APPENDIX

Thermodynamic Properties of Some

Selected Inorganic Compounds
As thermodynamic data are experimental, their values differ from one source
to another. A consistent set of values has been used here, summarized from
G. Aylward and T. Findlay, SI Chemical Data, 3d ed. (New York: Wiley, 1994).
DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

aluminate ion
bromide
carbide
chloride
chloride hexahydrate
fluoride
iodide
nitride
oxide
phosphate
sulfate

Al(s)
Al( g)
Al31(aq)
Al(OH)42(aq)
AlBr3(s)
Al4C3(s)
AlCl3(s)
AlCl3?6H2O(s)
AlF3(s)
AlI3(s)
AlN(s)
Al2O3(s)
AlPO4(s)
Al2(SO4)3(s)

10
1330
2538
21502
2511
2209
2704
22692
21510
2314
2318
21676
21734
23441

128
1165
2325
1103
1180
189
1111
1318
166
1159
120
151
191
1239

10
1290
2492
21305
2489
2196
2629
22261
21431
2301
2287
21582
21618
23100

Ammonium
bromide
chloride
fluoride
iodide
nitrate
sulfate
vanadate

NH41(aq)
NH4Br(s)
NH4Cl(s)
NH4F(s)
NH4I(s)
NH4NO3(s)
(NH4)2SO4(s)
NH4VO3(s)

2133
2271
2314
2464
2201
2366
21181
21053

1111
1113
195
172
1117
1151
1220
1141

279
2175
2203
2349
2113
2184
2902
2888

Antimony

Sb(s)
Sb( g)
SbCl5(l)
Sb2O5(s)
SbBr3(s)
SbCl3(s)
SbH3( g)
SbI3(s)
Sb2O3(s)
Sb2S3(s)

10
1262
2440
2972
2259
2382
1145
2100
2720
2175

146
1180
1301
1125
1207
1184
1233
1215
1110
1182

10
1222
2350
2829
2239
2324
1148
299
2634
2174

10
1302
21237

135
1174
1317

10
1261
21170

Compound
name
Aluminum

pentachloride
pentaoxide
tribromide
trichloride
trihydride
triiodide
trioxide
trisulfide
Arsenic
pentafluoride

Formula

As(s) (gray)
As( g)
AsF5( g)

A-1

A-2

APPENDIX 1 Thermodynamic Properties of Some Selected Inorganic Compounds

Formula

DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

As2O5(s)
AsBr3(s)
AsCl3(l)
AsF3(l)
AsH3( g)
AsI3(s)
As2O3(s)
As2S3(s)

2925
2130
2305
2786
166
258
2657
2169

1105
1364
1216
1289
1223
1213
1107
1164

2782
2159
2259
2771
169
259
2576
2169

Ba(s)
Ba( g)
Ba21(aq)
bromide
BaBr2(s)
carbonate
BaCO3(s)
chloride
BaCl2(s)
chloride dihydrate
BaCl2?2H2O(s)
fluoride
BaF2(s)
hydroxide
Ba(OH)2(s)
hydroxide octahydrate Ba(OH)2?8H2O(s)
iodide
BaI2(s)
nitrate
Ba(NO3)2(s)
nitride
Ba3N2(s)
oxide
BaO(s)
peroxide
BaO2(s)
sulfate
BaSO4(s)
sulfide
BaS(s)

10
1180
2538
2757
21216
2859
21460
21207
2945
23342
2605
2992
2363
2554
2634
21473
2460

163
1170
110
1146
1112
1124
1203
196
1101
1427
1165
1214
1152
170

10
1146
2561
2737
21138
2810
21296
21157
2856
22793
2601
2797
2292
2525

1132
178

21362
2456

Beryllium

10
1324
2383
2356
2490
21027
2903
2189
2609

19
1136
2130
1100
183
153
152
1120
114

10
1287
2380
2337
2445
2979
2815
2187
2580

Compound
name
pentoxide
tribromide
trichloride
trifluoride
trihydride (arsine)
triiodide
trioxide
trisulfide
Barium

bromide
chloride
fluoride
hydroxide
iodide
oxide

Be(s)
Be( g)
Be21(aq)
BeBr2(s)
BeCl2(s)
BeF2(s)
Be(OH)2(s)
BeI2(s)
BeO(s)

