TUTORIAL : CARBONYL

ANSWERS
1. a) Butanal
b) 3-bromo-4-methyl-2-butanone
c) 2-methyl-2-butanone
d) 4-phenylpentanal

2. a) CH
3
CH
2
CH = O
b) CH
3
( CH
3
) CH
2
CH
3
CO CH
3
c) CH
3
CO CH
3

d) CH
3
CH = O

3. a) CH
3
CH
2
CH
2
OH
b) C
6
H
5
CH(OH) CH
2
CH
3
+ Mg(OH)Br
c) CH
3
CH
2
CH
2
OH
d) CH
3
CH
2
COOH

4. a) Rgt : 2,4diphenyl hydrazine
Benzaldehyde orange precipitate
benzyl alcohol no change
b) Rgt : Tollens reagent /alkaline iodine
Hexanal silver mirror / yellow precipitate
2hexanone no change / no change
c) Rgt : alkaline iodine
2-pentanone yellow precipitate
3-pentanone no change