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ATOMIC STRUCTURE IIT QUESTIONS Single answer type questions : 1.

Select the correct statement : 1) Orbital angular momentum is


h for the electron having n = 5 and lower value of the p

azimuthal quantum number 2) If n = 3, L = 0, m = 0 for the last valence shell electron, then the possible atomic number may be 12 or 13 3) Total spin of electrons for the atom (Z = 25) Mn is + 2.
7 5

3.

4.

4) Magnetic moment due to spin for nobel gas is zero Identify the correct statement(s) I) The radial probability distribution curves for 1s, 2s, 2p and 3d are identical II) The number of nodal planes for 2p, 3p and 4p orbitals is same III) Theoretically calculated spin only magnetic moment is same for Ti+2 and Ni+2 IV) A P orbital can accomodate a maximum of six electrons 1) I and II are correct 2) II and III are correct 3) III and IV are correct 4) Only IV is correct The magnetic moment of two ions Mx+ and My+ of the element M(z = 26) is found to be 5.916 BM. If x > y, then which of the following statement is correct 1) My+ is more stable than Mx+ 2) My+ is less stable than Mx+ 3) Both are equal stable 4) Cannot be predicted If l0 is threshold wavelength for photoelectric emission, l wavelength of light falling on the surface of metal, and m, mass of electron, then de Broglie wavelength of emitted electron is

h ( ll0 ) 2 1) 2mc ( l0 - l )
5.

h ( l0 - l ) 2 2) 2mcll0

h ( l - l0 ) 2 3) 2mcll0

hll0 2 4) 2mc

6. 7.

From the following observation of Mr. Gupta, Mr. Agarwal and Mr. Maheshwari predict the type of orbital Mr. Gupta : The angular function of the orbital intersect the three axes to origin only Mr. Agarwal : XY plane acts as a nodal plane Mr. Maheswari : The graph of radial probability v/s r intersects the radial axis at three separate regions points including origin 1) 5dyz 2) 4pz 3) 6dyz 4) 6dxy 2 2 The probability of finding the electron is maximum for dx - y orbital in 1) along x-axis only 2) along y-axis only 3) along x, y axes 4) between x, y axes Which one of the following statement is not correct 1) Rydbergs constant and wave number have same units 2) Lymon series of hydrogen spectrum occurs in UV region 3) The angular momentum of the electron into the ground state hydrogen atom is equal to
h 2

8.

4) The radius of first Bohr orbit of hydrogen atom is 2.11610-8 cm Which one of the following statement is correct 1) 2S orbital is spherical with two nodal planes 2) The debrogolic wavelength (l) of a particle of mass m and velocity v is equal to 3) The principal quantum number n indicates the shape of orbital
1 1 4) The electronic configuration of phosphorous is given by Ne 3S2 3p1 x py pz

mv h

9.

10.

What is true regarding the length of photographic film occupied by various series in hydrogen emission spectrum? (L1 : Length of Lyman series; L2 : Length of Balmer series; L3 : Length of Paschen series) 1) L1 = L2 = L3 2) L1 < L2 < L3 3) L1 < L2 > L3 4) L1 > L2 > L3 Photons having energy equivalent to binding energy of 4th state of He+ ion is used the metal surface of work function 1.4 eV. If electrons are further accelerated through the potential difference of 4 V then the minimum value of de-Broglies wavelength associated with the electron is 1) 1.1. A
o

2) 9.15 A

3) 5 A

4) 11 A

11.

If the angular momentum of an electron changes from

2h h to during a transition in a hydrogen atom, p p

12. 13.

14.

15. 16.

it results in the formation of spectral line is 1) mv region 2) visible region 3) IR region 4) Far IR region Proton, Alpha particles are accelerated with same potential. The de Broglie wavelength ratio is 1) 2 2 : 1 2) 1 : 2 2 3) 4 : 1 4) 1 : 4 + A stationary He ion emitted a photon corresponding to the first line of the Lymen series. The photon liberates a photo electron from a stationary hydrogen atom in ground state. The kinetic energy of electron is 1) 10.2 eV 2) 13.6 eV 3) 20.4 eV 4) 27.2 eV 0 The uncertainty in position is of the order of 1 A . The uncertainty in velocity of a cricket ball (0.1505 kg) is 1) 1.710-23 m/sec 2) 1.710-24 m/sec 3) 3.410-23 m/sec 4) 3.410-24 m/sec A standing wave in a string 35cm long has a total of six nodes including ends. Hence wave length is 1) 14 cm 2) 5.82 cm 3) 7 cm 4) 17.5 cm The m value for an electron in an atom is equal to the number of m values for l = 1. The electron may be present in 1) 3d x 2 - y2 2) 5f xyz 3) 2Px 4) 3 S

17.

An electron travels with velocity of v ms1. For a proton to have the same de-Broglie wavelength, the velocity will be approximately 1) v ms1 2) 1840 v ms1 3) v/1840 ms1 4) 1840/v ms1
0

18.

The dye Acriflavine, when dissolved in water, has its maximum light absorption at 4530 A and the
0

maximum fluorescence emission at 5080 A . The number of fluorescence quanta is, on the average 53% of the number of quanta absorbed. Using the wavelengths of maximum absorption and emission, what percentage of absorbed energy is emitted as fluorescence?

19.

20.

1) 100% 2) 47% 3) 36% 4) 12% A gaseous particle X has a proton (atomic) number n and a charge of +1. An another gaseous particle Y has a proton (atomic) number of (n + 1) and is isoelectronic with X. Which of the following statements correctly describe X and Y? 1) X has larger radius than Y 2) X requires more energy than Y when a further electron is removed from each particle 3) X releases more energy than Y when an electron is added to each particle 4) X and Y both has same electronegativity When an electron is transited from 2E to E energy level, the wavelength of photon produced is l1. If

electronic transition involves 4/3 E to E level, the wavelength of resultant photon is l2. Which of the following is a correct relation?
3 4 3) l2 = l1 4) l2 = l1 4 2 If a certain metal was irradiated by using two different light radiations of frequency x and 2x, the kinetic energies of the ejected electrons are y and 3y, respectively. The threshold frequency of the metal will be :

1) l2 = l1 21.

