Gerak Gempur SPM Chemistry paper 3

3 4541/3 For Examiners Use

Answer all questions The time suggested to complete Question 1 and Question 2 is 45 minutes 1 A student carried out two experiments to determine the concentration of HX acid solution. Seorang pelajar menjalankan dua eksperimen untuk menentukan kepekatan larutan asid HX . Experiment I Eksperimen I Titration of HX acid solution of unknown concentration with 20cm 3 of sodium hydroxide solution 1.0 mol dm-3 using phenolftalein as indicator. Pentitratan larutan asid HX yang tidak diketahui kepekatannya dengan 20cm 3 larutan natrium hidroksida 1.0 mol dm-3 menggunakan penunjuk fenolftalein. Experiment II Eksperimen II Titration of similar HX acid solution of difference concentration with 20cm 3 of sodium hydroxide solution 1.0 mol dm-3 using phenolftalein as indicator. Pentitratan larutan asid HX lain yang tidak diketahui kepekatannya dengan 20cm 3 larutan Natrium Hidroksida 1.0 mol dm-3 menggunakan penunjuk fenolftalein. Diagram 1 shows the initial and final burette readings for both experiments. Rajah 1 menunjukkan bacaan awal dan bacaan akhir buret bagi kedua-dua eksperimen. Experiment 1 Eksperimen 1

20

1
Initial burette reading Bacaan awal buret

21

Final burette reading Bacaan akhir buret

4541/3

[Next page

Gerak Gempur SPM Chemistry paper 3 Experiment II Eksperimen II

4 4541/3 For Examiners Use

15

25

16

26

Initial burette reading Bacaan awal buret Diagram 1 Rajah 1

Final burette reading Bacaan akhir buret

(a) Construct a table to record the initial and final burette readings and the volumes of the acid used for both experiments. Bina jadual dan catat bacaan awal dan bacaan akhir buret serta isipadu asid yang digunakan bagi kedua-dua eksperimen di atas.

1(a) [ 3 marks]

(b) State the colour change of phenolftalein in the titration. Nyatakan perubahan warna fenolftalein dalam titratan tersebut. .. [ 3 marks]

1(b)

4541/3

[Next page

Gerak Gempur SPM Chemistry paper 3

5 4541/3

(c) The chemical equation for the reaction in the experiment is : Persamaan kimia bagi tindak balas dalam eksperimen ini ialah : HX + NaOH NaX + H 2O

For Examiners Use

Calculate the concentration of HX acid solutions used in both experiments. Hitung kepekatan larutan asid HX yang digunakan dalam kedua-dua eksperimen . Experiment I Eksperimen I

Experiment II Eksperimen II

1(c)

[ 3 marks]

(d) State the hypothesis in this experiment. Nyatakan hipotesis bagi eksperimen ini. .. .. [ 3 marks]

1(d)

4541/3

[Next page

Gerak Gempur SPM Chemistry paper 3

6 4541/3

(e) If HX acid is replaced with sulphuric acid of the same concentration, it is found that the volume of the sulphuric acid used in the titration is half of the volume of HX acid. Explain why. Jika asid HX digantikan dengan asid sulfurik yang mempunyai kepekatan yang sama, didapati isipadu asid sulfurik yang digunakan dalam titratan ialah separuh daripada isipadu asid HX. Terangkan mengapa. [ 3 marks]

For Examiners Use

1(e)

Total

Diagram 2 shows the apparatus set-up for an experiment to compare the heat of combustion of methanol and ethanol. 200 cm3 of water is used in this experiment. Rajah di bawah menunjukkan susunan radas bagi eksperiment untuk membandingkan Haba pembakaran antara metano dengan etanol. 200 cm3 air digunakan dalam ekperimen ini.

Thermometer Thermometer

Wind shield Penghadang Copper container Bekas kuprum Water Air Tripod stand Tungku kaki tiga Alcohol Alkohol Spirit lamp Pelita Wooden block Blok kayu

Diagram 2 Rajah 2

4541/3

[Next page

Gerak Gempur SPM Chemistry paper 3

7 4541/3

The table below shows the results obtained from the experiment I the heat of combustion of methanol and experiment II the heat of combustion of ethanol. Jadual di bawah menunjukkan keputusan eksperimen I haba pembakaran methanol dan eksperimen II haba pembakaran etanol. Experiment I Eksperimen I 25 20 15 Initial temperature of water: .................. Suhu awal air 65 60 55 Highest temperature of water: ........................... Suhu tertinggi air Experiment II Eksperimen II 25 20 15 Initial temperature of water: ......................... Suhu awal air 65 60 55 Highest temperature of water: .......................... Suhu tertinggi air