Bismuth
chloride
oxide
oxide chloride
sulfide

Bi(s)
BiCl3(s)
Bi2O3(s)
BiOCl(s)
Bi2S3(s)

10
2379
2574
2367
2143

157
1177
1151
1120
1200

10
2315
2494
2322
2141

Boron

B(s)
B( g)
H3BO3(s)
B4C(s)
B10H14( g)
B2H6( g)
BN(s)
B5H9(l)
BBr3(l)
BCl3( g)

10
1565
21095
271
132
136
2254
143
2240
2404

10
1153
190
127
1353
1232
115
1184
1230
1290

16
1521
2970
271
1216
187
2228
1172
2238
2389

boric acid
carbide
decaborane(14)
diborane
nitride
pentaborane(9)
tribromide
trichloride

Thermodynamic Properties of Some Selected Inorganic Compounds

Formula

DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

trifluoride
trioxide (di)
trisulfide (di)

BF3( g)
B2O3(s)
B2S3(s)

21136
21273
2252

1254
154
192

21119
21194
2248

Bromine

Br2(l )
Br2( g)
Br( g)
Br2(aq)
BrO32(aq)
BrO2(aq)
BrCl( g)
BrF( g)
BrF5( g)
BrF3( g)

10
131
1112
2121
267
294
115
294
2429
2256

1152
1245
1175
183
1162
142
1240
1229
1320
1293

10
13
182
2104
119
233
21
2109
2351
2229

Cd(s)
Cd( g)
Cd21(aq)
CdBr2(s)
CdCO3(s)
CdCl2(s)
CdF2(s)
Cd(OH)2(s)
CdI2(s)
Cd(NO3)2(s)
CdO(s)
CdSO4(s)
CdS(s)

10
1112
276
2316
2751
2391
2700
2561
2203
2456
2258
2933
2162

152
1168
273
1137
192
1115
177
196
1161

10
177
278
2296
2669
2344
2648
2474
2201

155
1123
165

2228
2823
2156

10
1178
2543
2683
260
21207
2796
21220
2186
2986
2533
2938
2635
24121
21567
21434
21577
22023
2482

142
1155
256
1130
170
193
1105
169
142
183
1142
1193
138
1236
182
1107
1131
1194
156

10
1144
2553
2664
265
21129
2748
21167
2147
2898
2529
2743
2603
23885
21499
21332
21437
21797
2477

10
12
1717
2675

16
12
1158
250

10
13
1671
2528

Compound
name

bromate ion
hypobromite ion
monochloride
monofluoride
pentafluoride
trifluoride
Cadmium

bromide
carbonate
chloride
fluoride
hydroxide
iodide
nitrate
oxide
sulfate
sulfide
Calcium

bromide
carbide
carbonate
chloride
fluoride
hydride
hydroxide
iodide
nitrate
oxide
phosphate
silicate
sulfate
sulfate hemihydrate
sulfate dihydrate
sulfide
Carbon

carbonate ion

Ca(s)
Ca( g)
Ca21(aq)
CaBr2(s)
CaC2(s)
CaCO3(s) (calcite)
CaCl2(s)
CaF2(s)
CaH2(s)
Ca(OH)2(s)
CaI2(s)
Ca(NO3)2(s)
CaO(s)
Ca3(PO4)2(s)
CaSiO3(s)
CaSO4(s)
CaSO4?12H2O(s)
CaSO4?2H2O(s)
CaS(s)
C(s) (graphite)
C(s) (diamond)
C( g)
CO 322(aq)

A-3

A-4

APPENDIX 1 Thermodynamic Properties of Some Selected Inorganic Compounds

Compound
name
chloride (yl)
(phosgene)
cyanide ion
dioxide
dioxide
disulfide
ethane
hydrogen
carbonate ion
methane
monoxide
tetrabromide
tetrachloride
tetrafluoride
thiocyanate ion
Cesium

bromide
carbonate
chloride
fluoride
iodide
nitrate
sulfate
Chlorine

chlorate ion
dioxide
hypochlorite ion
monofluoride
oxide (di-)
perchlorate ion
trifluoride
Chromium

