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EXERCISE - I Q.1 How many 1carbon atom will be present in a simplest hydrocarbon having two 3 and one 2 carbon atom? (A) 3 (B) 4 (C) 5 (D) 6 How many carbons are in simplest alkyne having two side chains? (A) 5 (B) 6 (C) 7
Q.2
(D) 8
Q.3
Which of the following pairs have absence of carbocyclic ring in both compounds? (A) Pyridine, Benzene (B) Benzene, Cyclohexane (C) Cyclohexane, Furane (D) Furane, Pyridine The commercial name of trichloroethene is: (A) Westron (B) Perclene
Q.4
(C) Westrosol
(D) Orlone
Q.5
How many secondary carbon atoms does methyl cyclopropane have? (A) None (B) One (C) Two (D) Three The compound which has one isopropyl group is: (A) 2,2,3,3-Tetramethyl pentane (B) 2,2-Dimethyl pentane (C) 2,2,3-Trimethyl pentane (D) 2-Methyl pentane Which of the following is the first member of ester homologous series? (A) Ethyl ethanoate (B) Methyl ethanoate (C) Methyl methanoate (D) Ethyl methanoate The group of heterocylic compounds is: (A) Phenol, Furane (C) Thiophene, Phenol
Q.6
Q.7
Q.8
Q.9
and Number of secondary carbon atoms present in the above compounds are respectively: (A) 6,4,5 (B) 4,5,6 (C) 5,4,6 (D) 6,2,1
Q.10
A substance containing an equal number of primary, secondary and tertiary carbon atoms is: (A) Mesityl Oxide (B) Mesitylene (C) Maleic acid (D) Malonic acid The molecular formula of the first member of the family of alkenynes and its name is given by the set (A) C3H2, Alkene (B) C5H6, Pent-1-en-3-yne (C) C6H8, Hex-1-en-5-yne (D) C4H4, Butenyne
Q.11
[2]
Q.12
HC = CH (A) | HC = CH
(C)
(B)
HC = CH (D) | HC = CH
Q.13
CH 3 CH 3 | | The correct IUPAC name of the compound CH 3 - CH 2 - C = C - CH - C - CH 2 - CH 2 - CH 3 : | C2H5 (A) 5-Ethyl-3, 6-dimethyl non-3-ene (C) 4-Methyl-5, 7-diethyl oct-2-ene (B) 5-Ethyl-4, 7-dimethyl non-3-ene (D) 2,4-Ethyl-5-methyl oct-2-ene
Q.14
CH = CH - CHCH 2 CH 3 is: | CH 3
(B) 3-Methyl-5-cyclohexylpent-1-ene (D) 1-Cyclohexyl-3,4-dmethyl-but-1-ene
Q.15
IUPAC name of
is:
Q.16
Q.17
The IUPAC name of CH 3 CH 2 - N - CH 2CH 3 is: | CH 3 (A) N-Methyl-N-ethyl ethanamine (C) N-Ethyl-N-methyl ethanamine (B) Diethyl methanamine (D) Methyl diethyl ethanamine
Q.18
The IUPAC name of acetyl acetone is: (A) Pentane-2,5- dione (C) Hexane-2,4-dione
Q.19
When vinyl & allyl are joined each other, we get (A) Conjugated alkadiene (B) comulative alkadiene (C) Isolated alkadiene (D) Allenes
[3]
Q.20
(a)
and
(b)