2) l2 = 3l1

22.

23.

24.

25.

x x 3x 2x 2) 3) 4) 3 2 2 3 During the excitation of an electron, it travels at a distance of nearly 0.795 nm in the hydrogen atom. The maximum no. of spectral lines formed during the de-excitation is 1) 1 2) 3 3) 6 4) 10 The ratio between the wave numbers of spectral lines of Balmer series of hydrogen having the least and the highest wavelength values is 1) 5 : 27 2) 27 : 5 3) 5 : 9 4) 9 : 5 The number of nodal planes, radial nodes and peaks in the radial probability curve of 5d orbital are respectively 1) 5, 2, 3 2) 4, 3, 2 3) 2, 3, 2 4) 2, 2, 3 nd The number of revolutions made by electron in Bohrs 2 orbit of hydrogen atom in one second is

1)

1) 6.55 1015 26.

2) 8.2 1014

3) 1.64 1015

4) 2.62 1016

When an excited state of H-atom emits a photon of wavelength l and returns to the ground state, the principal quantum number of excited state is given by 1)

(l R -1)
lR

2) l R (l R -1)

3)

lR (l R -1)

4) l R (l R +1)

27.

What is the maximum number of electrons in an atom that can have the following quantum numbers n = 4, m1 = +1? 1) 4 2) 15 3) 3 4) 6
1 The wave function (Y) of 2s is given by ( Y ) = 1 2s 2 2p a0
1/ 2

28.

r 2 a

e-r / 2 a 0 at r = r0, radial node 0

is formed. Thus for 2s, r0 in terms of a0 is 1) r0 = a0 29. 2) r0 = 2a0 3) r0 = a0/2 4) r0 = 4a0 Which of the following statements in relation of the hydrogen atom is correct? 1) 3s, 3p and 3d orbitals all have the same energy 2) 3s and 3p orbitals are of lower energy than 3d orbital

30.

31.

3) 3p orbital is lower in energy than 3d orbital 4) 3s orbital is lower in energy than 3p orbital Choose wrong statement 1) The shape of an atomic orbital depends upon azimuthal quantum number 2) The orientation of an atomic orbital depends upon the magnetic quantum number 3) The energy of an electron in an atomic orbital of multi-electron atom depends upon principal quantum number only 4) The number of degenerate atomic orbitals of one type depends upon the value of azimuthal and magnetic quantum number only The ground state electronic configurations of the elements, U, V, W, X and Y (the symbols do not have any chemical significance) are as follows U 1s22s22p3 V W X 1s22s22p63s1 1s22s22p63s23p2 1s22s22p63s23p63d54s2

Y 1s22s22p63s23p63d104s24p6 Determine which sequence of elements satisfy the following statements I) Element-forms a carbonate which is not decomposed by heating II) Element-is most likely to form coloured ionic compounds III) Element-has largest atomic radius IV) Element-forms only acidic oxide 1) V W Y U 2) V X Y W 3) V W Y X 32.

4) V X W U

If the quantum number are defined as follows : n = 1, 2, 3 ........ , l = 0, 1, 2, ...... (n + 1), m = l in integral steps to +l. How many electrons could be fitted in Ist shell 1) 2 2) 8 3) 10 4) 18 If electrons were to fill up progressively with orbit saturation (neglecting Auf Bau rule) and each orbital were to accommodate the three electrons, instead of two; which of the following would NOT hold correct for the new electronic arrangement in Zirconium atom (Z = 40)? 1) The number of p-electrons would be double the number of s-electrons 2) Spin quantum number would become super flows 3) Zirconium would continue to belong to the 4th period (in new periodic table) 4) Zirconium would show retention of block If the above radial probability curve indicates 2s orbital, the distance between the peak points x, y is

33.

34.

35.

1) 2.07 A 2) 1.59 A 3) 0.53 A 4) 2.12 A An electron is continuously accelerated in a vacuum tube by applying potential difference. If the de-Broglies wavelength is decreased by 10%, the change in the kinetic energy of electron is nearly 1) decreased by 11% 2) increased by 23.4% 3) increased by 10% 4) increased by 11.1% The angular momentum of electron in Li2+ was found to be (7h/11). The distance of the electron from nucleus is

36.

37.

38.

1) 1.69 A 2) 0.68 A 3) 2.82 A 4) 8.19 A The frequency n of certain line of the Lyman series of the atomic spectrum of hydrogen satisfies the following conditions I) It is the sum of the frequencies of another Lyman line and a Balmer line II) It is the sum of the frequencies of a certain line, a Balmer line and a Paschen line III) It is the sum of the frequencies of a Lyman and a Paschen line but no Brackett line To what transition does n correspond? 1) n2 = 3 to n1 = 1 2) n2 = 3 to n1 = 2 3) n2 = 2 to n1 = 1 4) n2 = 4 to n1 = 1 A hydrogen atom sample in the ground state is excited by monochromatic light radiation of wavelength l A . The resulting spectrum consists of maximum 15 different lines. What is l? (RH = 109677 cm1)
0

39. 40.

41.