(II) chloride
(III) chloride
chromate ion
dichromate ion
(III) oxide
(VI) oxide
(III) sulfate
Cobalt

Formula

DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

COCl2( g)
CN2(aq)
CO2( g)
CO2(aq)
CS2(l )
C2H6( g)

2219
1151
2394
2413
190
285

1284
194
1214
1119
1151
1230

2205
1172
2394
2386
165
233

HCO32(aq)
CH4( g)
CO( g)
CBr4(s)
CCl4(l )
CF4( g)
NCS2(aq)

2690
275
2111
119
2135
2933
176

198
1186
1198
1213
1216
1262
1144

2587
251
2137
148
265
2888
193

Cs(s)
Cs( g)
Cs1(aq)
CsBr(s)
Cs2CO3(s)
CsCl(s)
CsF(s)
CsI(s)
CsNO3(s)
Cs2SO4(s)

10
176
2258
2406
21140
2443
2554
2347
2506
21443

185
1176
1132
1113
1204
1101
193
1123
1155
1212

10
149
2291
2391
21054
2415
2526
2341
2407
21324

Cl2( g)
Cl2(aq)
Cl( g)
Cl2(aq)
ClO32(aq)
ClO2( g)
ClO2(aq)
ClF( g)
Cl2O( g)
ClO42(aq)
ClF3( g)

10
223
1121
2167
2104
1102
2107
254
180
2128
2163

1223
1121
1165
157
1162
1257
142
1218
1266
1184
1282

10
17
1105
2131
28
1120
237
256
198
28
2123

10
1397
2139
2256
2395
2556
2881
21490
21140
2580
22911

124
1175

1115
1123
150
1262
181
172
1259

10
1352
2165
2205
2356
2486
2728
21301
21058
2513
22578

10
1425

130
1180

10
1380

Cr(s)
Cr( g)
Cr21(aq)
Cr31(aq)
CrCl2(s)
CrCl3(s)
CrO42(aq)
Cr2O722(aq)
Cr2O3(s)
CrO3(s)
Cr2(SO4)3(s)
Co(s)
Co( g)

Thermodynamic Properties of Some Selected Inorganic Compounds

Compound
name

Formula

Co21(aq)
Co31(aq)
CoCO3(s)
CoCl2(s)

DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

258
192
2713
2313

2113
2305
189
1109

254
1134
2637
2270

CoCl2?6H2O(s)
Co(OH)2(s) (pink)
CoO(s)
CoSO4(s)

22115
2540
2238
2888

1343
179
153
1118

21725
2454
2214
2782

CoSO4?7H2O(s)

22980

1406

22474

Cu(s)
Cu( g)
Cu1(aq)
Cu21(aq)
(I) chloride
CuCl(s)
(II) chloride
CuCl2(s)
(II) chloride dihydrate CuCl2?2H2O(s)
(II) hydroxide
Cu(OH)2(s)
(I) oxide
Cu2O(s)
(II) oxide
CuO(s)
(II) sulfate
CuSO4(s)
(II) sulfate
pentahydrate
CuSO4?5H2O(s)
(I) sulfide
Cu2S(s)
(II) sulfide
CuS(s)

10
1337
172
165
2137
2220
2821
2450
2169
2157
2771

133
1166
141
298
186
1108
1167
1108
193
143
1109

10
1298
150
165
2120
2176
2656
2373
2146
2130
2662

22280
280
253

1300
1121
167

21880
286
254

10
179
2335

1203
1159
214

10
162
2281

(II) carbonate
(II) chloride
(II) chloride
hexahydrate
(II) hydroxide
(II) oxide
(II) sulfate
(II) sulfate
heptahydrate
Copper

Fluorine

F2( g)
F( g)
F2(aq)

