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ents. Molecules with hydrocarbon chain (hydrophilic) and (hydrophobic). Clean effectively in soft water. Reduce the surface tension of water.(act as wetting agent) Act as emulsifying agent. Soap Differences Molecular structure Yes No No No Form scum in hard water. Scum consist of magnesium stearate and calcium stearate. Mg2+ + 2C17H35COO- (C17H35COO-)2Mg
Stearate ion (soap ion) Magnesium stearate(scum)
Detergent
No Yes Yes Yes Do not form scum in hard water. 2R-O-SO3- + Mg2+ (R-O-SO3)2Mg
Magnesium alkyl sulphate (dissolves in water because Ionic bond between head and Mg is very weak)
Made from natural resources (animal fats or vegetable oils) Form precipitate in acidic water
Made from synthetic resources (petroleum fractions) Do not form precipitate in acidic water