1) 937.3 A 2) 1025 A 3) 1236 A 4) None of these The ratio between time periods taken by electron in Bohrs 2nd and 3rd orbits for each revolution is 1) 9 : 4 2) 4 : 9 3) 8 : 27 4) 27 : 8 th The velocity of an electron in n orbit of hydrogen atom bears the ratio 1 : 411 to the velocity of light. The number of coloured lines formed when electron jumps from (n+3) state to ground state. 1) 4 2) 3 3) 5 4) 6 The de-Broglie wave length (l) of electron is related to its accelerating potential (V) by the equation : 1) l( A0) = 12.27 12.27 150 150 2) l(nm) = 3) l( A0) = 4) l(nm) = V V V V Hydrogen-like ion has the wavelength difference between the first lines of Balmer and lymen series equal to 33.4 nm. The atomic number of that ion equal to 1) 4 2) 3 3) 2 4) 5 When a certain metal was irradiated with light of frequency 3.2 1016 Hz. The photo clectrons emitted has twice the kinetic energy as did photoelectrons emitted when the same metal was irradiated with light of frequency 2.5 1016 Hz. . The threshold frequency of the metal is ______ 1015 Hz. 1) 18 2) 20 3) 22 4) 16 What is the wavelength of the photon emitted by a hydrogen atom when an electron makes transition from n = 2 to n = 1. Given that ionization potential is 13.786 eV. Answer expressed in Angstrom units 1) 1200 2) 900 3) 800 4) 1000 The ratio of the energy of the electron in ground state of hydrogen to the electron in first excited state of Be3+ is 1) 1 : 4 2) 1 : 8 3) 1 : 16 4) 16 : 1 5 1 4 2 The configuration of Cr atom is 3d 4s but not 3d 4s due to reason R1 and the configuration of Cu atom is 3d10 4s1 but not 3d9 4s2 due to reason R2. R1 and R2 are 1) R1 : The exchange energy of 3d5 4s1 is greater than that of 3d4 4s2. R2 : The exchange energy of 3d10 4s1 is greater than that of 3d9 4s2. 2) R1 : 3d5 4s1 and 3d4 4s2 have same exchange energy but 3d5 4s1 is spherically symmetrical. R2 : 3d10 4s1 is also spherically symmetrical 3) R1 : 3d5 4s1 has greater exchange energy than 3d4 4s2. R2 : 3d10 4s1 has spherical symmetry. 4) R1 : 3d5 4s1 has greater energy than 3d4 4s2. R2 : 3d10 4s1 has greater energy than 3d9 4s2. M aximum value (n+l+m) for unpaired electrons in second excited state of chlorine 17Cl is 1) 28 2) 25 3) 20 4) none of these If r is the radius of first Bohrs orbit for hydrogen atom. The de Broglie wavelength in the nth orbit of hydrogen atom is given by

42.

43.

44.

45.

46.

47. 48.

49.

50.

51.

1) 2r n 2) 2r.n 3) 2r n 2 4) 2rn 2 When two electrons are present in two degenerate, orbitals of an atom, the energy is lower if their spin is parallel. The statement is based upon 1) Paulis exclusion principle 2) Aufbau principle 3) Hunds rule 4) Bohrs rule If the nitrogen atom had electronic configuration 1s7, it would have energy lower than that of the normal ground state configuration 1s2 2s2 2p3, because the electrons would be closer to the nucleus. et 1s7 is not observed because it violates. 1) Heisenberg uncertainly principle 2) Hunds rule 3) Pauli exclusion principle 4) Bohr postulate of stationary orbits If RH is the Rydberg constant, then the energy of an electron in the ground state of hydrogen atom is
hC 1 R HC 2) R 3) R Ch 4) - RH hC h H H When electronic transition occurs from higher energy state to a lower energy state with energy difference equal to DE eV. The wavelength of line emitted is approximately equal to

1) 52.

53. 54. 55.

12400 10-10 13397 1010 14322 10 -10 12387 1010 m m m cm 2) 3) 4) DE DE DE DE In Mosdeys equation given constants a = b = 1 then the frequency is 100 sec-1. The element will be 1) K 2) Na 3) Rb 4) Cs Which of the pair of orbitals have electronic density along the axis 1) 1) dxy dyz 2) d x 2 - y2 d z2 3) dx y dx z 4) d xy d z 2 If azimuthal quantum number could have value of n also in addition to normal value, then E.C of Cr(z = 24) would have been 1) 1s2 2s2 2p6 3s2 3p6 4s2 3d4 2) 1s2 2s2 2p6 3s2 3p6 4s1 3d5 2 6 2 6 2 6 3) 1s 1p 2s 2p 3s 2d 4) 1s2 1p6 2s2 2p6 2d6 In radial probability distribution curve of 2s orbital the distance between two peaks is 1) 0.53 2) 2.1 3) 1.1 4) 1.57 If n and l are respectively principal, Azimuthal quantum numbers, then the expression for calculating the total number of electrons in any energy level is
l =n-1

56. 57.

1) 58.

l =0

l =n

2(2 l +1)

2)

l =1

l =n-1

2(2l +1)

3)

l =1

2(2l +1)

4)

2(2l +1)
l =n l =0

59.

60.

61.

Consider following statements concerning the sub shells of (I) The maximum value of m for g sub shell is 4 (II) The maximum no. of unpaired electrons in g sub shell is 9 (III) The lowest value for the shell having of g sub shell is 5 Select correct statements 1) II, I only 2) II, III only 3) I, III only 4) I, II, III -1 If a 1 gm body is travelling along the X-axis at 100 cm sec within 1cm sec-1 then uncertainty in its position is 1) 2.64 10-30 m 2) 5.28 10 -30 m 3) 1.32 10 -30 m 4) 0.66 10-30 m The photoelectric emission requires a threshold frequency V0 for a certain metal l1=2000 and l2=1660 produce electrons with kinetic energy KE1 and KE2 of KE2 = 2KE1. The threshould requency V0 is 1) 1.15 1015 sec1 2) 1.15 1014 sec1 3) 1.19 1015 sec1 4) 1.19 1014 sec1 Calculate the wavelength emitted during the trastition of electrons in between two levels of Li+2 ion whose sum is 4 and difference is 2 1) 1.14106 cm 2) 1.14105 cm 3) 2.12106 cm 4) 2.14105 cm

62.

63.

64.

65.

66. 67.

A certain dye absorbs light of l =4700 and then fluorencene light of X. Assuming that 47 % of absorbed light is reemitted as fluorescence. The ratio of quanta emitted out to the number of quanta absorbed is 0.5. The value of X is 1) 4000 2) 5000 3) 5500 4) 6000 The bond dissociation of H-H bond is 400 KJ/mole. The energy required to excile 0.04 mole of Hydrogen gas to the first excisel state of hydrogen atom is 1) 94.6 KJ 2) 47.3 KJ 3) 70.9 KJ 4) 80.4 KJ The angular momentum of an electron in a Bohrs orbit of hydrogen atom is 4.217 1034 kg - m2/sec. The no. of specifed lines formed is visible region when electron fallls from this level is 1) 4 2) 3 3) 2 4) 6 What transition in the hydrogen spectrum would have the same wavelength as the transition n = 4, n =2 in He+ ion 1) 4 2 2) 3 1 3) 3 2 4) 2 1 If the radius of first Bohr orbit is X1 then deBroglie wavelength of electron is 3rd orbit is nearly : 1) 2 p x 2) 6 p x 3) 9x 4) x/3 The angular speed of the electron in nth orbit of Bohr hydrogen atoms is 1) Directly propertional to n 2) Inversly propertional of n 3) Inversly propertional to n2 4) Inversly propertional to n3 In hydrogen atom, the electronic motion is represented as follow. The number of revolutions made by that electron in one second is equal to 1) 6.5 1015 2) 2 1014 3) 2 1013 4) 1.01 1014

68.