Gallium

Ga(s)
Ga( g)
Ga31(aq)
GaBr3(s)
GaCl3(s)
GaF3(s)
GaI3(s)
Ga2O3(s)

10
1277
2212
2387
2525
21163
2239
21089

141
1169
2331
1180
1142
184
1204
185

10
1239
2159
2360
2455
21085
2236
2998

Ge(s)
Ge( g)
GeO(s)
GeCl4( g)
GeO2(s)

10
1372
2262
2496
2580

131
1168
150
1348
140

10
1331
2237
2457
2521

H2( g)
H( g)
H1(aq)
HBr( g)
HCl( g)
HF( g)

10
1218
10
236
292
2273

1131
1115
10
1199
1187
1174

10
1203
10
253
295
2275

bromide
chloride
fluoride
iodide
oxide
Germanium
dioxide
tetrachloride
tetroxide
Hydrogen

bromide
chloride
fluoride

A-5

A-6

APPENDIX 1 Thermodynamic Properties of Some Selected Inorganic Compounds

Compound
name
hydrobromic acid
hydrochloric acid
hydrofluoric acid
hydroiodic acid
iodide
oxide (water)
hydroxide ion
peroxide
selenide
sulfide
telluride
Indium

(I) chloride
(III) chloride
oxide
Iodine

iodate ion
heptafluoride
monochloride
triiodide ion
Iron

(II) carbonate
(II) chloride
(III) chloride
(II) disulfide
(II) hydroxide
(III) hydroxide
(II) oxide
(II)(III) oxide
(III) oxide
(II) sulfate
(II) sulfate
heptahydrate
(III) sulfate
(II) sulfide
Lead

(II) carbonate
(II) chloride

Formula

DH U
(kJ?mol21)

HBr(aq)
HCl(aq)
HF(aq)
HI(aq)
HI( g)
H2O(l )
H2O( g)
OH2(aq)
H2O2(l )
H2Se( g)
H2S( g)
H2Te( g)

2122
2167
2333
255
126
2286
2242
2230
2188
130
221
1100

182
156
214
1111
1207
170
1189
211
1110
1219
1206
1229

2104
2131
2279
252
12
2237
2229
2157
2120
116
234
185

In(s)
In( g)
In31(aq)
InCl(s)
InCl3(s)
In2O3(s)

10
1243
2105
2186
2537
2926

158
1174
2151
195
1141
1104

10
1209
298
2164
2462
2831

I2(s)
I2( g)
I( g)
I2(aq)
IO32(aq)
IF7( g)
ICl( g)
I32(aq)

10
162
1107
255
2221
2944
118
251

1116
1261
1181
1106
1118
1346
1248
1239

10
119
170
252
2128
2818
25
251

Fe(s)
Fe( g)
Fe21(aq)
Fe31(aq)
FeCO3(s)
FeCl2(s)
FeCl3(s)
FeS2(s) (pyrite)
Fe(OH)2(s)
Fe(OH)3(s)
FeO(s)
Fe3O4(s)
Fe2O3(s)
FeSO4(s)

10
1416
289
249
2741
2342
2399
2178
2569
2823
2272
21118
2824
2928

127
1180
2138
2316
193
1118
1142
153
188
1107
161
1146
187
1108

10
1371
279
25
2667
2302
2334
2167
2487
2697
2251
21015
2742
2821

FeSO4?7H2O(s)
Fe2(SO4)3(s)
FeS(s)

23015
22582
2100

1409
1308
160

22510
22262
2100

10
1196
11
2699
2359

165

10

118
1131
1136

224
2626
2314

Pb(s)
Pb( g)
Pb21(aq)
PbCO3(s)
PbCl2(s)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

Thermodynamic Properties of Some Selected Inorganic Compounds

Compound
name

Formula

(IV) chloride
(II) oxide
(IV) oxide
(II) sulfate
(II) sulfide

PbCl4( g)
PbO(s)
PbO2(s)
PbSO4(s)
PbS(s)

