381

6905.3980

1.7272+04

143.0732

140.1646

200.0000

1000.0000

100.0000

99.8295

550.0000

550.0000

500.0000

14.6959

0.8693

1.0000

0.0

0.0

0.1307
0.0

0.0
0.0

1.0000
0.0

1.0000
0.0

VAP1
FL1
----

0.0
0.0

284.0726

1.2268+04

2.0502+04

2.1330+04 -

16.6742

720.0899

265.3408

270.8683 -

1.7044+05

7.3608+06

2.0148+06

2.0373+06 -

-15.1700

-2.8811

-58.1491

-59.0416

-0.8904

-0.1691

-0.7526

-0.7498

8.6889-02

3.4739-02

0.6869

0.6814

1.4803

0.5918

53.0730

53.6622

AVG MW
5.2393
MIXED

17.0367

17.0367

77.2654

78.7483

MISSING

MISSING

MISSING

MISSING

1.4803

0.5918

53.0730

53.6622

SUBSTREAM PROPERTIES:

*** ALL PHASES


KVISC
SQFT/HR
MISSING
RHOMX
LB/CUFT
0.4311
ASPEN PLUS
PAGE 8

***

PLAT: WIN32

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


STREAM SECTION
VAP2
---STREAM ID
FROM :
TO
:

VAP2
FL2
----

SUBSTREAM: MIXED
PHASE:
VAPOR
COMPONENTS: LBMOL/HR
H2
0.7539
CH4
1.3976
C6H6
0.6003
TOLUENE
1.0315-02
TOTAL FLOW:
LBMOL/HR
2.7621
LB/HR
71.7855
CUFT/HR
1123.6274
STATE VARIABLES:
TEMP
F
99.8295
PRES
PSI
14.6959
VFRAC
1.0000
LFRAC
0.0
SFRAC
0.0
ENTHALPY:
BTU/LBMOL
-8155.8483
BTU/LB
-313.8164
BTU/HR
-2.2527+04
ENTROPY:
BTU/LBMOL-R
-15.5741
BTU/LB-R
-0.5993
DENSITY:
LBMOL/CUFT
2.4582-03
LB/CUFT
6.3887-02
AVG MW
25.9892
MIXED

SUBSTREAM PROPERTIES:

*** ALL PHASES


KVISC
SQFT/HR
RHOMX
LB/CUFT

***
MISSING
6.3887-02

ASPEN PLUS
PAGE 9

PLAT: WIN32

VER: 11.1

09/30/2003

SIMULACION DEL PROCESO DE SEPARACION DE BENCENO


PROBLEM STATUS SECTION
BLOCK STATUS
------------

*************************************************************************
***
*
*
* Calculations were completed normally
*
*
*
* All Unit Operation blocks were completed normally
*
*
*
* All streams were flashed normally
*
*
*
*************************************************************************
***