2014 12 02 16 41 49

CUMULATIVE TEST-2 (CT-2)
TARGET : JEE (MAIN + ADVANCED) 2016
COURSE : VIKAAS (JA)
DATE : 24-08-2014
HINTS & SOLUTIONS ladsr ,oa gy

1 3 4a 1
PAPER-1
2 4a 4
Part-I
Mathematics
1.
1
a 1
2
If A1 A2 A3 is equilateral triangle .
;fn A1 A2 A3 leckgq f=kHkqt gS vkSj .

Sol. A1 A2 A3
A5 A6 A7
4.
If variable line y = 2x + k lies between the .
;fn ,d pj js[kk y = 2x + k o`kks .

Sol. S1 : (x 1)2 + (y 1)2 = 1 and vkSj S2 : (x 8)2 + (y 1)2 = 4
Line will lies between the circle
js[kk o`kksa ds e/; fLFkr gSA
centre of circles lie on opposite sides of the line
o`kksa ds
dsU] js[kk 2x y + k = 0 ds foijhr vksj fLFkr gSA

(2 1 + k)(16 1 + k) < 0 (k + 15)(k + 1) < 0
A44 A45 A43 = A4 A5 A3 = 120

2.
k (15, 1)
Value of .
Line will neither touch not cut the circle
4 sin9 sin 21 sin39 sin51 sin 69 sin81

dk
sin54
3.
Sol.
2 1 k
4 sin9 sin 21 sin39 sin51 sin 69 sin81

sin54
=
js[kk u rks o`k dks
Li'kZ djrh gS vkSj u gh frPNsn djrh gSA
.
Sol.
..........(1)
12 22
> 1 |1 + k| >
5 1) (1 +
5 , ) ........(2)
k (,
4 sin9 cos9 . sin39 cos39 sin 21 cos 21

sin54
and
sin18 . sin78 sin 42

2 sin54
k (, 2
sin18 sin(60 18 )sin(60 18 ) 1 1 1

=
.
=
4 2 8
2 sin54
vkSj
16 1 k
22 12
>2
|k + 15| > 2
5 15) (2 5 15 , ) ........(3)
(1) (2) (3)

k (2
5 15,
5 1)
The set of all values of a for .
Integer value of k = 10, 9, 8, 7, 6, 5, 4
a ds
ekuksa dk leqPp; ftlds .
dk iw.kkd eku = 10, 9, 8, 7, 6, 5, 4
(sin2 x cos2 x)2 2sin2 x.cos2 x a

2 sin2 x . cos2x = 1 a
1
(2 sin x.cos x)2 1 a
2
1 2
sin 2x 1 a
2
1
(1 cos 4x) 1 a
4
1 cos 4x = 4 4a
5.
Suppose a and b are rational .
ekuk a vkSj b ifjes; la[;k,s gS vkSj .

Sol.
2a
b
let ekuk x
( )2 2
x 2a 4a2 2b
cos 4x = 3 + 4a
(x 2a)2 4a2 2b
1 cos 4x 1
x2 + 4ax + 4a2 = 4a2 - 2b

x2 + 4ax + 2b = 0
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SOLJACT2240814-1
6.
If the ratio in which line y x + 2 = 0 divides .
;fn js[kk y x + 2 = 0 fcUnqvksa (3,1) vkSj (8, 9) dks
1 3 2 2
Sol. Ratio vuqikr =
=
=4
=
9 8 2 3 6
7.
Circumradius of the triangle whose .
11.
If two points A(p, q), B(r, s) lie on the .
;fn nks fcUnq A(p, q), B(r, s) o`k x2 + y2 = 2 ij .

Sol. p2 + q2 = 2 and vkSj r2 + s2 = 2
use AM GM ds
mi;ksx ls
p + s 2ps and q2 + r2 2qr ps + qr 2

2
Aliter (p, q) =
( 2 cos , 2 sin )
; (r, s) =
( 2 cos , 2 sin )
,d f=kHkqt dh ifjf=kT;k gksxh ftlds .

Sol.
ps + qr = 2sin( + )
Maximum
12.
vf/kdre (ps + qr) = 2.1 = 2
Radius of a circle, which touches .
,d o`k tks y-v{k dks fcUnq (0, 4) ij Li'kZ .

