A.

Tabla de la concentracin de la disolucin de tiosulfato (S2O3)2-

W KIO3
(g)

Vol. de
disol. de
KIO3(mL)

Alcuota
(mL)

Mol de
IO3-

Mol de
I2

0.0818

25

1.53478x
10-05
1.48975x
10-05
1.66987x
10-05

4.60434
x10-05
4.46925
x10-05
5.00962
x10-05

0.0794
0.089

25
25

1
1

Vol. De
(S2O3)2- en
el p. final
(mL)
0.019

Mol de
(S2O3)2-

Concentracin
de (S2O3)2(mol/L)

9.20869x10-

0.00484668

05

0.0165

8.93851x10-

0.00541728

05

0.0166

0.000100192

0.00603568

Con.
Promedio

0.00543321

B. Determinacin de I2 en hexano.
Vol. (S2O3)2- (L)

Conc. De (S2O3)2-

Vol. Punto final (L)

Mol de (S2O3)2-

Mol de I2

Conc. I2 (Hex) (mol/L)

0.01
0.01
0.005

0.00543321
0.00543321
0.00543321

0.006
0.0059
0.003

3.25993E-05
3.20559E-05
1.62996E-05

1.62996E-05
1.6028E-05
8.14982E-06
Con. Promedio

0.001629963
0.001602797
0.001629963
0.001620908

C. Estudio de la distribucin del yodo entre el hexano y disoluciones acuosas de yoduro de potasio de
concentracin variable
No.
Embudo

Vol. De
(S2O3)2(mL)

Mol de
(S2O3)2

Mol de I2
en fase ac.
(Des. Del
reparto)

Mol de I2
inicial en
fase org.

Conc. I2 fase
acuosa
(Despus
del reparto)

Conc. I2
fase org.
(Des. del
reparto)

1.62091E05
1.62091E05
1.62091E05

Mol de I2
en fase
org. (Des.
del reparto
)
1.43075E05
1.43075E05
1.43075E05

0.7

0.7

0.7

3.80325E06
3.80325E06
3.80325E06

1.90162E06
1.90162E06
1.90162E06

1.2

1.2

1.1

6.51985E06
6.51985E06
5.97653E06

1.8

1.7

1.6

2.1

0.00143075

Conc. De KI
en la fase
ac. ( antes
del
reparto)
0

3.80325E-05

3.25993E06
3.25993E06
2.98827E06

1.62091E05
1.62091E05
1.62091E05

1.29492E05
1.29492E05
1.32208E05

9.77978E06
9.23646E06
8.69314E06

4.88989E06
4.61823E06
4.34657E06

1.62091E05
1.62091E05
1.62091E05

1.14097E05
1.08664E-

5.70487E06
5.43321E-

1.62091E05
1.62091E-

1/D

0.02658223 37.6191094

3.80325E-05

0.00143075

0.02658223 37.6191094

3.80325E-05

0.00143075

0.02658223 37.6191094

6.4553E-05

0.00129492

0.0009901

0.04985105 20.0597586

6.4553E-05

0.00129492

0.0009901

0.04985105 20.0597586

5.91736E-05

0.00132208

0.0009901

0.04475782

1.13192E05
1.15909E05
1.18625E05

9.58802E-05

0.00113192 0.00196078 0.08470571 11.8055801

9.05535E-05

0.00115909 0.00196078 0.07812484

8.52268E-05

0.00118625 0.00196078 0.07184539 13.9187776

1.05042E05
1.07759E-

0.000109709 0.00105042 0.00384615 0.10444274 9.57462459

22.342464

12.800026

0.000104485 0.00107759 0.00384615 0.09696165 10.3133558

2.1

2.3

2.3

2.4

2.6

2.8

3.2

3.5

3.6

3.6

05
1.14097E05

06
5.70487E06

05
1.62091E05

05
1.05042E05

1.24964E05
1.24964E05
1.30397E05

6.24819E06
6.24819E06
6.51985E06

1.62091E05
1.62091E05
1.62091E05

9.96091E06
9.96091E06
9.68925E06

1.41263E05
1.5213E-05

7.06317E06
7.60649E06

1.62091E05
1.62091E05

9.14593E06
8.60261E06

1.73863E05
1.90162E05
1.95596E05
1.95596E05

8.69314E06
9.50812E06
9.77978E06
9.77978E06

1.62091E05
1.62091E05
1.62091E05
1.62091E05

7.51596E06
6.70098E06
6.42932E06
6.42932E06

0.000109709 0.00105042 0.00384615 0.10444274 9.57462459

0.00011789

0.00099609 0.00566038 0.11835307

8.4492953

0.00011789

0.00099609 0.00566038 0.11835307

8.4492953

0.000123016 0.00096892 0.00566038 0.12696143 7.87640799

0.0001308

0.00091459 0.00740741 0.14301393 6.99232566

0.000140861 0.00086026 0.00740741 0.16374224 6.10715954

0.000158057

0.0007516

0.00909091 0.21029507

4.7552232

0.000172875

0.0006701

0.00909091 0.25798435 3.87620407

0.000177814 0.00064293 0.00909091 0.27656749 3.61575396

0.000177814 0.00064293 0.00909091 0.27656749 3.61575396

Grafica 1/D vs [ I - ]
40

35

30

1/D

25

y = -2795.7x + 25.934
R = 0.6967

20

15

10

0
0

0.001

0.002

0.003

0.004

0.005

0.006

0.007

Concentracion de Yodo (antes del reparto) (mol/L)

0.008

0.009

0.01