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Methanol Losses in Vapor Phase

Pressure = 600 psia

100

Gal/MMSCF

10

0.1

0.01
-100

-90

-80

-70

-60

-50

-40

-30

-20

-10

10

20

30

40

50

60

70

80

90

100

110

Temperature, F

8/15/2014
RAJ

Methanol

T R

T,F

559.7
534.7
509.7
484.7
459.7
434.7
409.7
384.7
359.7

100
75
50
25
0
-25
-50
-75
-100

Vapor Pressure
psi
4.6397
2.32415
1.07997
0.46006
0.17713
0.06058
0.01801
0.00453
0.00093

310.944
297.056
283.167
269.278
255.389
241.5
227.611
213.722
199.833

0.3934
0.42049
0.44759
0.47468
0.50178
0.52887
0.55597
0.58306
0.61016

pvp,bars
0.31989
0.16024
0.07446
0.03172
0.01221
0.00418
0.00124
0.00031
6.4E-05

Vapor Pressure of Methanol

Vapor Pressure, psi

10
1
0.1
0.01
0.001
0.0001
-110-100-90 -80 -70 -60 -50 -40 -30 -20 -10 0 10 20 30 40 50 60 70 80 90 100 110
Temperature, F

Page 2

gal/MMSCF
98.7944
49.4887
22.9962
9.79627
3.77171
1.28988
0.38352
0.09652
0.01987

Methanol

gal/MMSCF

Page 3

MEG Heat Capacity

0.95

0.9

0.85

Cp, BTU/Lb-F

0.8

0.75

0.7

0.65
40 wt %

0.6

60 wt%
80 wt%
100 wt %

0.55

0.5
60

70

80

90

100

110

120

130

140

150

160

170

180

190

200

210

220

230

240

241342152.xls.ms_office
8/15/2014
RAJ

MEG

F
60
80
100
120
140
160
180
200
220
240

100 wt%
0.563
0.576
0.59
0.604
0.618
0.632
0.646
0.66
0.674
0.688

80
0.66
0.673
0.685
0.697
0.71
0.722
0.735
0.748
0.761
0.774

75

70

Heat Capacity of Glycol


65
62.5

0.7085
0.721
0.7325
0.7445
0.7565
0.768
0.78
0.7925
0.805
0.8175

Page 5

0.744875
0.757
0.768125
0.780125
0.791375
0.8025
0.81375
0.825875
0.838
0.850125

60
0.757
0.769
0.78
0.792
0.803
0.814
0.825
0.837
0.849
0.861

55

50
0.806
0.8165
0.826
0.836
0.8455
0.855
0.865
0.8755
0.8855
0.8955

MEG

45

40

20

10

0.855
0.864
0.872
0.88
0.888
0.896
0.905
0.914
0.922
0.93

0.94
0.942
0.944
0.946
0.948
0.95
0.952
0.954
0.956
0.958

0.976
0.977
0.978
0.979
0.98
0.981
0.982
0.982
0.983
0.984

Page 6

MEG

62.5 wt% MEG ( 60 volume %)

0.86
0.85
0.84
0.83
0.82
0.81
0.80
0.79
0.78
0.77
0.76
0.75
0.74
0.73
0

50

100

150

Page 7

200

250

300

Activity Coeffiecient For Water In TEG


1

0.8

0.6

Rosman
Parrish

0.4

Scauzilla

0.2

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

Mole Fraction Water

\John M Campbel\241342152.xls.ms_office

TEG Activity Coef


g
Scauzilla
0.99999
0.95
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0.0001
0.1938
0.4191
0.6102
0.2961
0.503
0.6386

80

1
0.998178
0.992644
0.970185
0.932556
0.880459
0.815397
0.739639
0.65611
0.568201
0.47951
0.470735
0.461992
0.453283
0.444611
0.43598
0.427394
0.418854
0.410365
0.40193
0.393634

