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8: Solutions
Answer
n(NO) =
m
100
=
= 3.33 mol
30.01
M
6
n(NO) = 5.00 mol
4
n
5.00
V(NaNO2) = =
= 3.60 dm3
1.39
c
3
n(H2SO
n(NO) = 2.50 mol
4) required =
4
n
2.50
V(H
SO4) = =
= 1.12 dm3
2
2.225
c
n(NaNO2) required =
m(H2O)
= density volume = 1.00 180 = 180 g
m
180
n(H
O) =
=
= 9.99 mol
2
M 18.02
m
8.35
n(Na) =
=
= 0.363 mol
22.99
M
If all of Na reacts, only 0.363 mol water required
a
b
m
10.0
=
= 0.0658 mol
M 152.0
n(KBrO3) = c V = 0.774 0.120 = 0.0929 mol
If all of Cr2O3 reacts:
n(Cr2O3) =
n(KBrO
3) consumed in reaction =
6
n(Cr2O3) = 0.0789 mol
5
KBrO3 is in excess by 0.014 mol (0.0929 0.0789) and Cr2O3 is the limiting reagent.
n(Br2) formed =
3
n(Cr2O3) = 0.0395 mol
5
Page 1
Pearson Education Australia (a division of Pearson Australia Group Pty Ltd) 2008.
This page from the Chemistry: For use with the IB Diploma Programme SL Teachers Resource may be reproduced for classroom use.
Answer
a
b
m 100 10 3
=
= 734.5 mol
M 136.14
1
n(Ca3(PO4)2) required =
n(CaSO4) = 244.8 mol
3
m(Ca3(PO4)2) = n M = 244.8 310.18 = 7.59 104 g = 75.9 kg
However, the process is only 75% efficient, hence the mass needed will be greater.
100
4)2) =
m(Ca3(PO
75.9 = 101 kg
75
n(H2SO4) required = n(CaSO4) = 734.5 mol
100
100
m(H2SO4) = n M
= 734.5 98.08
= 9.61 104 g = 96.1 kg
75
75
n(CaSO4) =
Page 2
Pearson Education Australia (a division of Pearson Australia Group Pty Ltd) 2008.
This page from the Chemistry: For use with the IB Diploma Programme SL Teachers Resource may be reproduced for classroom use.