Sol.
Triangle is right angle f=kHkqt
R =
8.
ledks.k f=kHkqt gS
B C 10
=
=5
2
2
If (x1, y1) be the centroid of the triangle .
;fn (x1, y1) funsZ'kh v{kksa vkSj js[kk L ls .

13.
Sol.
A ray of light is sent along the line 2x 3y = 5.
,d dk'k fdj.k] js[kk 2x 3y = 5 ds .

Sol.
P
2x3y=5
00a
0b0
x1 =
, y1 =
3
3
Equation lehdj.k :
9.
x y
+ =1
a b
x
y
+
=1
3x1 3y1
8 3
,
5 5
If a,b,c,d are real numbers .

mqp =
;fn a,b,c,d okLrfod la[;k,a .

Sol. Since pwfd (a b)2 + (b c)2 + (c d)2 + (d a)2
2
3
slope of required ray
= 2(a2 + b2 + c2 + d2) 2 (ab + c + cd + da)
2
tan15
3
m=
2
1 tan15
3
= 2 2(ab + bc + cd + da)
The value of LHS of (1) is minimum when ab + bc + cd + da
is maximum and the minimum value of LHS is equal to zero.
Therefor maximum value of ab + bc + cd + da = 1
(1)
ds LHS eku U;wure gS tc ab + bc + cd + da vf/kdre gS
m=
10.
3 3 4 3 3 8
,
72 3
rFkk LHS dk U;wure eku 'kwU; ds cjkcj gSA blfy, ab + bc +

cd + da = 1 dk
x+y=1
15
vf/kdre eku gS&
equation
1 2 3
3 3 3 8
8
y 5 =
x 5
1 2 3
Distance between the lines .
ljy js[kk;qXe 9x2 6xy + y2 + .

Sol. Lines are js[kk, 3x y + 4 = 0
Distance nwjh =
42
3 1
2
and vkSj 3x y + 2 = 0
2
10
14.
If sin , sin , sin are in A.P. .
;fn sin , sin , sin l- Js- esa .

Sol. From the given conditions we have
fn;s x;s izfrfcE/k ds vuqlkj

2 sin = sin + sin
.....(i)
SOLJACT2240814-2
cos2 = cos cos
hx ky = h2 + k2
.....(ii)
Squaring oxZ
djus ij (i),4 sin2= sin2 + sin2 + 2 sin sin
hx ky
Using (ii) dk
mi;ksx djus ij, 4(1 cos cos )
h2 k 2
= 1 ........(1)
= 1 cos2 + 1 cos2 + 2 sin sin
homogenising the equation x2 (a + b)x + ab = 0 with the
cos2 + cos2 4 cos cos = 2 (sin sin 1)
help of (1)
cos2 cos2 4 cos cos
=2
1 sin sin
(1)
If pth, qth, rth terms of an A.P. are .
x2 (a + b) x.
dh lgk;rk ls lehdj.k x2 (a + b)x + ab = 0 dks le?kkr
cukus ij
2
15.
;fn fdlh l- Js- ds posa, qosa vkSj rosa .
coefficient of x2 + coefficient of y2 = 0
a (q 1)d a (r 1)d
Sol. Given fn;k x;k gS, k =
=
a (p 1)d a (q 1)d
[as lines are 1 js[kk,sa (1) gksxh]

x2 dk
a (q 1)d a (r 1)d
=
a (p 1)d a (q 1)d
=
(q r)d (q r)
=
(p q)d p q
Since one root is 1, therefore, other root =
pq 1
=
qr k
pq 1
vr% ,d ewy 1 gS, o vU; ewy =
=
qr k
16.
18.
(a b)h
h2 k 2
(h2 k 2 )2
ab
(h2 k 2 )
abk 2
(h2 k 2 )2
=0
=0
fcUnqiFk x2 + y2 (a + b)x + ab = 0
Let O be the origin. If A (1, 0) .
quadrant. The inequality x + y < 1 represents all points

