Tutorial for Chemistry of Hydrocarbons

1)Write the 5 different isomers of hexane and name them by IUPAC system 2) Pre are butane from chloroethane usin! Wurt" and Corey#House synthesis $)What are all the ossible or!anic roducts in the follo%in! reaction CH& ' Cl2 U( li!ht

&)Assi!n )*+ confi!urations to each of the follo%in! al,enesi) CH$ C/C H iii) .r C/C CH22H CH2CH2CH$ H CH0CH$)2 i1) CH$ H C / C CH2CH$ C22H CH2CH$ ii) CH2.r C/C CH2CH$ CH2Cl CH$

5) )x lain %hy 2#butene and not 1#butene is the ma3or roduct %hen %ater molecule is eliminated from 2#butanol 4))x lain 5ar,o1ni,o1 and antimar,o1in,o1 rule each %ith an exam le 6).riefly ex lain the olymeri"ation reaction of al,ynes 7))x lain .ayer8s 9train theory %ith a ro riate exam les :)Com lete the follo%in! reaction mentionin! all the ste s and intermediates in1ol1ed; i)CH$#CH/CH2 ' CH2I2 ii)=iethyl adi ate iii) 2 >a Cu#+n < <

+n#H!*HCl >H2>H2*?2H

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1@)Write short notes on the follo%in!i)Ariedel craft8s al,ylation ii)Ariedel craft8s acylation 11)Com lete the follo%in! oxidation reactionsi) .en"ene ii)Toluene iii).en"ene '2$ (225*&5@C al,;?5n2& +nB H22

12)=ifferentiate bet%een aromaticB non aromatic and anti aromatic com ounds 1$)Classify the follo%in! as CIB 'I B #5B '5 effect !rou s .rB IB ClB #CH$B #CH$CH2B C/2B C>B >22 1&))x lain the rinci le of fractional distillation and %rite the 1arious roducts obtained at different tem erature ran!es durin! the distillation of crude oil; 15; =ifferentiate terminal and central al,ynes; 14; =iscuss the addition of halo!ens on al,enes; 16; Why do al,anes under!o free radical substitution reactions< 17; Con1ert 0i) Acetylene into mesitylene; 0ii) )thane into ben"ene; 0iii) Pro yne to 2#hexyne; 0i1) 5alonic ester to cyclohexane; 1:; Pre are 1B2#dimethylcyclobutane by all the ossible methods; 2@; What are cycloaddition reactions< Classify them alon! %ith exam les; 21; Denenrate sulfur trioxide for electro hilic substitution reactions; 22; =ifferentiate aromaticB antiaromatic and non#aromatic com ounds alon! %ith exam les; 2$; )x lainB nitrobe"ene but not ben"ene can act as a sol1ent in electro hilic substitution reactions;

2&; Arran!e the follo%in! com ounds in the increasin! order of reacti1ity to%ards electro hilic substittution reactions- C4H52HB C4H52CH$B C4H4B C4H5>22B C4H5CH$;