ID NAME 2 ETHANE 17 n-HEPTANE THE DEFAULT Kij MATRIX IS 2 17 17 .

0000 BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 245.69 P(MPa)= 1.000 ID LIQUID X VAPOR Y 2 .8870 .9999 17 .1130 .0001 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 260.51 P(MPa)= 1.500 ID LIQUID X VAPOR Y 2 .8870 .9998 17 .1130 .0002 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 272.22 P(MPa)= 2.000 ID LIQUID X VAPOR Y 2 .8870 .9996 17 .1130 .0004 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 282.11 P(MPa)= 2.500 ID LIQUID X VAPOR Y 2 .8870 .9992 17 .1130 .0008 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 290.82 P(MPa)= 3.000 ID LIQUID X VAPOR Y 2 .8870 .9985 17 .1130 .0015 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 298.70 P(MPa)= 3.500 ID LIQUID X VAPOR Y 2 .8870 .9975 17 .1130 .0025

Tc(K) 305.4200 540.2600

Pc(MPa) 4.8801 2.7358

WAS:

24 ID NO. IS 2 ID NO. IS 17 ZL= .3391E-01 ZV= .8414 Yi/Xi 1.127 .6719E-03 WAS: 6 ID NO. IS 2 ID NO. IS 17 ZL= .5032E-01 ZV= .7891 Yi/Xi 1.127 .1821E-02 WAS: 6 ID NO. IS 2 ID NO. IS 17 ZL= .6703E-01 ZV= .7425 Yi/Xi 1.127 .3930E-02 WAS: 6 ID NO. IS 2 ID NO. IS 17 ZL= .8422E-01 ZV= .6999 Yi/Xi 1.126 .7487E-02 WAS: 6 ID NO. IS ID NO. IS ZL= .1020 Yi/Xi 1.126 .1318E-01 WAS: 5 ID NO. IS ID NO. IS ZL= .1205 Yi/Xi 1.125 .2200E-01 2 17 ZV= .6604

2 17 ZV= .6238

REQUIRED NUMBER OF ITERATIONS WAS: 6 COMPONENT IS ETHANE ID NO. IS COMPONENT IS n-HEPTANE ID NO. IS T(K)= 306.01 P(MPa)= 4.000 ZL= .1399

2 17 ZV= .5899

ID 2 17

LIQUID X .8870 .1130

VAPOR Y .9960 .0040

Yi/Xi 1.123 .3528E-01 WAS: 7 ID NO. IS ID NO. IS ZL= .1602 Yi/Xi 1.120 .5486E-01 WAS: 9 ID NO. IS ID NO. IS ZL= .1690 Yi/Xi 1.000 .9986 2 17 ZV= .5586

REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 312.91 P(MPa)= 4.500 ID LIQUID X VAPOR Y 2 .8870 .9938 17 .1130 .0062 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 301.27 P(MPa)= 5.000 ID LIQUID X VAPOR Y 2 .8870 .8872 17 .1130 .1128

2 17 ZV= .1690

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL LIQUID WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 298.87 P(MPa)= 5.000 ID LIQUID X VAPOR Y 2 .8870 .8874 17 .1130 .1126 WAS: 6 ID NO. IS ID NO. IS ZL= .1681 Yi/Xi 1.000 .9966

2 17 ZV= .1680

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL LIQUID WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 314.26 P(MPa)= 5.500 ID LIQUID X VAPOR Y 2 .8870 .8873 17 .1130 .1127 WAS: 10 ID NO. IS ID NO. IS ZL= .1920 Yi/Xi 1.000 .9974

2 17 ZV= .1921

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL LIQUID WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 320.17 P(MPa)= 6.000 ID LIQUID X VAPOR Y 2 .8870 .8870 17 .1130 .1130 WAS: 13 ID NO. IS ID NO. IS ZL= .2123 Yi/Xi 1.000 .9997

2 17 ZV= .2123

WARNING - CHECK ANSWERS CAREFULLY

ERROR-ALL LIQUID WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 325.25 P(MPa)= 6.500 ID LIQUID X VAPOR Y 2 .8870 .8871 17 .1130 .1129 WAS: 13 ID NO. IS ID NO. IS ZL= .2324 Yi/Xi 1.000 .9995

2 17 ZV= .2324

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL LIQUID WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 329.94 P(MPa)= 7.000 ID LIQUID X VAPOR Y 2 .8870 .8871 17 .1130 .1129 WAS: 13 ID NO. IS ID NO. IS ZL= .2525 Yi/Xi 1.000 .9993

2 17 ZV= .2525

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL LIQUID WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 342.43 P(MPa)= 9.000 ID LIQUID X VAPOR Y 2 .8870 .8875 17 .1130 .1125 WAS: 9 ID NO. IS ID NO. IS ZL= .3243 Yi/Xi 1.001 .9954

2 17 ZV= .3246

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL VAPOR WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 342.56 P(MPa)= 8.500 ID LIQUID X VAPOR Y 2 .8870 .8872 17 .1130 .1128 WAS: 12 ID NO. IS ID NO. IS ZL= .3121 Yi/Xi 1.000 .9986

2 17 ZV= .3122

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL VAPOR WARNING-ROOTS CLOSE IN Z OR X,Y DT REQUIRED NUMBER OF ITERATIONS WAS: 7 COMPONENT IS ETHANE ID NO. IS COMPONENT IS n-HEPTANE ID NO. IS T(K)= 435.03 P(MPa)= 5.000 ZL= .7981

2 17 ZV= .8028

ID 2 17

LIQUID X .8859 .1141

VAPOR Y .8870 .1130

Yi/Xi 1.001 .9902

WARNING - CHECK ANSWERS CAREFULLY ERROR-ALL VAPOR WARNING-ROOTS CLOSE IN Z OR X,Y BT REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 312.99 P(MPa)= 4.500 ID LIQUID X VAPOR Y 2 .8862 .9938 17 .1138 .0062 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 312.90 P(MPa)= 4.500 ID LIQUID X VAPOR Y 2 .8871 .9938 17 .1129 .0062 REQUIRED NUMBER OF ITERATIONS COMPONENT IS ETHANE COMPONENT IS n-HEPTANE T(K)= 290.81 P(MPa)= 3.000 ID LIQUID X VAPOR Y 2 .8871 .9985 17 .1129 .0015 WAS: 7 ID NO. IS ID NO. IS ZL= .1602 Yi/Xi 1.121 .5474E-01 WAS: 6 ID NO. IS ID NO. IS ZL= .1602 Yi/Xi 1.120 .5487E-01 WAS: 7 ID NO. IS ID NO. IS ZL= .1020 Yi/Xi 1.126 .1318E-01

2 17 ZV= .5592

2 17 ZV= .5585

2 17 ZV= .6604

DT REQUIRED NUMBER OF ITERATIONS WAS: 6 COMPONENT IS ETHANE ID NO. IS