below the line x + y = 1 so that xy > 0 and x + y < 1 imply
that p lies either inside the triangle OAB or in third quadrant
Hindi.pwfd xy > 0, P
;k rks Fke prqFkk'k esa ;k rhljsa prqFkk'k esaA
vlfedk x + y < 1 js[kk ds uhps lHkh fcUnqvksa dks O;Dr djrk gSA
blfy, xy > 0 vkSj x + y < 1 bldk vFkZ gS fd p, ;k rks f=kHkqt
OAB ds
19.
6
= 5 H (5 A) = 6
H
(h2 k 2 )
abh2
ekuk O ewy fcUnw gS ;fn A (1, 0) .
1 1
3 2 30 k
1 1
1
=
= + kd = + k
H 2
2
10
60
A+
Sol. Since xy > 0, P lies either in the first quadrant or in the third
;fn kok l- ek- A gS rc H Hkh k ok g-ek- vuq:i gksxkA
3 2 20 k
vc, A = 2 + kd = 2 +k
= 10
10
(a b)h
so locus is blfy,
Sol. Let A be the kth A.M., then H will be the kth H.M.,
Now
xq.kkad + y2 dk xq.kkad = 0
h2 + k2 (a + b) h + ab = 0
If 9 A.M s and 9 H.M.s are inserted .
;fn 2 vkSj 3 ds e/; 9 lekUrj ek/; vkSj 9 .
hx ky
hx ky
+ ab
=0
2
2
h
k
h2 k 2
vUnj fLFkr gS ;k rhljs prqFkk'k esaA
If the circle x2 + y2 2x 2y + 1 = 0 is .
;fn o`k x2 + y2 2x 2y + 1 = 0 ,d .
Sol. ClearlyLi"rr;k% a > 2 andvkSj b > 2
17.
A variable line cuts pair of.
,d pj js[kk] js[kkvksa ds ;qXe .

Sol. Equation line L is y k =
h
(x h), where (h,k) is foot of
k
1 1
+
< 1 ........(1)
a b
Now equation of AB dk
lehdj.k:
perpendicular from origin
js[kk L dk lehdj.k y k =
x
y
+
=1
a b
h
(x h), tgk (h,k) ewy fcUnq ls
k
yEcikn ds funsZ'kkad gSA
ky k2 = hx + h2
SOLJACT2240814-3
1 1
1
1 1
a b
=1 1
1
1
a b
2
2
a
b
(iii)
1 1
(
1 < 0)
a b
1 1
a b =
1
a2
16k2 4.4 (k2 + 3k 66) 0
16.3 (k 22) 0 k 22
Hence vr% k (10, 22]
23.
D 0
If the roots of the equation .
;fn lehdj.k ax2 + bx + c = 0 ds ewy .

ax2 + bx + c = 0 be and + 2,
Sol. Let the roots of
where 2 is an even integer
ekuk lehdj.k ax2 + bx + c = 0 ds ewy vkSj + 2 gSA,
b2
tgk 2 ,d le iw.kkZad la[;k gS

20.
If a and x are positive integers such that .

;fn a vkSj x /kukRed iw.kkZad bl .

Sol.
2 x = ax +
2
24.
ax a x
ax
i.e. |b| 6a
ax
2x
x=
ax =
In the given figure a circle of .
fn;s x;s fp=k esa 1 bdkbZ f=kT;k dk .
x 3 x = 2 a x
Sol. (r)2 = a2
a2 =
5
a=
x
4
AB = 2
least possible required value of a is 5.

a dk
The image of the line 2x y + 3 = 0 .
;fn 2a + 3b + c = 3 ; a > 0, .
4 1
,
3 3
Sol. 2a + 3b + c = 3
1/ 9
5
2
2a 3b c 2 3b c
.
a .

9
5 2
2
39
5
a .b .c .3
a b c
22.
a2
4
js[kk 2x y + 3 = 0 dk js[kk x + y + 1 = 0 .
If 2a + 3b + c = 3 ; a > 0, .
r2
U;wure lEHkkfor eku 5 gSA

25.
21.
b
=++26
a
x+y+1=0
Sol.
R
Q
L
Let point P be (1, 1) its image line x + y + 1 = 0 is R(2, 0)

Equation of line Li s x 2y + 2 = 0
55.22
its distance from (5, 1) is
5 5 . 22
314
522
The complete set of all .
4 1
,
3 3
;fn lehdj.k 4x2 4kx + .