69. 70.

The length of the minor axis corresponding to the elliptical path for which n = 4 and k = 2. 1) 8.464 A0 2) 16.92 A0 3) 2.116 A0 4) 4.23 A0 In which quantum level does the electron jumps in He+ ion to ground state if it is given an energy corresponding to 99% of the ionisation potential of He+ ion. 1) 4 2) 6 3) 8 4) 10 Which among the following is correct of 5B in normal state 1) 2) 3) 4) : Against Hunds rule : Against Aufbau principle as well as Hunds rule : Violation of Paulis exclusion principle and not Hunds rule : Against Aufbau principle

71.

72.

73. 74.

How many times does light travel faster in vaccum than an electron in Bohrs first orbit of hydrogen atom? 1) 13.7 times 2) 67 times 3) 137 times 4) 97 times When a hydrogen atom emitts a photon of energy 12.1 eV. The orbit angular momentum changes by 1) 1.05 10-34 J.sec 2) 2.11 10 -34 J.sec 3) 3.16 10 -34 J.sec 4) 4.22 10 -34 J.sec If kinetic energy of a particle is doubled; de Broglie wavelength becomes 1) 2 times 2) 4 times 3)

2 times

4) 1

2 times

75.

Imagine an atom made up of a proton and a hypothetical particle of double the mass of the electron but having the same charge as the electron. Apply the bohr atomic model and consider possible transitions of this hypothetical particle to the first excited level. The largest wavelength of photon that will be emitted has wavelength equal to (R is Rydberg constant) 1)
9 5R

2)

36 5R

3)

18 5R

4)

27 5R

76.

77.

When a certain metal was irradiated with light having a frequency of 3.0 1016 sec -1. The photo electrons emitted had twice the kinetic energy as did photoelectrons emitted when the same metal was irradiated with light having a frequency of 2.0 1016 sec -1. The threshold frequency of metal (in 1016 sec-1) is 1) 1 2) 2 3) 3 4) 4 Given ionisation potential of hydrogen atom is 2.0 10- 18 J Planks constant is 6.0 10- 34 J.sec. The frequency H line in Balmer series is in the values of (1012 Hz) is 1) 625 2) 840 3) 925 4) 520 The radius of the orbit in hydrogen atom is 0.8464nm. The velocity of electron in this orbit (in the order of 103 m/sec) is 1) 547 2) 637 3) 342 4) 832 2+ The calculated magnetic moment of Cr is 1) 1.73 BM 2) 2.8 BM 3) 4.8 BM 4) 5.9 BM 2+ The no. of d electrons in Fe is not equal to that of 1) p-electrons in Ne 2) s-electrons in Mg 3) p-electrons in Cl - 4) p-electrons in Mg De Broglie wavelength of the Bohr first orbit is . The circumference of the Bohr fourth orbit is 1) 4 2) 8 3) 16 4) 2 What hydrogen like ion has the wavelength difference between the first line of Balmer and Lymen series equal to 133 nm 1) He+ 2) Li+2 3) Be+3 4) 13+4 The shortest wavelength of hydrogen atom in Lyman series is X. The longest wavelength in Balmer series of He+ is
9x 36x x 5x 2) 3) 4) 5 5 4 9 Pick out the correct option. Where T stands for true. F stands for false. (a) The energy of the 3d orbital is high when compared to 4s orbital in hydrogen atom

78.

79. 80. 81. 82.

83.

1) 84.

(b) The electron density in xy plane in d x 2 - y2 orbital is zero (c) 24th electron in Cr goes to 3d orbital (d) The three quantum numbers were clearly explained in terms of schrodinger wave equation 1) TTFF 2) TFTT 3) TFTF 4) FFTT 0 The uncertainty in position is of the order fo 1 A . The uncertainty in velocity of a cricket ball (0.1505 kg) is 1) 1.7 10- 23 m/sec 2) 1.7 10- 24 m/sec 3) 3.4 10- 23 m/sec 4) 3.4 10- 24 m/sec The velocity of electron in a certain Bohr orbit of hydrogen atom bears the ratio 1 : 275 to the velocity of light. So the no. of orbit is 1) 1 2) 2 3) 3 4) 4 If there were three possibilities of electron spin, k(19) would be placed in 1) s block 2) p block 3) d block 4) f block

85.

86.

87.

88. Consider the following plots for 2sorbitals


x y z

r (I) (II)

r (III)

x,y and z are respectively, 1) Y, Y2 and 4pr2 drY2 2) Y2, Y and 4pr2 drY2 3) 4pr2 drY2 and Y2 and Y 4) Y2, 4pr2 drY2 and Y For a hypothetical H like atom which follows Bohrs model, some spectral lines were observed as shown. If it is known that line E belongs to the visible region, then the lines possibly belonging to ultra violet region will be (n1 is not necessarily ground state) [Assume for this atom, no spectral series shows overlaps with other series in the emission spectrum] 1) B and D 2) D only 3) C only 4) A only If any subshell, the maximum number of electrons having same value of spin quantum number is : 1) 91.

89.