Rosman

Parrish

1
0.940761
0.860819
0.746941
0.679061
0.635583
0.605683
0.58396
0.567503
0.554619
0.544269
0.543344
0.542438
0.541549
0.540677
0.539822
0.538982
0.538158
0.537349
0.536554
0.535782

Page 9

1
0.998946
0.982705
0.902035
0.834846
0.785482
0.744431
0.706633
0.669756
0.632784
0.595358
0.591587
0.587813
0.584033
0.580249
0.576461
0.572669
0.568873
0.565073
0.561269
0.557501
0.630478
0.713734
0.790015
0.66832
0.745598
0.803136

Parrish

t,F

a
b
c
80 0.054015 0.269801 0.314559

Viscosity of Dehydrating Liquids


1000

Viscosity, cp

100

TEG
MEG

10

Methanol

0.1
0

50

100

150

200

250

Temp, F

300

350

400

450

TEG Viscosity

a
TEG
MEG
MeOH

b
c
d
-13.8883 3.06E+03 2.05E-02 -1.05E-05
-7.811 3.14E+03
0
0
-3.94E+01 4.83E+03 1.09E-01 -1.13E-04

Page 11

-17.74
-12.19
-6.63
-1.07
4.48
10.04
15.59
21.15
26.70
32.26
37.81
43.37
48.93
54.48
60.04
65.59
71.15
76.70
82.26
87.81
93.37
98.93
104.48
110.04
115.59
121.15
126.70
132.26
137.81
143.37
148.93
154.48
160.04
165.59
171.15
176.70
182.26
187.81
193.37
198.93
204.48

TEG
Temp,K Temp,F Visc,cp
255.3889
0 466.0316
260.9444
10 313.9885
266.5
20 216.4782
272.0556
30 152.4979
277.6111
40 109.6133
283.1667
50 80.28945
288.7222
60 59.86038
294.2778
70 45.37683
299.8333
80 34.9386
305.3889
90 27.29909
310.9444
100 21.6265
316.5
110 17.35679
322.0556
120 14.10173
327.6111
130 11.59021
333.1667
140 9.630374
338.7222
150 8.084679
344.2778
160 6.853347
349.8333
170 5.86315
355.3889
180 5.059763
360.9444
190 4.402467
366.5
200 3.860444
372.0556
210 3.410149
377.6111
220 3.033436
383.1667
230
2.7162
388.7222
240 2.447392
394.2778
250 2.218289
399.8333
260 2.021953
405.3889
270 1.85283
410.9444
280 1.706443
416.5
290 1.579158
422.0556
300 1.468013
427.6111
310 1.370573
433.1667
320 1.284831
438.7222
330 1.20912
444.2778
340 1.142049
449.8333
350 1.082453
455.3889
360 1.029352
460.9444
370 0.981914
466.5
380 0.939435
472.0556
390 0.901312
477.6111
400 0.867029

TEG Viscosity

Page 12

TEG Viscosity

MEG
89.63284
68.9726
53.65749
42.1733
33.46811
26.80183
21.64762
17.62618
14.4615
11.95077
9.943459
8.326887
7.015948
5.945839
5.066838
4.340501
3.736899
3.232572
2.809013
2.451527
2.148385
1.890163
1.669256
1.479489
1.315827
1.174142
1.051035
0.943696
0.849792
0.767374
0.694813
0.630739
0.573996
0.523607
0.47874
0.438688
0.402844
0.370689
0.341778
0.315724
0.292195

Meoh
1.057919
0.938666
0.84107
0.760272
0.692646
0.63545
0.586582
0.544417
0.50768
0.475366
0.446671
0.420949
0.397677
0.37643
0.356858
0.338676
0.321647
0.30558
0.290316
0.275725
0.261705
0.248173
0.235064
0.222331
0.209938
0.197862
0.18609
0.174617
0.163444
0.152578
0.142032
0.131819
0.121956
0.11246
0.103348
0.094637
0.086341
0.078473
0.071044
0.064059
0.057524

