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SIMILARITIES BETWEEN SOAP AND DETERGENT. Both are cleansing agents.

ents. Molecules with hydrocarbon chain (hydrophilic) and (hydrophobic). Clean effectively in soft water. Reduce the surface tension of water.(act as wetting agent) Act as emulsifying agent. Soap Differences Molecular structure Yes No No No Form scum in hard water. Scum consist of magnesium stearate and calcium stearate. Mg2+ + 2C17H35COO- (C17H35COO-)2Mg
Stearate ion (soap ion) Magnesium stearate(scum)

Detergent

Biodegradable Cause pollution Effective in acidic water Effective in hard water

No Yes Yes Yes Do not form scum in hard water. 2R-O-SO3- + Mg2+ (R-O-SO3)2Mg

Ca2+ + 2C17H35COO- (C17H35COO-)2Ca


Stearate ion (soap ion) Calcium stearate (scum)

Formation of scum in hard water

Alkyl sulphate ion (detergent)

Magnesium alkyl sulphate (dissolves in water because Ionic bond between head and Mg is very weak)

Made from natural resources (animal fats or vegetable oils) Form precipitate in acidic water

Sources Formation of precipitate

Made from synthetic resources (petroleum fractions) Do not form precipitate in acidic water

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