90.

l (l +1)

2) l + 2

3) 2l + 1

4) 4l + 2

1 - r /a y = e 0 , the Given the wave function of an orbital of hydrogen atom; 1,0 3/2 pa 0
most probable distance of the electron present in the given orbital from the nucleus is A) a 0 .e -2r B) a 0 C) (3/2) a 0 D) 2a 0

92. Given the correct order of initials T(true) or F(false) for following statements. i) Maximum kinetic energy a photoelectron emitted from a metal [work function = 2eV] by a photon of wavelength 310 nm is 3.2 10-19 J. ii) The ratio of magnitude of Total Energy: Kinetic energy: Potential Energy for any orbitis 1 : 1 : 2 iii) Number of maximum for the curve 4 pr 2 R 2 (r) v/s r are three for the 5px orbital. iv) The ratio of de-broglie wavelength of a H atom, He atom and CH 4 molecule moving with equal kinetic energy is 4 : 2 : 1 A) FFTT B) TTFT C) TFTF D) FTTT

The difference nth and (n + 1)th Bohrs radius of H-atoms is equal to (n 1)th Bohrs radius. Hence the value of n is 1) 1 2) 2 3) 3 4) 4 Assertion (A) & Reason (R) type questions : 93. 1) Both A and R are true and R is correct explanation of A 2) Both A and R are true and R is not correct explanation of A

3) A is true, R is false 4) A is false, R is true 101. Assertion (A) : The wave functions of p-type (l = 1) with the same value of n but with different values of m will have the same radial distribution function Reason (R) : Radial distribution function depends only on the values of n and l and not on the value of m 102. Assertion(A) : According to Bohr IE2 of He is 54.4 ev/atom 2 Z eff Reason (R) : IE of atom is given by 13.6 2 ev/atom n 103. Assertion (A) : An electron can never be found in the nucleus Reason (R) : Velocity of the electron wave is less than the velocity of ligtht 104. Assertion (A) : No two electrons of an atom can have the same set of all four quantum numbers Reason (R) : An orbital can accommodate a maximum of two electrons 105. Assertion (A) : 3dxy, 4dxy, 5dxy ......... all are having the same shape i.e., the double dumb bell Reason (R) : The size of orbitals are independent of the principal quantum number eratio of anode rays is different for different gases m Reason (R) : Proton is the fundamental particle present in gases 107. Assertion (A) : Y2 measures the electron probability density at a point in an atom 106. Assertion (A) : Reason (R) : Y and Y2 vary as a function of the three co-ordinates r (radial part), q and f (angular part)

108. Assertion (A) : Twoorbitals withsamevalueofl but differentvalues of M l will havesame numberofangularnodes. Reason (R) : Angular wave function of an orbital depends upon its l and ml values 109. Assertion (A) : Aufbau principle is violated in writing electronic configuration of Pd Reason (R) : Pd is diamagnetic in nature 110. Assertion (A) : Spectral line would not be seen for a 2px-2py transition Reason (R) : P-orbitals are degenerate orbitals 111. Assertion (A) : Energy of orbitals on in hydrogen atom is 1s < 2s = 2p < 3s = 3p = 3d < 4s = 4p = 4d = 4f Reason (R) : The energy of orbitals in hydrogen atom is determined by using principal quantum number 112. Assertion (A) : Angular momentum of an electron in a orbit is quantized Reason (R) : The electron wave propagating around the nucleus remains in the same phase, 2pr = nl 113. Assertion (A) : Fine lines are observed in spectra if an atom is placed in a strong magnetic field. Reason (R) : Degenerate orbitals split in the presence of magnetic field. 114. Assertion (A) : Spin quantum number can have the value +1 2 or - 1 2 Reason (R) : (+) Sign here signifies the wave function. Assertion (A) : The transition of electrons n 3 n 2 in the atom will emit greater energy than n 4 n 3 Reason (R) : n3 and n2 are closer to nucleus than n4.

115.

Comprehensions type: I. Imagine a universe in which the four quantum numbers can have the same possible values as in our universe except the angular momentum quantum number l can have integral

values of 0, 1, 2 . n instead of 0, 1, 2 .. (n-1) and magnetic quantum number m can have integral values of (l+1) to 0 to (l+1) instead of l to 0 to +l. 121. Electronic configuration of the element with atomic number 25, based on the above assumption is 1) 1s2 1p6 2s2 1d10 2p5 2) 1s2 1p10 2s2 1d11 3) 1s3 1p9 2s3 2p9 3s1 4) 1s6 1p10 2s6 2p3 Based on above assumption magnetic moment of the element with atomic number 18 is 1) 24 BM 2) 8 BM 3) zero BM 4) 15 BM Based on assumption after completion of 3s orbital electron enters into _______ orbital 1) 3 p 2) 2 d 3) 4 s 4) 1 d

122. 123.

124.

-1 1 , 0, + based on the above assumption electronic configuration of 2 2 the element with atomic number 30 is 1) 1s3 2s3 2p9 3s3 3p9 4s3 2) 1s3 1p15 2s3 1d9 9 15 6 3) 1s 1p 2s 4) 1s3 1p9 2s3 2p9 1d6
If spin quantum numbers are Imagine an atom made up of a proton and a hypothetical particle of half the mass of the electron but having the same charge as the electron. Bohrs model is applicable and all transition of this hypothetical particle from higher level to ground state is possible.

II.

125.

The largest wavelength of photon that will be emitted when hypothetical particle jumps to first excited level is

126.

18 72 36 2) 3) 5R 5R 5R The velocity of this particle in second Bohr orbit is 1) 2.188106 m/sec 2) 1.094106 m/sec 3) 0.547106 m/sec
1) The radius of Third Bohr orbit is 1) 9.522 A0 2) 4.761 A0 3) 2.380 A0 The kinetic energy of the hypothetical particle in first orbit is 1) 6.8 eV 2) 6.8 eV 3) 27.2 eV

4)

8 R

4) 4.376106 m/sec

127. 128.

4) 1.587 A0 4) 27.2 eV

III.

A single electron atom has nuclear charge +Ze here Z is atomic number, e is charge. It requires 47.2 eV to excite the electron from second Bohr orbit to third Bohr orbit Atomic number of the element is 1) 2 2) 3 3) 4 4) 5 The wavelength required to remove electron from the first Bohr orbit in above data 1) 0.2210-7 cm 2) 1.010-7 cm 3) 5.610-7 cm 4) 3.710-7 cm The kinetic energy of electron in First Bohr orbit in above data 1) 1.96210-10 ergs 2) 3.4810-10 ergs 3) 0.87210-10 ergs 4) 5.4510-10 ergs A gas of identical H-like atom has some atoms in the lowest energy level A and some atoms in

129. 130. 131.