Page 13

TEG Viscosity

1000

Viscosity, cp

100

10

0.1

Page 14

TEG Viscosity

Page 15

TEG Viscosity

Viscosity of Dehydrating Liquids

1000

100

TEG
MEG

10

Methanol

0.1
-25.00

25.00

75.00

125.00

Temp, C

Page 16

175.00

225.00

TEG Viscosity

Page 17

TEG Viscosity

Page 18

Vapor Pressure
of Glycols and Methanol
1000

EG
Water

Methanol

DEG

100

TEG

Vapor Pressure, MMHG

10

0.1

0.01

0.001

0.0001

0.00001
-100

-50

50

100

150

200

Temperature, F

250

300

350

400

TEG Vapor Pressure

a
torr,K
mmhg,K
Psia,F
Psia,F

Psia,F

b
c
17097.1 9.652867
0
8.702614 2852.623 210.398
12.0229
-6987
202.7
13.1222 -8395.32
258.7

12.0229

-6987

P
P
22.12806
2.960099
17.49691
17.59734

202.7

8.45E-06
0.000814
0.021462
0.251118
1.706576
7.921697
27.85391
79.49697
193.2117
413.838
801.0861
904.7651
1.24E-06
3.07E-06
7.15E-06
1.57E-05
3.29E-05
6.58E-05

t
560
560
560
560

50
100
150
200
250
300
350
400
450
500
550
560
70
80
90
100
110
120

1.961938
1.786671
1.640151
1.515841
1.409046
1.316309
1.235025
1.163196
1.099263
1.041992
0.990393
0.980681

below data all from the Chemistry and Physics Handbook

torr,K

teg
17097.1 9.652867

torr,K

deg
16146.7 9.668173

1000/t,R
2.175332
1.961938
0 1.786671
1.72503
1.640151
1.515841
1.409046
1.316309
1.235025
1.163196

0 2.175332
1.961938
1.786671
1.72503
1.640151

Vapor Presst, F
1.06E-05
0.000289
0.004353
0.011305
0.042074
0.288348
1.506723
6.333209
22.29458
67.79495

7.14E-05
0.001618
0.020986
0.051686
0.178813

Page 20

0
50
100
120
150
200
250
300
350
400

-17.778
10.000
37.778
48.889
65.556
93.333
121.111
148.889
176.667
204.444

0
50
100
120
150

-17.778
10.000
37.778
48.889
65.556

TEG Vapor Pressure

torr,K

EG
14032.4 9.394685

1.515841
1.409046
1.316309
1.235025
1.163196

1.101113
5.248437
20.36836
66.85722
191.1161

200
250
300
350
400

93.333
121.111
148.889
176.667
204.444

2.44081
0 2.175332
1.961938
1.786671
1.72503
1.640151
1.515841
1.409046
1.316309
1.235025
1.163196

8.39E-05
0.00245
0.036886
0.342095
0.748759
2.20184
10.6868
41.51835
134.9119
379.0101
944.2133

-50
0
50
100
120
150
200
250
300
350
400

-45.556
-17.778
10.000
37.778
48.889
65.556
93.333
121.111
148.889
176.667
204.444

2.780095
2.44081
2.175332
1.961938
1.786671
1.72503
1.640151

0.0503
0.897145
8.549915
52.35615
231.9324
391.4693
804.8908

-100
-50
0
50
100
120
150

-73.333
-45.556
-17.778
10.000
37.778
48.889
65.556

5
32
50
100
150
200

-15.000
0.000
10.000
37.778
65.556
93.333
100

Methanol
torr,K

9377.2

8.9547

water

0.17811
0.9492
3.718
11.526
29.825
67.013

2.151926
2.03376
1.961938
1.786671
1.640151
1.515841

1.436
4.579
9.210068
49.08313
192.2578
596.0095
760

Page 21

TEG Vapor Pressure

water

0.08865
0.09991
0.12163
0.17796
0.25611
0.36292
0.50683
0.69813
0.94294
1.275
1.6927
2.223
2.8892
3.7184
4.7414
5.9926
7.511
9.34
11.526
14.123