DH U
SU
DG U
21
21
21
(kJ?mol ) (J?mol ?K ) (kJ?mol21)
2552
2217
2277
2920
2100

1382
169
169
1149
191

2492
2188
1217
2813
299

Li(s)
Li( g)
Li1(aq)
bromide
LiBr(s)
carbonate
Li2CO3(s)
chloride
LiCl(s)
fluoride
LiF(s)
hydride
LiH(s)
hydroxide
LiOH(s)
iodide
LiI(s)
nitrate
LiNO3(s)
nitride
Li3N(s)
oxide
Li2O(s)
sulfate
Li2SO4(s)
sulfide
Li2S(s)
tetrahydridoaluminate LiAlH4(s)

10
1159
2278
2351
21216
2409
2616
291
2479
2270
2483
2164
2598
21436
2441
2116

129
1139
112
174
190
159
136
120
143
187
190
163
138
1115
161
179

10
1127
2293
2342
21132
2384
2588
268
2439
2270
2381
2128
2561
21322
2433
245

Magnesium

Mg(s)
Mg( g)
Mg21(aq)
MgBr2(s)
MgCO3(s)
MgCl2(s)
MgCl2?6H2O(s)
MgF2(s)
MgH2(s)
Mg(OH)2(s)
MgI2(s)
Mg(NO3)2(s)
Mg(NO3)2?6H2O(s)
Mg3N2(s)
MgO(s)
MgSO4(s)
MgSO4?7H2O(s)
MgS(s)

10
1147
2467
2524
21096
2641
22499
21124
275
2925
2364
2791
22613
2461
2602
21285
23389
2346

133
1149
2137
1117
166
190
1366
157
131
163
1130
1164
1452
188
127
192
1372
150

10
1112
2455
2504
21012
2592
22115
21071
236
2834
2358
2589
22080
2401
2569
21171
22872
2342

Mn(s)
Mn( g)
Mn21(aq)
MnCO3(s)
MnCl2(s)
MnF2(s)
MnF3(s)
Mn(OH)2(s)
MnO(s)
Mn2O3(s)
MnO2(s)

10
1281
2221
2894
2481
2803
21004
2695
2385
2959
2520

132
1174
274
186
1118
192
1105
199
160
1110
153

10
1238
2228
2817
2441
2761
2935
2615
2363
2881
2465

Lithium

bromide
carbonate
chloride
chloride hexahydrate
fluoride
hydride
hydroxide
iodide
nitrate
nitrate hexahydrate
nitride
oxide
sulfate
sulfate heptahydrate
sulfide
Manganese

(II) carbonate
(II) chloride
(II) fluoride
(III) fluoride
(II) hydroxide
(II) oxide
(III) oxide
(IV) oxide

A-7

A-8

APPENDIX 1 Thermodynamic Properties of Some Selected Inorganic Compounds

DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

MnO42(aq)
MnSO4(s)
MnS(s)

2541
21065
2214

1191
1112
178

2447
2957
2218

Hg(l )
Hg( g)
Hg 221(aq)
Hg21(aq)
Hg2Cl2(s)
HgCl2(s)
HgO(s)
Hg2SO4(s)
HgSO4(s)

10
161
1167
1170
2265
2224
291
2743
2708

176
1175
166
236
1192
1146
170
1201
1140

10
132
1154
1165
2211
2179
259
2626
2595

Ni(s)
Ni( g)
Ni21(aq)
NiBr2(s)
NiCO3(s)
NiCl2(s)

10
1430
254
2212
2681
2305

130
1182
2129
1136
1118
198

10
1385
246
2198
2613
2259

NiCl2?6H2O(s)
NiF2(s)
Ni(OH)2(s)
NiI2(s)
NiO(s)
NiSO4(s)

22103
2651
2530
278
2240
2873

1344
174
188
1154
138
192

21714
2604
2447
281
2212
2760

NiSO4?7H2O(s)
NiS(s)
Ni(CO)4(l )

22976
282
2633

1379
153
1313

22462
280
2588

N2( g)
N( g)
NH3( g)
N 32(aq)
N2O( g)
N2O5( g)
N2O4( g)
N2O3( g)
N2H4(l )
HN3(l )
HNO3(l )
NO32(aq)
NO22(aq)
NO2( g)
NO( g)

