Acidic Powers & Their Orders (Chemistry Fact Sheet- 1)

Acidic power 1.

Order

Why ?

2.

Farther the (I) group (Cl), lesser III < II < I the acidic strength Farther the (+I) I < II < III group, greater the acidic power C 3 is electron donating and II < I < III !"2 is electron attracting

3.

#.

C 3 is electron repelling$ II < I < III decreases acidic strength o% phenol

&.

"C 3 group contains +' e%%ect III < I < II and decreases acidic poer.

(.

-.

!"2 is electron attracting$ III is )ore resonance sta*ilised than I I < II < III and also than II. In I, onl+ inducti,e e%%ect is operati,e. I . II . III sp2 h+*ridised car*on o% I, II are )ore el/ ectronegati,e hence acid strength is inc/ reased. 0en1+lic (C( &C 2) is )ore sta*/ilised than all+lic

(C 222C C 2).

3.

5%%ect o% one C"" on the other decr/eases I . II . III . as its distance I4 *etween the) increases, (C"" )2 is )a6i)u) acidic. !"2 is electron II < III < I attracting (I e%%ect) " shows electron withdrawing nature at o / and m / and electron repelling at p /, o III < II < I / iso)er due to intra)olecular *onding in salic+late ion is stronger than m / iso)er III < II < I do I < III < II ! 2 is electron donating.

7.

18.

11. 12.