1000
Methanol

Water

100

Vapor Pressure, MMHG

32.018
35
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210

10
1
0.1
0.01
0.001

0.0001
0.00001
-75

-50

-25

25

50

75

100

Temperature, C

Page 22

TEG Vapor Pressure

Page 23

TEG Vapor Pressure

1000

Vapor Pressure, MMHG

100

10

Water
0.1

0.01

0.001

0.0001

EG

0.00001
1 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2 2.1 2.2

Temperature, 1000/

EG
Water

100

DEG
TEG

125

150

175

200

Page 24

TEG Vapor Pressure

Page 25

TEG Vapor Pressure

1000
100
10
1

Water

Methanol

0.1
0.01
0.001
0.0001

TEG

0.00001

2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3

0.000001

DEG

perature, 1000/R

Page 26

100

200

300

TEG Vapor Pressure

Page 27

TEG Vapor Pressure

300

400

500

600

Page 28

TEG Dehy

Calculates TEG Trayed column performance

Input
Gas Rate, MMSCFD
P, psia
T, F
Z, compressibility
Mw
Lbw/MMSCFD,in
Lbw/MMSCFD,out
Reboiler btu/gal
Number of Theoretical Trays
Contactor K value
Contactor Fs
TEG Circ Rate
Lean TEG, gpm
Lean TEG Wt%
Gas Heat capacity, btu/lb-F

326.00 MMSCFD
1300 PSIA
115 Deg F
0.87
19.47
76
1.32
1400
3
0.195
2.6

240.00 MMSCFD
600 PSIA
90 Deg F
0.89
22.5
60
0.1
1400
4
0.16
2.6

550.00 MMSCFD
650 PSIA
90 Deg F
0.89
22.89
45
0.1
1400
4
0.23
2.9

25 gpm
99.500 Wt%
0.55

60 gpm
99.970 Wt%
0.55

30 gpm
99.975 Wt%
0.55

8.49
6.60
92.782
6.181E-01
1.076E-03
3.36
2.0543
3.43
117.99
1.48
2.100 MMBTU/Hr
1.67
1.25
4.72

9.98
7.09
98.220
5.726E-01
7.719E-04
12.38
0.0914
0.0938
92.08
6.01
5.040 MMBTU/Hr
2.58
1.94
2.57

12.42
10.00
94.209
5.718E-01
5.684E-04
4.05
0.0561
0.1824
91.53
1.75
2.520 MMBTU/Hr
1.83
1.37
2.83

Output
Contactor Tray Dia, Ft
Contactor Packing Dia, Ft
Rich TEG, Wt %
activity coef
K value
A, L/KV
Lbw/MMSCF in eql with lean TEG
Lbw/MMSCF in Product gas
Gas Temp out, F
gal lean teg/lbw absorbed
Reboiler Duty, MMBTU/Hr
Still Col Dia, ft
Stripping Col Dia, ft
Gas density, Lb/Ft
Lean TEG

Page 29

TEG Dehy

TEG
Water

TEG
Water

lb/hr
moles/hr
lb/hr
moles/hr
Rich TEG
lb/hr
moles/hr
lb/hr
moles/hr

13939.95
96.34
70.05
3.89

33613.91
224.59
10.09
0.56

16807.80
112.26
4.20
0.23

13939.95
96.34
1084.45
60.25

33613.91
224.59
609.09
33.84

16807.80
112.26
1033.16
57.40

Page 30

TEG Reboiler

TEG Regenerator Heat Balance


Dehydrated Gas, MMSCFD
Water Content, lb/mmscfd
Rich TEG In
F
lb/hr
(Water)
Stripping Gas in

scf/gal
scfm
lb/hr
Temp

Lean TEG out, gpm


lb/hr
Effluent Gas out
water out
lb/hr Gas
Reflux
in
out
Water heat,
Glycol heat
Gas heat
reflux
desup, ovhd
Total