True statement for the above compounds is: (A) (a) is phenol while (b) is alcohol (B) Both (a) and (b) are primary alcohol (C) (a) is primary and (b) is secondary alcohol (D) (a) is secondary and (b) is primary alcohol Q.21 The IUPAC name of the following structure (CH3)C.C.C.(CH3)CH(CH3) is: (A) 3-Methylhex-4-yn-2-ene (B) 3-Methylhex-2-en-4-yne (C) 4-Methylhex-4-en-4-yne (D) all are correct The IUPAC name of the following structure is [CH3CH(CH3)]2 C(CH2CH3)C(CH3) C(CH2CH3)2 (A) 3,5-Diethyl-4,6-dimethyl-5-[1-methylethyl]hept-3-ene (B) 3,5-Diethyl-5-isopropyl-4,6-dimethylhept-2-ene (C) 3,5-Diethyl-5-propyl-4,6-dimethylhept-3-ene (D) None of these The correct IUPAC name of CH 3 - CH 2 - C - COOH is: || CH 2 (A) 2-Methyl butanoic acid (C) 2-Carboxybutene Q.24 (B) 2-Ethylprop-2-enoic acid (D) None of the above
Q.22
Q.23
The correct IUPAC name of 2-ethylpent-3-yne is: CH 2 - CH - CH 2 (A) 3-Methyl hex-4-yne pent-2-yne |(B) 4-Ethyl | | (C) 4-methyl hex-2 yne (D) None of these OH OH OH The IUPAC name of the compound Glycerire is:
Q.25
All the following IUPAC names are correct except: (A) 1-Chloro-1-ethoxy propane (B) 1-Amino-1-ethoxypropane (C) 1-Ethoxy-2-propanol (D) 1-Ethoxy-1-propanamine The IUPAC name of the compound CH3CH = CHCH=CHCCCH3 is: (A)Octa-4,6-diene-2-yne (B)Octa-2,4-diene-6-yne (C) Oct-2-yne-4,6-diene (D) Oct-6-yne-2,4-diene C3H6Br2 can shows: (A) Two gem dibromide (C) Two tert. dibromo alkane
Q.27
Q.28
[4]
Q.29
As per IUPAC rules, which one of the following groups, will be regarded as the principal functional group? (A) CC (B) OH (C) - C || O (D)
Q.30
The IUPAC name of the compound Br(Cl) CI. CF3 is: (A) 2-Bromo-2-chloro-2-iodo1,1,1-trifluoroethane (B) 1,1,1-Trifluoro-2-bromo-2-chloro-2-iodo ethane (C) 2-Bromo-2-chloro-1,1,1-trifluoro-2-iodo ethane (D) 1-Bromo-1-chloro-2,2,2-trifloro-1-iodo ethane The IUPAC name of the given compound is:
Q.31
The IUPAC name of (C2H5)2 NCH 2CH.COOH is: | Cl (A) 2-Chloro-4-N-ethylpentanoic acid (C) 2-Chloro-2-oxo diethylamine (B) 2-Chloro-3-(N,N-diethyl amino)-propanoic acid (D) 2-Chloro-2-carboxy-N-ethyl ethane
- C3 -Ph H CH CHCH 2CH 2CHO || | | O Q.33 The IUPAC name of the compound is CH 3 - CH - CH -3NH 2 CH | CH 3
Which of the following compound is wrongly named? (A) CH 3CH 2CH 2CHCOOH ; | Cl (B) CH 3C CCHCOOH | CH 3 (D) ; 2-Chloro pentanoic acid
(C) CH3CH2CH=CHCOCH3 ; ;
[5]
Q.35
O = C - CH 2 - CH - CHO | | OH H - C = O
(A) 3,3-Diformylpropanoic acid (C) 3,3-Dioxo propanoic acid Q.36 The correct IUPAC name of compound: (B) 3-Formyl-4-oxo-butanoic acid (D) 3,3-Dicarbaldehyde propanoic acid
is: (A) 2-Cyano-3-oxopentanal (C) 2-Cyanopentane-1,3-dione Q.37 IUPAC name of: (B) 2-Formyl-3-oxopentanenitrile (D) 1,3-Dioxo-2-cyanopentane
(A) Methyl 2,2-bis(1-oxoethyl)ethanoate (B) 2,2 -Bis(1-oxoethyl)-1-methoxy ethanone (C) Methyl 2-Ethanoyl-3-oxobutanoate (D) Methyl 2-acetoxy-3-oxo butanoate
Q.38
Q.39
HO - C = O CH 3 | | The IUPAC name of compound CH 3 - C = C C - H is: | | NH 2 Cl (A) 2-Amino-3-chloro-2-methylpent-2-enoic acid (B) 3-Amino-4-chloro-2-methylpent-2-enoic acid (C) 4-Amino-3-chloro-2-methylpent-2-enoic acid (D) All of the above