For Examiners Use

150.50 245 Initial mass of spirit lamp and methanol: .............g Jisim awal pelita dan metanol

151.35 Initial mass of spirit lamp and ethanol: ....... g Jisim awal pelita dan metanol

149.37 Final mass of spirit lamp and methanol: ......g Jisim akhir pelita dan metanol

150.50 Final mass of spirit lamp and ethanol: ............. g Jisim akhir pelita dan etanol

4541/3

[Next page

Gerak Gempur SPM Chemistry paper 3

8 4541/3 For Examiners Use 2(a)

(a) Write the readings of the temperature and the mass of spirit lamp and alcohol in the spaces above. Tuliskan bacaan suhu dan jisim pelita dan alkohol dalam ruangan di atas. [3 marks] (b) Based on the information above, complete the table below. Berdasarkan kepada maklumat di atas lengkapkan jadual di bawah. Name of variables Nama pemboleh ubah (i) Manipulated variable: Pemboleh ubah dimanipulaskan: ............ .................... ........... .................... (ii) Responding variable: Pemboleh ubah bergerak balas: .................... .................... (iii) Fixed variable: Pemboleh ubah yang dimalarkan: ... ... (iii) The way to maintain the controlled variable: Cara menetapkan pemboleh ubah dimalarkan : [3 marks] (c) (i) Calculate the energy change in the experiment I and II. Hitungkan perubahan tenaga dalam eksperimen I dan II [Given: Energy change = mc, specific heat capacity of water, c = 4.2 Jg-1oC] [Diberi: perubahan tenaga = mc, muatan haba tentu air, c = 4.2 Jg-1oC] (ii) What to observe in the responding variable: Apa yang diperhatikan bagi menentukan pemboleh ubah gerak balas: Action to be taken Tindakan yang dibuat (i) The way to manipulate variable: Cara mengubah pemboleh ubah dimanipulasi:

2(b)

2(c)(ii)

[3 marks]

4541/3

[Next page

Gerak Gempur SPM Chemistry paper 3

9 4541/3

(ii) Calculate the number of moles of methanol and ethanol burnt in this experiment. Hitungkan bilangan mol methanol dan etanol yang terbakar dalam eksperimen ini. [Molar mass of methanol = 32 g mol-1] [Molar mass of ethanol = 46 g mol-1] [Jisim molar metanol = 32 g mol-1] [Jisim molar etanol = 46 g mol-1]

For Examiners Use

2(c)(ii)

[3 marks] (iii) Calculate the heat of combustion of methanol in this experiment. Hitungkan haba pembakaran metanol dalam eksperimen ini.

2(c)(iii)

[3 marks] (d) Predict the heat of combustion of ethanol compare to the heat combustion of methanol. Ramalkan haba pembakaran etanol berbanding dengan haba pembakaran methanol. 2(d) [3 marks] Total

4541/3

[Next page

Gerak Gempur SPM Chemistry paper 3

10 4541/3

The further the distance between two metals in the electrochemical series, the bigger the potential difference. Semakin jauh kedudukan pasangan logam dalam siri elektrokimia, semakin besar nilai voltan. You are given the copper strip, lead strip, iron strip, zinc strip, aluminium strip, magnesium strip and copper(II) sulphate solution.Referring to the statement above, plan a laboratory experiment to construct the electrochemical series of the potential differences using different pair of metals. Your explanation should include all the followings: Anda dibekalkan dengan kepingan kuprum, kepingan plumbum, kepingan ferum, kepingan zink, kepingan aluminium, kepingan magnesium dan larutan kuprum(II) sulfat. Merujuk kepada situasi di atas, rancangkan satu eksperimen dalam makmal untuk membina siri elektrokimia . Penerangan anda hendaklah mengandungi perkara-perkara berikut: (a) Aim of the experment Tujuan eksperimen (b) All the variables Semua pemboleh ubah yang terlibat (c ) Statement of the hypothesis Pernyataan hipotesis (d) List of materials and apparatus Senarai bahan dan alat radas (e) Procedure of the experiment Prosedur eksperimen (f) Tabulation of data Penjadualan data [ 17 marks ]

END OF QUESTION PAPER

4541/3

[Next page