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Code no 56/1
2. The process of changing the colloidal particles in a sol into the insoluble
precipitate by addition of some suitable electrolytes is known as coagulation
process. (1)
(1)
5. Hexen-3-ol (1)
6.
(1)
7. In aqueous solutions, the increasing order of basic strengths is:
(CH3)2NH > CH3NH2 > (CH3)3N > NH3
(1)
Or
◦
MnO4-(aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O(l) E = +1.51V
◦
Sn4+ (aq) + 2e- → Sn2+ (aq) E = -0.15V
Anode-Oxidation reaction:
Sn2+ (aq) → Sn4+ (aq) + 2e-
Redox equation:
2MnO4-(aq) + 16H+(aq) + 5Sn2+ (aq) → 2Mn2+ (aq) + 8H2O(l) + 5Sn4+ (aq)
(1)
◦ ◦
Cell potential = E reduction - E oxidation (1/2)
= 1.51 - (-0.15)
= 1.66 V (1/2)
11.(i) In this method ,the impure metal acts as anode which undergoes
oxidation and pure metal acts as cathode which undergoes reduction. The
metal ions deposit on the cathode as metal. (1)
(ii) Vapour phase refining is based on the principle that metal is converted to
its volatile compound and collected which decomposes to give pure metal.
(1)
12.
(i) 2XeF2 + 2H2O → 2Xe + 4HF + O2 (1)
13.
(i) 2MnO4-(aq) + 5C2O42- (aq) + 16H+(aq)→ 2Mn2+ (aq) + 8H2O + 10CO2
(1)
14.
because is a
15. (i)
HI
(1)
(1 Mark)
16. Four bases in DNA are Adenine ,Guanine, Thymine and Cytosine
(1)
Sources Disease
A Carrots, butter Xerophthalmia
(1)
D Exposure to sunlight, Rickets
fish (1)
18.
Thermoplastic polymers Thermosetting polymers
Ans.19
k = 0.0051 min-1
[A0] = 0.10 M
t = 3 hours = 3× 60 min
k = 2.303 log [A0] (1)
t [A]
◦ + ◦ 2+
Since E Ag /Ag >E Cu /Cu
Ag Antilog(1.155)
Ag 0.0699M (1 )
22. (i) If an electrolyte is added to a hydrated ferric oxide sol , the colloidal
particles get precipitated (1)
(ii) Scattering of light takes place and the the path of the beam is
illuminated (1)
23. (i) The splitting of the degenerate d orbitals into eg and t2g orbitals due
to the presence of ligands in a definite geometry is called crystal field
splitting. (1)
(iii) Ligands which can bind the central metal atom through two different
atoms are called ambidentate ligands
Example: SCN ,NCS (1)
OR
[Co(NH3)6]3+
Cr(NH3 )6
3
Ni(CO)4
Ni - 3d8 4s2
24.(i) Hydrogen bonding in ethanol causes the boiling point of ethanol to be higher
(1)
26 (a)
(1)
(b)
(1)
(c)
(1)
27. (i) Non ionic detergents do not contain any ion in their constitution.
(1)
(ii) Van’t Hoff factor is the ratio of normal molar mass to the abnormal
molar mass. (1)
Van’t Hoff factor is the ratio of observed value of colligative property to
calculated value of colligative property assuming no association or
dissociation.
(b) Mass of protein = 100mg = 0.1 g
V= 10 mL
(1)
(1)
M = 13.98 g
Or
(a)
(i) All the properties which depend on the number of solute particles
irrespective of their nature relative to the total number of particles
present in the so solution are known as colligative properties. (1)
(ii) Molality of solution is the number of moles of solute present in 1
kilogram of solvent. (1)
(b)
pn2 KH x
XN2 (in air) 0.78
1000
nH2O 55.5mol (1)
18
Sincenn2 nH2O
nN2
xn2
nH2O
nN2 0.78 * 55.5 43.29 mol (1)
(1)
(ii) HClO4
(1)
(ii) Oxygen has a small size as compared to sulphur. So, the lone pairs on
oxygen repel each other. Thus, the O-O bond is weak whereas in case of
sulphur, the lone pair do not repel to the same extent.
As a result, S-S bond is stronger than O-O bond. So, S has a greater
tendency for catenation than oxygen. (1)
1
(iii) The net energy release for X (aq) is more negative for
X2 (g)
2
fluorine as compared to chlorine i.e. sum of dissociation energy, electron
gain enthalpy and hydration energy is more negative for fluorine. So, it a
stronger oxidising agent than chlorine. (1)
Or
(1)
(ii) HClO3
(1)
(b) (i) Because of partial double bond character of (N-O) bond. (1)
(ii) The axial bonds due to more repulsion are longer than
equatorial bonds. (1)
30. (a)
(i) Aldehydes which do not have an -hydrogen atom undergoes self
oxidation and reduction on treatment with concentrated alkali. (1)
(ii) Carboxylic acids having an -hydrogen are halogenated at the -
position on treatment with chlorine or bromine in the presence of
small amount of red phosphorus to give - halocarboxylic aids. (1)
Fehling’s test
CH3CH3CHO 2Cu2 5OH CH3CH2COO Cu2O 3H2O
Re d ppt
Propanone being a ketone will not give this test. (1)
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15
FeCl3 test
OR
(a)
(i)
(1)
(ii)
(1)
(b)
(1)
CrO3
CH3 CH2 CH2 CH2 OH CH3 CH2 CH2 COOH
C B
dehydration
(1)
CH3 CH2 CH2 CH2 OH
H2O
CH3 CH2 CH CH2
But 1 ene
(1)