10
1473
246
1275
182
111
19
184
151
1264
2174
2207
2105
133
190

1192
1153
1193
1108
1220
1356
1304
1312
1121
1141
1156
1147
1123
1240
1211

10
1456
216
1348
1104
1115
198
1139
1149
1327
281
2111
232
151
187

O2( g)
O3( g)
O( g)
O2( g)
OF2( g)

10
1143
1249
1102
125

1205
1239
1161
1158
1247

10
1163
1232
192
142

Compound
name

Formula

permanganate ion
(II) sulfate
(II) sulfide
Mercury

(I) chloride
(II) chloride
(II) oxide
(I) sulfate
(II) sulfate
Nickel

(II) bromide
(II) carbonate
(II) chloride
(II) chloride
hexahydrate
(II) fluoride
(II) hydroxide
(II) iodide
(II) oxide
(II) sulfate
(II) sulfate
heptahydrate
(II) sulfide
tetracarbonyl(0)
Nitrogen
ammonia
azide ion
dinitrogen oxide
dinitrogen pentoxide
dinitrogen tetroxide
dinitrogen trioxide
hydrazine
hydrogen azide
hydrogen nitrate
nitrate ion
nitrite ion
nitrogen dioxide
nitrogen monoxide
Oxygen

difluoride

Thermodynamic Properties of Some Selected Inorganic Compounds

Compound
name
Phosphorus

hydrogen phosphate
pentachloride
pentafluoride
phosphate ion
phosphoryl chloride
tetraphosphorus
decaoxide
trichloride
trifluoride
trihydride (phosphine)
Potassium

bromide
carbonate
chlorate
chloride
chromate
cyanide
dichromate
dioxide(2) (peroxide)
dioxide(1)
(superoxide)
fluoride
hydride
hydrogen carbonate
hydrogen sulfate
hydroxide
iodide
nitrate
nitrite
oxide
perchlorate
permanganate
peroxodisulfate
pyrosulfate
sulfate
sulfide
tetrafluoroborate
Rubidium

bromide
carbonate
chloride
fluoride
iodide

DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

P4(s) (white)
P(s) (red)
P4( g)
P( g)
H3PO4(s)
PCl5( g)
PF5( g)
PO432( aq)
POCl3(l )

10
218
159
1317
21279
2375
21594
21277
2597

141
123
1280
1163
1110
1365
1301
2220
1222

10
212
124
1278
21119
2305
21521
21019
2521

P4O10(s)
PCl3(l )
PF3( g)
PH3( g)

22984
2320
2919
15

1229
1217
1273
1210

22700
2272
2898
113

K(s)
K( g)
K1(aq)
KBr(s)
K2CO3(s)
KClO3(s)
KCl(s)
K2CrO4(s)
KCN(s)
K2Cr2O7(s)
K2O2(s)

10
189
2252
2394
21151
2398
2437
21404
2113
22062
2494

165
1160
1101
196
1156
1143
183
1200
1128
1291
1102

10
161
2284
2381
21064
2296
2409
21296
2102
21882
2425

KO2(s)
KF(s)
KH(s)
KHCO3(s)
KHSO4(s)
KOH(s)
KI(s)
KNO3(s)
KNO2(s)
K2O(s)
KClO4(s)
KMnO4(s)
K2S2O8(s)
K2S2O7(s)
K2SO4(s)
K2S(s)
KBF4(s)

2285
2567
258
2963
21161
2425
2328
2495
2370
2363
2433
2837
21916
21987
21438
2376
21882

1117
167
150
1116
1138
179
1106
1133
1152
194
1151
1172
1279
1225
1176
1115
1152

2239
2538
253
2864
21031
2379
2325
2395
2307
2322
2303
2738
21697
21792
21321
2363
21786

Rb(s)
Rb( g)
Rb1(aq)
RbBr(s)
Rb2CO3(s)
RbCl(s)
RbF(s)
RbI(s)