[6]
Q.40
The IUPAC name of the structure is: H 2 N - CH - CH - CHO | | HOOC COOH (A) 3-Amino-2-formyl butane-1, 4-dioic acid (B) 3-Amino-2, 3-dicarboxy propanal (C) 2-Amino-3-formyl butane-1, 4-dioic acid (D) 1-Amino-2-formyl succinic acid
Q.41
One among the following is the correct IUPAC name of the compound
The number of primary, secondary and tertiary amines possible with the molecular fomula C3H9N is: (A) 1,2,2 (B) 1,2,1 (C) 2,1,1 (D) 3,0,1 The IUPAC name of C6H5CH=CHCOOH is: (A) Cinnamic acid (B) 1-Phenyl-2-carboxy ethane (C) 3-Phenyl prop-2-enoic acid (D) Dihydroxy-3-phenyl propionic acid The IUPAC name of BrCH 2 - CH - CO - CH 2 - CH 2CH 3 is: | CONH 2 HCH 2 CH 2 - CH || |(B) 1-Bromo-2-amino-3-oxohexane | (A) 2-Bromomethyl-3-oxohexanamide CH CH N - CHO CN 3 CN CN 2 (C) 1-Bromo-2-amino-n-propyl ketone (D) 3-Bromo-2-propyl propanamide IUPAC name will be
Q.43
Q.44
Q.45
Q.46
The IUPAC name of compound (A) 1,2,3-Tricarboxypropan-2-ol (B) 2-Hydroxy propane-1,2,3- tricarboxylic acid (C) 3-Hydroxy-3-carboxypentane-1,5-dioic acid (D) None
[7]
Q.47
The IUPAC name of CH 3 - C - O - CH 2 - C - OH is: || || O O (A) 1-Acetoxy acetic acid (C) 2-Ethanoyloxyacetic acid (B) 2-Acetoxy ethanoic acid (D) 2-Ethanoyloxyethanoic acid
Q.48
The correct IUPAC systematic name of the above compound is: (A) 2-Acetoxy ethanoic acid (B) 2-Methoxy carbonyl ethanoic acid (C) 3-Methoxy formyl ethanoic acid (D) 2-Methoxy formyl acetic acid
Q.49
Q.50
is:
(A) 2-Methoxy-4-nitro benzaldehyde (C) 3-Methoxy-4-formyl nitro benzene Q.51 The IUPAC name of compound
(A) -oic acid, chloro, hydroxy, oxo, methyl, hept-4-ene (B) -oic acid, chloro, hydroxy, methyl, oxo, hept-4-ene (C) -one, carboxy, chloro. methyl, hydroxy, hept-4-ene (D) -one, carboxy, chloro, methyl, hydroxy, hept-4-ene
[8]
Q.55
Q.56
O || C - CH3 is: (B) Methyl phenyl ketone (D) Phenyl methyl ketone
Q.57
(C)
(D)
Q.58
The IUPAC name of b-ethoxy-a-hydroxy propionic acid (trivial name) is: (A) 1,2-Dihydroxy-1-oxo-3-ethoxy propane (B) 1-Carboxy-2-ethoxy ethanol (C) 3-Ethoxy-2-hydroxy propanoic acid (D) All above
[9]
Q.59
Which of the following is not correctly matched: (A) Lactic acid CH 3 - CH - COOH | OH
(D) Iso-octane
Q.60 (A)
Column - I
(B)
(Q)
Anthracene
(C)
(R)
Azulene
(D)
[10]
EXERCISE - II Give the IUPAC names for each of the following : Q.10
Q.1
Q.11
Q.2
Q.12 Q.13
Q.5
Q.17
Q.6
Q.18
Q.7
Q.19
Q.8
Q.20
Q.9
Q.21
[11]
Q.22
Q.34
Q.24
Q.25
Q.37
Q.38 Q.26
Q.27
Q.39
Q.30
Q.41
[12]
Q.44 Q.51
Q.53 Q.47
Q.54 Q.48
Q.55 Q.49 O Cl || | CH 2 - C - CH 2 - CH - CH 3
Q.50
[13]
EXERCISE - III Q.1 The IUPAC name of the compound having the formula is:
CH 3 | H 3C - C - CH = CH 2 | CH 3