Passage - I:

a particular upper (excited) energy level B and there are no atoms in any other energy level. The atoms of the gas make transition to a higher energy level by absorbing monochromatic light of photon of energy 2.55 eV. Subsequently, the atoms emit radiation of only six different photon energies. Some of the emitted photons, have energy 2.55 eV. Some have more and some have less than 2.55 eV 132. The initially excited level B is 1) 2nd orbit 2) 3rd orbit 133. The ionisation energy of the gaseous atom is 1) 13.6 eV 2) 14.4 eV 134. The minimum energy of the emitted photon is 1) 2.7 eV 2) 2.0 eV Passage - II: In the photoelectric effect, an incoming photon brings a definite quantity of energy, hv. It collides with an electron close to the surface of the metal target, and transfers its energy to it. The difference between the work function, f, and the energy hv appears as the kinetic energy of the ejected electron. The minimum potential at which the plate photoelectric current becomes zero is called the stopping potential. If V0 is the stopping potential, then eV0 = h(v v0) 135. Light of wavelength 4000 A is incident on a metal whose work function is 2 eV. Then the maximum possible kinetic energy of the photoelectron is 1) 3.09 eV 2) 1.9 eV 3) 1.09 eV 4) None of these 136. The threshold frequency for emitting photoelectrons from a metal surface is 5 1014 s1. Which of the following could be the frequency of radiation to produce photoelectrons having twice the kinetic energy of those produced by the radiation of frequency 1015 sec1. 1) 2.15 1014 s1 2) 3.70 1013 s1 3) 4.11 1014 s1 4) 15 1014 s1 137. If one photon has 25 eV energy and the work function of the material is 7 eV, then value of the stopping potential will be 1) 32 V 2) 18 V 3) 3.3 V 4) Zero Passage I : According to Plancks quantum theory of radiation, the radiant energy is emitted or absorbed discontinuously in the form of quanta. The energy of a quantum is given by E = hv, where v is the frequency of radiation. Moreover, a body can emit or absorb energy only in an integral multiple of quantum. 138. Plancks quantum theory of radiation favours the following nature of electromagnetic radiation 1) Particle nature 2) Wave nature 3) Dual nature 4) None of these 139. The energy associated with one photon of wavelength 3000 A is 1) 5.42 1019 J 2) 6.63 1019 J 3) 3.73 1016 J 4) 3.73 1019 J 140. Which of the following is not the correct representation of Einsteins photoelectric equation? 1)
1 2 mv = h ( v + v0 ) 2 1 2 2) hv = hv0 + mv 2 1 2 3) hv = W + mv 2
0

3) 4th orbit 3) 27.2 eV 3) 0.66 eV

4) 5th orbit 4) 54.4 eV 4) 0.54 eV

4)

1 2 mv = h ( v - v0 ) 2

Passage II :

The properties of electrons indicate that they have a dual nature, i.e., they behave both as particle and as wave. de-Broglie suggested that every object which possesses mass and velocity behaves both as a particle and as a wave. According to de-Broglie, the wavelength l of a particle of mass m, moving with a velocity v is given by l = h/mv. The dual nature of electron further gets support by Heisenbergs uncertainty principle which states that it is not possible to determine simultaneously and accurately the position and momentum of a moving electron or some other microscopic particle.
h , where Dx and Dp respectively represent the uncertainties 4p involved in the simultaneous determination of position and momentum of a moving particle

According to Heisenberg, Dx Dp

144. The de-Broglie wavelength of a cricket ball of mass 0.2 kg moving with a velocity of 30 ms1 would be 1) 1.8 1034 m 2) 3.6 1032 m 3) 2.2 1034 m 4) 1.1 1034 m 145. An electron can be located with an error equal to 1010 m. What is the uncertainty in its momentum? 1) 5.28 1025 kg ms1 2) 5.5 1026 kg ms1 3) 3.34 1014 kg ms1 4) 6.63 1027 kg ms1 146. If the uncertainty in the position and momentum for an electron are equal, then the uncertainty in its velocity is 1)

h p

2)

h 2p

3)

1 h m 2p

4)

1 h 2m p

Passage I : In 1908, W. Ritz introduced his combination principle, which is virtually a generalization of Balmer formula. In its simplest form the principle states that the wave number of any spectral line may be represented as the combination of two terms, one of which is constant and the other variable through out each spectral series. R R - ; x and y integers for H-atom. The later on theories have modified the above x2 y2 principle as for H-atom.

n=

1 1 n = RH 2 - 2 n1 n2
RH is Rydberg number = 109,677.76 cm1 and n1 and n2 are lower and higher energy levels of the H-atom 147. What transition H-spectrum would have the same l as the Balmer transition n = 4 to n = 2 of He+ spectrum? 1) 2 1 2) 3 1 3) 4 1 4) 5 1 + 148. The wavelength of radiation of longest transition in Lyman series of He ion is 1) 22.8 nm 2) 32.2 nm 3) 40 nm 4) 48 nm

149. If the shortest l of H-atom in Balmer series is l1, the longest l in Lyman series is

1) 0.14 l1 2) 0.33 l1 3) 0.44 l1 4) 0.66 l1 Passage- I A hydrogen - like atom (atomic number z) is in a higher excited state of quantum numbe n. This excited atom can make a transition to the first excited state by successively emitting two photons of energies 10.2 eV and 17.00 eV respectively. Alternatively, the atom from the same excited state can make a transition to the second excited state by emitting two photons of energy 4.25 eV and 5.95 eV respectively. 150. The value of n is 1) 8 2) 6 3) 5 4) 4 151. The atomic number Z is 1) 1 2) 2 3) 3 4) 4 Passage - I: A formula analogous to the Rydberg formula applies to the series of spectral lines which arise from transitions from higher energy levels to the lower energy level of hydrogen atom. A muonic hydrogen ion is like a hydrogen atom in which the electron is replaced by a heavier partical the muon. The mass of the muon is 207 times the mass of an electron while charge the double that the electron (assume charge of proton is same) 152. Radius of first Bohr orbit of muonic hydrogen ion is
0.529 0 0.529 0 0.529 0 A A A 2) 3) 207 414 828 153. Ionization energy of muonic hydrogen ion is 1) 13.6 207 eV 2) 13.6 414 eV 3) 13.6 828 eV st rd 154. Distance between 1 and 3 Bohr orbit of muonic hydrogen ion wil be