10
181
2251
2395
21179
2435
2558
2334

177
1170
1122
1110
1186
196
175
1118

10
153
2284
2382
21096
2408
2521
2329

Formula

A-9

A-10

APPENDIX 1 Thermodynamic Properties of Some Selected Inorganic Compounds

DH U
SU
DG U
21
21
21
(kJ?mol ) (J?mol ?K ) (kJ?mol21)

Compound
name

Formula

nitrate
sulfate

RbNO3(s)
Rb2SO4(s)

2495
21436

1147
1197

2396
21317

Selenium

Se(s) (gray)
Se( g)
SeF6( g)
SeO422(aq)
SeCl4(s)

10
1227
21117
2599
2183

142
1177
1314
154
1195

10
1187
21017
2441
295

Si(s)
Si( g)
SiC(s)
SiO2(s)
SiCl4(l )
SiF4( g)
SiH4( g)

10
1450
265
2911
2687
21615
134

119
1168
117
141
1240
1283
1205

10
1406
263
2856
2620
21573
157

Ag(s)
Ag( g)
Ag1(aq)
AgBr(s)
Ag2CO3(s)
AgCl(s)
Ag2CrO4(s)
AgCN(s)
AgF(s)
AgI(s)
AgNO3(s)
Ag2O(s)
Ag2SO4(s)
Ag2S(s)

10
1285
1106
2100
2506
2127
2732
1146
2205
262
2124
231
2716
233

143
1173
173
1107
1167
196
1218
1107
184
1115
1141
1121
1200
1144

10
1246
177
297
2437
2110
2642
1157
2187
266
233
211
2618
241

Na(s)
Na( g)
Na1(aq)
NaN3(s)
NaBr(s)
Na2CO3(s)

10
1107
2240
122
2361
21131

151
1154
158
197
187
1135

10
177
2262
194
2349
21044

Na2CO3?H2O(s)
Na2CO3?10H2O(s)
NaClO3(s)
NaCl(s)
NaCN(s)
NaH2PO4(s)
Na2O2(s)
NaF(s)
NaH(s)
NaHCO3(s)
Na2HPO4(s)
NaHSO4(s)
NaOH(s)
NaI(s)

21431
24081
2366
2411
287
21537
2511
2574
256
2951
21748
21126
2425
2288

1168
1563
1123
172
1116
1127
195
151
140
1102
1150
1113
164
199

21285
23428
2262
2384
276
21386
2448
2544
233
2851
21608
2993
2379
2286

hexafluoride
selenate ion
tetrachloride
Silicon
carbide
dioxide (quartz)
tetrachloride
tetrafluoride
tetrahydride (silane)
Silver

bromide
carbonate
chloride
chromate
cyanide
fluoride
iodide
nitrate
oxide
sulfate
sulfide
Sodium

azide
bromide
carbonate
carbonate
monohydrate
carbonate decahydrate
chlorate
chloride
cyanide
dihydrogen phosphate
dioxide(22) (peroxide)
fluoride
hydride
hydrogen carbonate
hydrogen phosphate
hydrogen sulfate
hydroxide
iodide

Thermodynamic Properties of Some Selected Inorganic Compounds

Compound
name

Formula

DH U
(kJ?mol21)

SU
(J?mol21?K21)

DG U
(kJ?mol21)

nitrate
nitrite
oxide
perchlorate
phosphate
silicate
sulfate
sulfide
sulfite
tetrahydroborate
thiosulfate
thiosulfate
pentahydrate

NaNO3(s)
NaNO2(s)
Na2O(s)
NaClO4(s)
Na3PO4(s)
Na2SiO3(s)
Na2SO4(s)
Na2S(s)
Na2SO3(s)
NaBH4(s)
Na2S2O3(s)

2468
2359
2414
2383
21917
21555
21387
2365
21101
2189
21123

1117
1104
175
1142
1174
1114
1150
184
1146
1101
1155

2367
2285
2375
2255
21789
21463
21270
2350
21012
2124
21028

Na2S2O3?5H2O(s)

22608

1372

22230

Strontium

Sr(s)
Sr( g)
Sr21(aq)
SrCO3(s)
SrCl2(s)
SrO(s)
SrSO4(s)

