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SULIT
4541/3
Chemistry
Paper 3
September
2009
1½ hours
CHEMISTRY
Paper 3
Total 50
This question booklet contains 12 printed pages including the front page.
SULIT 2 4541/3
For
Examiner’s 1 Diagram 1.1 shows the apparatus set-up for an experiment to measure the
Use
potential difference between copper,Cu and metal M. The experiment is repeated
by replacing metal M with metals J and Q. The results are used to determine the
position of metals M, J, Q and copper,Cu in the Electrochemical Series.
Rajah 1.1 menunjukkan susunan radas bagi eksperimen untuk mengukur beza keupayaan
antara kuprum,Cu dan logam M. Eksperimen ini diulangi secara menggantikan logam M
dengan logam J dan Q. Keputusan yang diperolehi digunakan untuk menentukan
kedudukan logam M, J, Q dan kuprum,Cu di dalam Siri Elektrokimia.
V
Copper, Cu
Kuprum Metal M
Logam M
Diagram 1.1
Rajah 1.1
Diagram 1.2 shows the voltmeter readings for three pairs of metals; Cu/M, Cu/J
and Cu/Q respectively.
Rajah 1.2 menunjukkan bacaan voltmeter bagi tiga pasangan logam; Cu/M, Cu/J dan
Cu/Q.
Diagram 1.2
Rajah 1.2
For
Pairs of metal Potential difference Positive terminal Examiner’s
Pasangan logam Beza keupayaan / (V) Terminal positif Use
Cu and M
Cu
Cu dan M
Cu and J
Cu
Cu dan J
Cu and Q
Q
Cu dan Q
Table 1
Jadual 1
1 (a)
(a) Record the voltmeter reading for the pairs of metal in Table 1.
Rekodkan bacaan voltmeter bagi pasangan-pasangan logam tersebut dalam
Jadual 1.
[3 marks]
[3 markah]
(c) Iron is located between metal M and copper in the Electrochemical Series.
Classify the metals into groups of more electropositive and less
electropositive metals than iron.
Logam ferum terletak antara logam M dan logam kuprum dalam Siri
Elektrokimia. Kelaskan logam-logam ini ke dalam kumpulan logam yang lebih
elektropositif dan kurang elektropositif daripada ferum.
More electropositive metals than iron Less electropositive metals than iron
Logam yang lebih elektropositif Logam yang kurang elektropositif
berbanding ferum berbanding ferum
1 (c)
[3 marks]
[3 markah]
For
Examiner’s (d) Diagram 1.2 shows a simple cell using copper and metal J.
Use Rajah 1.2 menunjukkan sel kimia ringkas menggunakan kuprum dan logam J.
Diagram 1.2
Rajah 1.2
1. ………………………………………………………………
1(d)(i)
2. ………………………………………………………………
3. ………………………………………………………………
[3 marks]
[3 markah]
(ii) What would you observe at metal J if the cell is allowed to stand
for 6 hours?
Apakah yang anda akan perhatikan pada logam J jika sel ini di biarkan
1(d)(ii) selama 6 jam?
……………………………………………………………………...
……………………………………………………………………...
[3 marks]
[3 markah]
For
2 Two experiments are carried out to determine the relationship between the pH value Examiner’s
and the concentration of two alkaline solutions. The pH values of three different Use
concentrations of sodium hydroxide and ammonia solutions are recorded using pH
meter.
Dua eksperimen dijalankan untuk menentukan hubungan antara nilai pH dengan kepekatan
bagi dua larutan alkali. Nilai pH bagi tiga kepekatan berbeza larutan natrium hidroksida
dan ammonia telah direkodkan menggunakan meter pH.
Sodium
hydroxide
Natrium
hidroksida
I
Ammonia
II
Ammonia
Diagram 2
Rajah 2
……………………………… ……………………………………….
………………….……………………
Table 2.1
Jadual 2.1 [3 marks]
[3 markah]
(b) Construct a table and record the results for Experiment I and II in the space
provided below.
Berdasarkan eksperimen ini, bina jadual dan rekodkan keputusan Eksperimen I dan II
pada ruangan di bawah.
2(b)
[3 marks]
[3 markah]
For
Examiner’s
(c) Based on the answer in Table 2.1, state the relationship between the concentration Use
of OH- ions and the pH value.
Berdasarkan keputusan eksperimen dalam Jadual 2.1, nyatakan hubungan antara
kepekatan ion OH- dengan nilai pH.
………………………………………………………………………………………
2(c)
………………………………………………………………………………………
[3 marks]
[3 markah]
(d) Ammonia solution of 0.1 mol dm-3 has different pH value compared to sodium
hydroxide solution of the same concentration.
Explain why?
Larutan ammonia 0.1 mol dm-3 mempunyai nilai pH yang berbeza dibandingkan dengan
larutan natrium hidroksida yang sama kepekatannya.
Terangkan mengapa.
………………………………………………………………………………………
………………………………………………………………………………………
2(d)
………………………………………………………………………………………
[3 marks]
[3 markah]
(e) Sodium hydroxide solution is a strong alkali while ammonia solution is a weak
alkali. State the operational definition for the strong alkali and weak alkali.
Larutan natrium hidroksida adalah alkali kuat manakala larutan ammonia adalah alkali
lemah. Nyatakan definisi secara operasi bagi alkali kuat dan alkali lemah.
……………………………………………………………………………………… 2(e)
………………………………………………………………………………………
[3 marks]
[3 markah]
(f) A sodium hydroxide solution has pH value of 9. Estimate the concentration of the
solution.
Suatu larutan natrium hidroksida mempunyai nilai pH 9. Anggarkan kepekatan larutan
tersebut.
2(f)
………………………………………………………………………………………
………………………………………………………………………………………
[3 marks]
[3 markah]
3 Diagram 3 shows a reaction between dilute acid and metal in Test tube I and
For Test tube II.
Examiner’s Rajah 3 menunjukkan tindak balas antara asid cair dan logam dalam Tabung uji I dan
Use Tabung uji II.
Diagram 3
Rajah 3
The time taken for the reaction in Test tube II to complete is shorter than in Test
tube I.
Identify the factor that influences the difference in the observation between Test
tube I and Test tube II.
Masa yang diambil untuk tindak balas selesai bagi Tabung uji II adalah lebih pendek
berbanding Tabung uji I.
Tentukan faktor yang mempengaruhi perbezaan pemerhatian antara Tabung uji I dan
Tabung uji II.
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2. Write your answers for Question 1 and 2 in the spaces provided in the question
paper.
Tuliskan jawapan bagi Soalan 1 dan 2 dalam ruang yang disediakan dalam kertas
soalan.
3. Write your answers for Question 3 on the lined pages at the end of the question
paper in detail.
Tuliskan jawapan bagi Soalan 3 pada halaman bergaris di bahagian akhir kertas soalan
ini dengan terperinci.
5. If you wish to cancel any answer, neatly cross out the answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu
6. The diagrams in the questions are not drawn to scale unless stated.
Rajah yang terdapat dalam soalan tidak dilukis mengikut skala kecuali dinyatakan
sebaliknya.
7. Marks allocated for each question or part of the question is shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam
kurungan.
10. Hand in all your answer sheets at the end of the examination.
Serahkan semua kertas jawapan anda di akhir peperiksaan.