Chem 3 ICE PS Answer Key c!

e-γoT 2010
1.
[CO 2 ][CF 4 ] 0.2622
QC = 2
= 2
=3.26 K C =2.00QC =3.26
[COCF 2]  0.145
therefore reverse
M 2COF2 (g)  CO2(g) + CF4 (g) [CO 2 ] EQ [CF 4 ] EQ 0.0524−x 2
K C= = =2.00
I 0.0290 0.0524 0.0524 [COCF 2 ]2EQ 0.02902x 2
C -+2x -x -x 0.0524−x  0.0524−0.0290  2.00 −3
= 2.00 x= =2.97×10
E 0.0290 + 2x 0.0524 - x 0.0524 - x
0.02902x 12  2.00 
[CO 2]=[CF 4 ]=0.0524−x =0.0494 M
2. [COCF 2 ]=0.02902x=0.0349 M
n PCl5 (g)  PCl3(g) + Cl2 (g) at eqm PT = 1.0 atm KP = 3.60
 P PCl  P Cl 
I 0.200 3.00 0 K P= 3 2

P PCl
C -x +x +x 5

x 3.00x 
E 0.200 - x 3.00 + x x  1.0 atm 1.0 atm
3.20x 3.20x 
3.60=
0.200−x 
1.0 atm
3.20x 
4.6x2 13.8x−2.304=0 x=0.159 ,−3.16
3. P PCl =0.0123 atm P PCl =0.940 atm P Cl =0.0472 atm
5 3 2

n H2 (g) + I2 (g)  2HI (g) x=0.181−0.00748=0.174

I (1/2) (46/254) 0 n HI =2x=0.347 mole
C -x -x + 2x n H =0.500−x=0.326 mole
2

1.9
E 0.500 - x 0.181 – x = (1.9/254) 2x nI = =0.00748 mole
2
254
2x 2
 
[ HI ]2EQ V
K C= = =49.4
[ H 2 ] EQ [ I 2 ]EQ 0.500− x 0.00748
  
4. V V
n CO(g) + H2O (g)  CO2 (g) + H2 (g)  P CO  P H 
K P= 2 2

I 3.00 1.00 0 0  PCO  P H2O 

2
x
C -x -x +x +x  2.0 atm
4
E 3.00 - x 1.00 - x x x 0.63=
3.00−x  1.00−x 
2.0 atm 2.0 atm
at eqm PT = 2.0 atm KP = 0.63 4 4
x2
0.63=
5. 3.00−x 1.00−x 
2
[CO2] = {(0.28)(2.00 atm)}/(0.08206 x 1000) = 6.8 mM 0.37x 2.52x−1.89=0 x=0.68 ,−7.5
[CO] = {(0.72)(2.00 atm)}/(0.08206 x 1000) = 17.5 mM n =x=0.68 mole P =P = x 2.0 atm=0.34 atm
H CO H
2 2
4 2

2 2
KC = [CO] /[CO2] = (17.5e-3) /(6.8e-3) = 0.045 3.00− x
PCO = 2.0 atm=1.2 atm
4
1.00− x
P H2O = 2.0 atm=0.16 atm
4