Write the IUPAC name of CH3CH2CH = CH COOH The IUPAC name of the compound CH2=CHCH(CH3)2 is: (A) 1,1-dimethyl-2-propene (B) 3-methyl-1-butene (C) 2-vinyl propane (D) None of the above The number of sigma and pi-bonds in 1-butene 3-yne are: (A) 5 sigma and 5 pi (B) 7 sigma and 3 pi (C) 8 sigma and 2 pi (D) 6 sigma and 4 pi Write I.U.P.A.C name of following: (a)
CH 3 | H 3C - N CH - CH 2CH 3 | | CH 3 C 2 H 5
Q.4
Q.5
Me = methyl group
[JEE 1990]
(b)
[JEE 1991]
Q.6 Q.7
Write IUPAC name of succinic acid. The IUPAC name of C6H5COCl is (A) Benzoyl chloride (C) Benzene carbonyl chloride The IUPAC name of the following compound is
CN Br HO
[JEE 1994]
Q.8
[14]
ANSWER KEY
EXERCISE - I Q.1 B Q.8 B Q.15 B Q.22 A Q.29 D Q.36 B Q.43 C Q.50 A Q.57 D Q.2 B Q.9 A Q.16 D Q.23 B Q.30 D Q.37 C Q.44 A Q.51 B Q.58 C Q.3 D Q.10 B Q.17 C Q.24 C Q.31 C Q.38 C Q.45 D Q.52 B Q.59 D Q.4 C Q.11 D Q.18 B Q.25 D Q.32 B Q.39 B Q.46 B Q.53 D Q.60 (A) Q, EXERCISE - II Q.1 CH 3 - CH 2 - CH - CH 2 - CH 2 - CH 2 - CH 3 | CH 2 - CH 2 - CH 3 4-Ethyl octane
CH 3 - CH - CH 3 3| 2 1 CH 3 - CH 2 - CH - CH - CH 3 | CH 3
5 4
C A C B B C D C (C) P ,
D A D B B C B C
C A B A B C B A
Isopropylidenecyclopentane or 1-methyl ethylidene cyclopentane 1-(3-butenyl) cyclopentene 1,2-diethenyl cyclohexene Bicylo(2.2.1)heptane 9-methyl bicyclo(4.2.1) nonane
Q.2
Q.15 2spiro 1 3 (2.5)4octane 5 CH 2 = C - CH 2 - CH - CH 3 Q.16 |spiro(4.5) decane | CH 3 - CH - CH 3 CH 3 Q.17 Bicyclo (1.1.0) butane Q.18 Q.19 Q.20 Bicyclo(4.4.0) decane Bicyclo(2.2.1) heptane
1 2 3
Q.5
CH 2 = CH - CH 2 - OCH 3 3-Methoxypropene
CH 2 = CH - C - CH 2 || | O OH 1-Hydroxybut-3-en-2-one
4 3 2 1
Q.21
CH 3 - CH = C - CH 2 - OH | CH 2 - CH 3 2-Ethylbut-2-en-1-ol
[15]
Ethyl cyclohexanecarboxylate 4-Bromo-2-ethyl cyclopentanone 3-(hydroxymethyl)-5-methylheptanal 2-Bromo-6-oxocyclohexanecarbaldehyde 5-amino-6(1-methylpropyl) cyclo-hex-2-enol 2-bromo-2-methyl cyclopentanone Methyl-2-methoxy-6-methyl-3- cyclohexene carboxylate 8-chloro bicyclo(4.2.0) oct-2-ene 2-cyclopenten-1-ol Ethyl-2-oxo-cyclo pentane carboxylate Cyclohexylidene methanone Bicyclo (3.1.0) hexane Cyclohex-2-en-1,4-dione 2-ethynyl cyclohexanol
4 3 2
Q.23
CH = CH - CH 2 | | NO 2 OH
3-nitroprop-2-en-1-ol
OH O | || CH 2 = CH - CH - C - C CH
6 5 4 3 2 1
Q.24
Q.26
2-Formyl pentane nitrile Q.27 Q.28 Q.29 Q.30 Q.31 Q.32 Q.33 Q.34 Q.35 2,2,6,7-tetramethylocatane 3-Ethyl-4,6-dimethyloctane 5 Methyl cyclohexa-1,3-diene 1,3-cyclobutadiene 1,2-epoxy propane 1,3,4-trimethyl-1-cyclobutene Cyclopropanecarboxylic acid Cyclopent-2-en-1-one 1-cyclohexyl-1-propanone
EXERCISE - III Q.1 Q.2 C CH 3 - CH 2 - CH = CH - COOH 5 4 3 2 1 2-pentene, 1-oic acid and or 2-pentenoic acid B Q.4 (a) 5,6-diethyl-3-methyl-dec-4-ene (b) N,N, 3-trimethyl-3-pentanamine Butane-1,4-dioic acid Q.7
Q.8
[16]