1)

4) 0.529 828 A0 4) 13.6 3312 eV


0.529 8 A0 828

1)

0.529 8 A0 207

2)

0.529 8 A0 414

3)

0.529 5 A0 207

4)

One or more than one correct type questions : 160. Which of the followings can be concluded correctly from the solution of schrodinger equation ? 1) For all orbitals, the radial wave-function (y ) approaches to zero as r (distance from nucleus) approaches infinity. 2) The radial probability density (y 2 ) for 1s orbital is maximum at nucleus. 3) The radial distribution function 4p r 2 dr y 2 for 1s orbital is minimum at nucleus. 4) In plot of radial wave function (y ) ,y changes its sign at nodes. 161. When photons of energy 4.25 eV strike the surface of a metal A, the ejected photo electrons have maximum kenetic energy TA (expressed in eV) and de Broglie wavelength lA. The maximum kinetic energy of photo electrons liberated from another matal B by photons of energy 4.20 V is TB = TA 1.5 (expressed in eV). If the de Broglie wavelength of these photo electrons is

lB = 2lA then 1) Work function of A is 2.25 eV 3) TA = 2 eV

2) Work function of B is 4.20 eV 4) TB = 2.50 eV

162. In a photoelectric experiment, the stopping potential is plotted against

1 of incident radiation for two l different metals, the curve is like as shown in the fig. Predict which of the following statements are coorect :

1) Slope of the curves for both the metals is 1.242 106 Jm coulumb1 2) When an electromagnetic radiation of wavelength 100 nm strikes the two metals separately, the stopping potential for metal I is 12.18 V 3) The stopping potential for metal I is more than that of metal II, if both the metals are exposed to electromagnetic radiation of wavelength 200 nm seperately 4) The stopping potential for metal II is more than that of metal I, if both the metals are exposed to electromagnetic radiation of wavelength 200 nm seperately 163. Consider following statements and select the correct statements 1) Light waves were considered electromagnetic in nature 2) In vacuum, all types of electromagnetic radiation regardless of their wavelength, travel at the same speed, i.e., 3108 ms-1. 3) The ideal body which emits and absorbs all frequencies, is called a black body. 4) Quantum is also called photon. 164. Which of the following pairs have identical values of magnetic moment 1) Zn+2, Cu+ 2) Co+2, Ni+2 3) Mn4+, Co2+ 4) Mg+2, Sc+ 165. Which of the following statements are (is) correct 1) Electrons in motion behaves as if they were waves 2) s-orbital is non directional 3) An orbital can accommodate a maximum of two electrons with parallel spins 4) The energies of the various sub shells in the same shell are in the order s > p > d > f 166. The nucleus of an atom is located at x = y = z = 0. If the probability of finding an s orbital electron in a tiny volume around x = a, y = z = 0 is 1.0 105, choose the correct statement(s) regarding the probability of e 1) The probability of finding the electron in the same-sized volume around x = z = 0, y = a is the same i.e. 1 105 2) The probability of finding the electron in the same-sized volume around x = y = 0, z = a is zero 3) The probability at the second site if the electron were in a pz orbital is zero

4) The probability at the second site if the electron were in a pz orbital is the same i.e. 1.0 105. 167. Choose the correct statement(s) regarding Bohr-Sommerfelds model. 1) All paths around the nucleus are elliptical 2) When an electron revolves around the nucleus following circular path, only angle of rotation is changed 3) When an electron revolves around the nucleus following elliptical path, both the angle of rotation and the distance from the nucleus are changed 4) For an elliptical path, k < n
1 1 - , 0, + 168. If there were three possible values for the spin magnetic quantum number (ms). Which of 2 2 the following statement(s) is/are correct regarding a hypothetical periodic table based on this condition? 1) First period would have only 2 vertical columns 2) Second period would have 12 elements 3) Periodic table would contain 27 groups 4) Third period would have 12 elements

169. Select the wrong statements : 1) If the shortest wave length of H-atom in Lyman series is x, then the longest wave length in Balmer 9x series of He+ ion is 5 2) When an electron jumps from 4th excited state to ground state, maximum no. of protons that may be emitted are 4 3) Number of nodal planes and radial nodes in 5dx2 y2 orbital are 2 and 1 spectively 4) All four quantam number are obtained from Schrodinger wave equation even applied on atom 170. Choose the correct statement among the following : 1) Radial distribution function (Y2 4pr2) give probability at a particular distance along one chosen direction 2) xz plane acts as nodal plane for 3Px orbital 3) For s orbitals wave function is independent of q and f 4) 2p orbital with quantum numbers n = 2, l = 1, m = 0, also shows angular dependence 171. According to Bohrs theory, 1) When the atom gets the required energy from the outside, electrons jump from lower orbits to higher orbits and remain there 2) When the atom gets the required energy from outside, electrons jump from lower orbits to higher orbits and remain there for very short intervals of time and return back to the lower orbit, radiating energy 3) Angular momentum of the electron is proportional to its quantum number 4) Angular momentum of the electron is independent of its quantum number 172. Choose the correct statement(s) regarding the photoelectric effect 1) No electrons are ejected, regardless of the intensity of the radiation, unless the frequency equal and exceeds a thereshould value characteristic of the metal 2) The kinetic energy of the ejected electrons varies linearly with the frequency of the incident radiation and its intensity 3) Even at low intensities, electrons are ejected immediately if the frequency is above the threshold value 4) An intense and a weak beam of monochromatic radiations differ in having number of photons and not in the energy of photons