mw Gas
Cp TEG
Cp TEG
cp gas
cp water
latent heat water
cp hot teg

H:\486106\TEGREB.XLS

Design
240.00
231.00
287.00
2310.00

500.00
58.00
287.00
1208.33

Current
500.00
58.00
280.00
1208.33

700.00
58.00
280.00
1691.67

800.00
58.00
280.00
1933.33

500.00
58.00
280.00
1208.33

700.00
58.00
280.00
1691.67

800.00
58.00
280.00
1933.33

50.00
35.00
280.00
72.92

15.00
95.00
280.00
59.38

3.00
135.00
480.24
50.00
45.00
25218
174.00
174.00

3.00
90.00
320.16
50.00
30.00
16812
174.00
174.00

3.00
90.00
320.16
50.00
30.00
16812
200.00
174.00

3.00
90.00
320.16
50.00
30.00
16812
174.00
174.00

3.00
90.00
320.16
50.00
30.00
16812
174.00
174.00

3.00
120.00
426.88
50.00
40.00
22416
200.00
174.00

3.00
120.00
426.88
50.00
40.00
22416
174.00
174.00

3.00
120.00
426.88
50.00
40.00
22416
174.00
174.00

3.00
9.00
32.02
50.00
3.00
1681
174.00
174.00

3.00
9.00
32.02
50.00
3.00
1681
174.00
174.00

140.00
150.00

85.00
130.00

85.00
130.00

85.00
130.00

85.00
130.00

85.00
130.00

85.00
130.00

85.00
130.00

85.00
130.00

85.00
130.00

2.05
1.88
0.0298
0.14

1.07
1.25
0.0198
0.42

1.08
1.33
0.0240
0.42

1.51
1.33
0.0198
0.42

1.73
1.33
0.0198
0.42

1.08
1.78
0.0320
0.55

1.51
1.78
0.0265
0.55

1.73
1.78
0.0265
0.55

0.07
0.13
0.0020
0.04

0.05
0.13
0.0020
0.04

4.10

2.76

2.85

3.28

3.50

3.44

3.87

4.09

0.24

0.23

22.50
0.66
0.55
0.50
1.00
1000.00
0.66

Page 31

TEG Reboiler

15.00
95.00
280.00
59.38

15.00
95.00
270.00
59.38

Dehydrated Gas, MMSCFD


Water Content, lb/mmscfd
Rich TEG In
F
lb/hr
(Water)

3.00
8.91
31.68
50.00
2.97
1664
194.60
194.60
31.68
85.00
110.00

3.00
8.91
31.68
50.00
2.97
1664
194.60
194.60
31.68
85.00
110.00

Stripping Gas in

0.0543
0.1318
0.0023
0.0229

0.0549
0.1263
0.0023
0.0229

Water heat,
Glycol heat
Gas heat
reflux

0.2112

0.2063

Total

H:\486106\TEGREB.XLS

scf/gal
scfm
lb/hr
Temp

Lean TEG out, gpm


lb/hr
Effluent Gas out
water out
Reflux

in
out

Page 32

TEG,Heat Capacity

0.7

0.65

CP, BTU/lb-F

0.6

0.55

0.5

0.45

0.4
0

50

100

150

200
Temp, F

250

300

350

400

TEG, CP

0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340
350
360
370
380
390
400
410
420
430

0.497661
0.5021
0.506539
0.510978
0.515417
0.519856
0.524295
0.528734
0.533173
0.537612
0.542051
0.54649
0.550929
0.555368
0.559807
0.564246
0.568685
0.573124
0.577563
0.582002
0.586441
0.59088
0.595319
0.599758
0.604197
0.608636
0.613075
0.617514
0.621953
0.626392
0.630831
0.63527
0.639709
0.644148
0.648587
0.653026
0.657465
0.661904
0.666343
0.670782
0.675221
0.67966
0.684099
0.688538

Page 34

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