Maureen Carolino

2012-59026
EXPERIMENT 6: SPECTROSCOPY
Part A. Determination of Concentration Range for Maximum Precision
Plot of Absorbance of KMnO4 against ppm (Parts per Million) of Manganese
0.25

0.2

0.15

0.1

0.05

0
0

10

X-axis ppm of Manganese

Y-axis Absorbance of KMnO4

12

14

16

18

Plot of Transmittance of KMnO4 against ppm (Parts per Million) of Manganese

120

100

80

60

40

20

0
0

10

20

30

40

X-axis - ppm of Manganese

Y-axis Transmittance of KMnO4

50

60

Maureen Carolino
2012-59026
EXPERIMENT 7: SPECTROPHOTOMETRIC DETERMINATION OF THE STOICHIOMETRIC OF A COMPLEX
Part A. Continuous Variation Method
Plot of Absorbance versus Mole Fraction of Iron (II)
0.14

0.12

0.1

0.08

0.06

0.04

0.02

0
0

0.000001

0.000002

0.000003

0.000004

X-axis Mole Fraction of Iron (II)

Y-axis Absorbance

0.000005

0.000006

Plot of Absorbance versus Mole Fraction of Iron

0.14
0.12
0.1
0.08
0.06
0.04
0.02
0
0

0.2

0.4

0.6

0.8

1.2

X-axis Mole Fraction of Iron

Y-axis Absorbance
Part B. Mole-Ratio Method
Plot of Absorbance versus (moles C12H8N2/moles Fe (II))
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
0

X-axis (moles C12H8N2/moles Fe (II))

Y-axis Absorbance

Part C. Slope-Ration Method

1. Constant amount of Fe (II)
Plot of Absorbance versus (C12H8N2)
0.25
0.2
0.15
0.1
0.05
0
0

0.00001

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

X-axis - (C12H8N2)
Y-axis Absorbance
2. (C12H8N2) is constant
Plot of Absorbance versus [Fe (II)]
0.25

0.2

0.15
Series1
0.1

0.05

0
0

0.000005 0.00001 0.000015 0.00002 0.000025 0.00003 0.000035 0.00004

X-axis [Fe (II)]

Y-axis Absorbance