173. Mark out the correct statement(s) 1) Electrons within a subshell for which l > 0 mean the relatively greater electrostatic repulsion between two electrons in the same orbital within a subshell as compared with occupancy of two orbitals having different m1 values 2) Electrons in singly occupied orbitals tend to have their spins in the same directon so as to maximise the net magnetic moment 3) In the ground state, an atom adopts a configuration with the greatest number of unpaired electrons 4) Electrons in different orbitals with parallel spins show mutual attraction, so the electron-nucleus interaction is improved 174. Which of the following statements is/are correct? 1) For all values of n the p-orbitals have the same shape, but the overall size increases as n increases, for a given atom 2) The fact that there is a particular direction, along which each p-orbital has maximum e-density, plays an important role in determining molecular geometries 3) The charge cloud of a single electron in 2Px atomic orbital consists of two lobes of e-density 4) The very fact that an e is present in both the lobes at equal times, and the fact that in order to move from one lobe to another, it MUST cross the node, implies, there is at least some probability of finding an e in the node 175. In a hydrogen like sample electron is in 2nd excited state, the Binding energy of 4th state of this sample is 13.6 eV then 1) A 24.17 eV photon can set free the electron from the second excited state of this sample 2) 3 different types of photon will be observed if electrons make transition up to ground state from the second excited state 3) If 23 eV photon is used then K.E of the ejected electron is 1 eV 4) 2nd line of Balmer series of this sample has same energy value as 1st excitaation energy of H-atoms 176. Identify the correct statement(s) among the following : 1) If Aufbau rule is not followed then chromium will still remain in d-block 2) If there are three possible values for spin quantum numbers then chromium would have been lying in s-block 3) If Hunds rule of maximum multiplicity is not followed then magnetic moment of chromium would be zero 4) If Hunds rule of maximum multiplicity is not followed then Cr3+ (aq) ion would be colourless 177. The energy of an electron in the first Bohr orbit of H-atom 13.6 eV; then which of the following statement(s) is/are correct for He+? 1) The energy of electron in second Bohr orbit is 13.6 eV 2) The K.E of electron in the first orbit is 54.46 ev 3) The K.E of electron in secondary orbit is 13.6 ev 4) The speed of electron in the second orbit is 2.19 106 m/sec Matching type questions : 181. Match the following Type I (A) Distance of maximum probability of 1s electron (B) Radial node of 2s electron is (C) Radius of 2nd orbit in He+ ion is (D) Radius of 3rd orbit in Li+2 ion is

Type II (p) (q) (r) (s) 1.1 A0 1.06 A0 1.59 A0 0.53 A0

182.

List I a) Emission spectrum b) Absorption spectrum c) Band spectrum d) Line spectrum

List II p) Cold nitrogen gas q) Excited atomic hydrogen r) Very hot carbon dioxide s) Neon gas at room temperature List II p) Principal Q.N. q) Azimthal Q.N. r) Magnetic Q.N s) Spin Q.N. List II (Factors affecting the energy) p) Principal quantum numer q) Azimuthal quantum number r) Exchange energy s) Symmetry Column II p) principal quantum number q) Azimuthal quantum number r) Magnetic quantum number s) Spin quantum number

183. Match the following : List I a) Magnetic moment of an atom or ion b) Radial node c) Hunds rule d) Orbital angular momentum of electron 184. Match the following List I with List II List I (Species) a) Hydrogen atom b) Nitrogen atom c) Li2+ ion d) Helium atom 185. Column I a) Magnetic movement b) splitting of spectral lines in magnetic field c) number of spherical nodes d) fine line spectra

186. n orbit no; z at no; rn, z radius Vn, z velocity; Tn, z Time period of revolution Kn, z kinetic energy of the electron Column I (of single electron species) a) r2, 1 : r1, 2 b) V1, 3 : V3, 1 c) T1, 2 : T2, 1 d) K1, 2 : K2, 1 List I a) Orbital angular momentum of the electron in a hydrogenlike atomic orbital b) A hydrogen-like one-electron wave function obeying Pauli principle c) Shape, size and orientation of hydrogen-like atomic orbitals d) Probability density of electron at the nucleus in hydrogen-like atom 188. Column - I (Quantum numbers) A) n p) 9 : 1 q) 8 : 1 r) 16 : 1 s) 1 : 32 Column II (ratio)

187. Match the entries in Column I with the correctly related quantum number(s) in Column II. List II p) Principal qunatum number q) Azimuthal qunatum number r) Magnetic quantum number s) Electron spin quantum number

Column - II (Relation) p) Stark effect

B) l C) m D) s

q) Schrodinger's equation r) Bohr's atomic model s) Pauli's exclusivity t) Auf Bau sequencing

189. 190. Numericals: 191. In which quantum level does the electron jumps in He+ ion to ground state if it is given an energy corresponding to 99% of the ionization potential of He+ ion. 192. When a certain metal was irradiated with light having a frequency of 3.01016 sec-1. The photo electrons emitted had twice the kinetic energy as did photoelectrons emitted when the same metal was irradiated with light having a frequency of 2.01016 sec-1. The threshold frequency of metal (in 1016 sec-1) is Given ionization potential of hydrogen atom is 2.010-18 J Planks constant is 6.010-34 J.sec. The frequency Hb line in Balmer series is in the values of (1012 Hz) is The radius of the orbit in hydrogen atom is 0.8464 nm. The velocity of electron in this orbit (in the order of 103 m/sec) is

193.

194.

195. The velocity of electron is a certain Bohrs orbit of hydrogen atom bears in the ratio 1 : 275 to the velocity of light. The qunatum number (n) of orbit is 196. The wave length of a line in Balmer series of hydrogen atom is 4814 A . In which orbit deexitation takes place 197. The debroglie wave length of an electron in a certain orbit of hydrogen atom is 13.3 A . So the no. of waves present in an orbit is 198. 199. 200. 201. Give the number of angular node of orbital belongs to subshell for which minimum value of magnetic quatum number is 2. What will be the number of lines corresponding to lymen series when an electron is in 3rd excited state of hydrogen atom. In a single hydrogen atom, the electron is excited to its 6th orbit. The maximum no.of distinct lines possible, when it comes to the ground state is : 1 For the hydrogen atom, En = 2 RH n 18 Where, RH = 2.178 x 10 J Assuming that the electrons in other shells exert no effect, find the minimum no.of Z(atomic no.) at which a transition from the second energy level to the first results in the emission of an Xray. Given that the lowest energy rays have l = 4 10-8 m .
0 0

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