CHE 254 Homework 11 -Chapter 4 4.39 ‘Acetylene is hydrogenated to form ethane. The feed to the reactor contains 1.50 mol H /mol C,H. a) Calculate the stoichiometric reactant ratio (mol H, react/mol CzH reac) and the yield ratio {kmol Cz He formed/kmol Hl, react). b) Determine the limiting reactant and calculate the percentage by which the other reactant is in excess. c) Calculate the mass feed rate of hydrogen (kg/s) required to produce 4+ 10® metric tons of ethane per year, assuming thatthe reaction goes to completion and tha the process operates for 24 hours a day, 300 days a year. 4) Theres a definite drawback to running with one reactant in excess rather than feeding reactants instlchiometic proportion, What is it? (Hint: In the process of part (c, what does the reactor effluent consist of and what wil probably have tobe done before the product ethane canbe sold or used] O5c0 gllarked alerts Hz ZL eg WON Aacts pet bit, reek) Ar tevet) OS ME OM pwd Ant My teacles 0) Me ae Me Cetnili, paneled . (0 trcei- CoMy Bb by lee papa) acted O) The pencleg ofllunt CO) Cenletva 4 tite GH, Thee worntel te an _erkin toe! ausmrmted gf Pepe oss fn Hee Pla be the qeedadt —ahucen th, cul ane af tal 0 ‘Tom Bertalan, Chris Barnes, Yang He, James Robinson CHE@TomBertalan.comcHE 254 | 2 Homework 11 - Chapter 4 4.47 (a-c) At low to moderate pressures, the equilibrium state of the water-gas shift reaction CO + H0 + CO, + Hy is approximately described by the relation YeosVite 4020) 7eoa7be — (7) = 0.0247 ex la Yeodiina where Tis the reactor temperature, K, is the equilibrium constant, and ysis thie mole fraction of the species i in the reactor contents at equilibrium. Thefeed to a batch shift reactyor contains 20.0 mole% CO, 10.0% CO, 40.0% water, and the balance an inert gas. The reactor is maintained at T = 1123. 2) Assume a basis of 1 mol feed and draw and label a flowchart. Carry out a degree-of-freedom analysis of the cerca bated on etads of esa a ov Efe eave avo fave ech terion ola tho convenes Uhre ecibae aecietete a cen b) Clouse te otalmoler af gt inthe ear teu tales you more than seconds yore ising the point} and then the equilibrium mole fraction of hydrogen in the product. (Suggestion: Begin by writing exersins or the moles ofeach sees nthe prod gas terms he eve of en nd han wre Saieato the ws inle taetons} is iisipest ex cae crest apical ane ST hydrogen sant ferent fom the edafsed ve surg hat a ellen mistakes Measurement errors have been made, what is a likely explanation for the discrepancy between the calculated ee eee eer Cea gies het, for ten k,) @) We ol lorkee) O) wW ‘Tom Bertalan, Chris Barnes, Yang He, James Robinson CHE@TomBertalan.comSheet (e Ghas Feanes Ca + 2lle —> CoH, Ime! be! Ton nb Yay Me Dawes fa bien GO) Arnall Hy grere / 108) CMa sere ©) Hale We pnt / tebe Me gem? — = ty, HHesn, 8 2205 Lge Boing gaaslct | DT smeoe Cyl = 10 nl Gly — OB rl C, OB al Cote peer Heol \ Cleve | D.00 ey He, Bo.0 byl, | [malty FU level tte 7 % rew'n KIery%s Ih} bee bey Boots | lowe, Ce) Heb ta Gt] In je) u Bood | 24h REET n>] vac, (on guahel vbat-] emma GO) Me calor fle.CO + HO=Co,+ He % £ is Shent Pe © toy 1) ©.20 wal CO/ne! ty (mst Co) 0.16 Pro! (clea! he Cet 4,6) Ge %0 wa! Hy fin! ts (wk Coz) O39 yest ZL Lyat Ky Cre i Hy Comb 2) Gh) DoF Ameysrs 6 uk (M2, §) 6 =H foucbm ngl@) 74 - Tome -) wel, Kolm ) Dor OD Bhp pratt) = bps errr) OS te = Bgsorens 000+E We = 6.50 Kea BU fyy * KIN = G2 (o.lo+8)(£) = (o.208-€) (ule) x + xe O=6,070B6445e a 43 cre )| te Tees Pain, = (te08) CE) ) (0.00 ~$) 6202 47 exp (4? Arg ) Le =|0,020) - 0.box +x4eo.ces20203 ~GLANGSH AS x ON GE TE KE & A > x = See °. 10 (When ee) =Iy [fr patat) © qernted gheet || eeeCbun Crewe Tn Cettelan Gola Lebinen Jun He Meersprent W 90 Schuh G04 Che 054-20! Teta Ferien