10
1164
2546
21220
2829
2592
21453

152
1165
233
197
1115
154
1117

10
1131
2559
21140
2781
2562
21341

S8(s) (rhombic)
S8(s) (monoclinic)
S8( g)
S( g)
SCl2(l )
S2Cl2(l )
SO2( g)
SF6( g)
H2SO4(l )
HS2(aq)
S2O822(aq)
SO422(aq)
S22(aq)
SO322(aq)
S2O322(aq)
SO3( g)

10
10.3
1102
1227
250
258
2297
21209
2814
216
21345
2909
133
2635
2652
2396

132
133
1431
1168
1184
1224
1248
1292
1157
167
1244
119
215
229
167
1257

10
10.1
150
1236
228
239
2300
21105
2690
112
21115
2744
186
2487
2522
2371

Tl(s)
Tl( g)
Tl1(aq)
Tl31(aq)
TlCl(s)
TlCl3(s)

10
1182
15
1197
2204
2315

164
1181
1125
2192
1111
1152

10
1147
232
1215
2185
2242

Sn(s) (white)
Sn(s) (gray)
Sn( g)
SnCl2(s)
SnCl4(l )
SnH4( g)
Sn(OH)2(s)

10
22
1301
2331
2551
1163
2561

151
144
1168
1132
1259
1228
1155

10
10.1
1266
2289
2440
1188
2492

carbonate
chloride
oxide
sulfate
Sulfur

dichloride
dichloride (disulfur)
dioxide
hexafluoride
hydrogen sulfate
hydrogen sulfide ion
peroxodisulfate ion
sulfate ion
sulfide ion
sulfite ion
thiosulfate ion
trioxide
Thallium

(I) chloride
(III) chloride
Tin

(II) chloride
(IV) chloride
hydride
(II) hydroxide

A-11

A-12

APPENDIX 1 Thermodynamic Properties of Some Selected Inorganic Compounds

Compound
name

Formula

DH U
(kJ?mol21)

(II) oxide
(IV) oxide
(II) sulfide
(IV) sulfide

SnO(s)
SnO2(s)
SnS(s)
SnS2(s)

2281
2578
2100
2154

157
149
177
187

2252
2516
298
2145

Titanium

Ti(s)
Ti( g)
TiCl2(s)
TiCl3(s)
TiCl4(l )
TiO2(s) (rutile)

10
1473
2514
2721
2804
2944

131
1180
187
1140
1252
151

10
1428
2464
2654
2737
2890

(II) chloride
(III) chloride
(IV) chloride
(II) oxide
(III) oxide
(IV) oxide
(V) oxide

V(s)
V( g)
VCl2(s)
VCl3(s)
VCl4(l )
VO(s)
V2O3(s)
VO2(s)
V2O5(s)

10
1514
2452
2581
2569
2432
21219
2713
21551

129
1182
197
1131
1255
139
198
151
1131

10
1469
2406
2511
2504
2404
21139
2659
21420

Xenon
difluoride
tetrafluoride
trioxide

Xe( g)
XeF2( g)
XeF4( g)
XeO3( g)

10
2130
2215
1502

1170
1260
1316
1287

10
296
2138
1561

Zinc

Zn(s)
Zn( g)
Zn21(aq)
ZnCO3(s)
ZnCl2(s)
Zn(OH)2(s)
Zn3N2(s)
ZnO(s)
ZnSO4(s)
ZnSO4?7H2O(s)
ZnS(s) (wurtzite)
ZnS(s) (sphalerite)

10
1130
2153
2813
2415
2642
223
2350
2983
23078
2193
2206

142
1161
2110
182
1111
181
1140
144
1110
1389
168
158

10
194
2147
2732
2369
2554
130
2320
2872
22563
2191
2201

(II) chloride
(III) chloride
(IV) chloride
(IV) oxide
Vanadium

carbonate
chloride
hydroxide
nitride
oxide
sulfate
sulfate heptahydrate
sulfide
sulfide

SU
DG U
21
21
(J?mol ?K ) (kJ?mol21)