Sol. Let f(x) = 4x2 4kx + k2 + 3k 66
P
x+y+1=0
Hindi
(i) f(2) > 0 k2 5k 50 > 0
(k + 5) (k 10) > 0
k ( , 5) (10, )
(ii)
(4k)
>2 k>4
2(4)
ekuk fd fcUnq P (1, 1) gSA rFkk bldk izfrfcEc js[kk x + y + 1

= 0 esa R(2, 0) gSA
js[kk L dk lehdj.k x 2y + 2 = 0
(5, 1) ls
nqjh =
522
5
5 gS
SOLJACT2240814-4
B
C
Part-II
26.
R
4
Physics
Fixed
2R
A wire frame is in the shape of a...........................
,d rkj dks ijoy;kdkj se y = 5x2 dh...........................

Loss in Gravitational potential energy of chain =
Sol.
2R R
Mg
It is equal to gain is kinetic energy of chain.
2R R
psu dh xq:Roh; fLFkfrt tkZ esa deh = Mg
m x
mg
;g psu dh xfrt tkZ esa o`f) ds leku gSA

m2x cos = mg sin
(1)
2 x
g
tan =
28.
ds d.k ij izkjEHk esa t = 0 ls...........................
Sol.
N = m2x sin + mg cos
(2)
1 kg nzO;eku
dy
= 10x
dx
; tan =
The particle of mass 1 kg is acted upon...........................
F dt P
x
m(v x u x )
10 rad / sec
0 = m (vx ux) vx = ux = 1
4
27.
F dt P
A uniform chain of mass M and length...........................

M nzO;eku
Sol. dm =
rFkk L =
m(v y u y )
R
yEckbZ dh...........................
2
2M
M
d
Rd =
R
2
1
4 5 1(v y 1) v y 11
2
v i 11j
29.
Block A of mass m is placed on a plank...........................

m nzO;eku
Rd
dk ,d CykWd A, Iykad B...........................
Sol.
d
R sin
U=0
In the frame of B (B
Initial potential energy
Wpseudo + Wspring = K = 0
izkjfEHkd fLFkfrt tkZ

/2
Ui =
ds funsZ'k rU=k esa)
+ ma xmax + (
2M
2R
d R sin = mg
xmax =
Final potential energy Uf = mg
R
vfUre fLFkfrt tkZ Uf = mg
30.
1 2
Kxmax ) = 0
2
2ma
K
A force F is applied on block A of...........................

M nzO;eku
ds CykWd A ij F cy...........................
Sol.
Wg = KE
U = KEf 0
2R R
KEf
4

Mg
Alternate solution
oSdfYid gy
a=
F
mM
Applying Newton's law on the system in horizontal direction

F = (M + m) a.
SOLJACT2240814-5
fudk; ij {kSfrt fn'kk esa U;wVu ds fu;e ls F = (M + m) a

2
2x 2 t 2xt 2 t 2 2t x 3 t 3
x
4
x5
x
Now consider the equilibrium of block B w.r.t. block M
CykWd B, CykWd M ds lkis{k lkE; voLFkk esa gS] vr%

F2 = (mg)2 + (ma)2 = (mg)2 +
m2 g2
F2 =
m m M
mg
; F=
m M 2
m
1
mM
34.
2t
x2
2t 4
or
x5
x5
If a ball is thrown vertically upwards...........................
,d xsan dks /okZ/kj ij dh rjQ...........................

Sol. Distance covered in last t seconds of ascent is equal to the
distance covered in first t seconds of free fall
31.
In shown figure, two identical particles...........................
1 2
gt .
2
ij tkus ds nkSjku t lSd.M esa r; nwjh] eqDr :i ls fxjrs
Sol. F = 2T cos 30
a=
a=
i.e
nf'kZr fp=k esa nks le:i d.k (R;sd dk ...........................
T sin30
m
le; izFke t lSd.M esa r; nwjh ds cjkcj gksxhA

vFkkZr~ h
1 2
gt .
2
2 3m
aapproach = 2a =
35.
Which of the following option is correct...........................
ljy jsf[k; fn'kk esa xfr'khy oLrq ds...........................
3 m
Sol. In the given graph, net displacement is zero.

32.
Block A in the figure is released...........................

Average velocity =
iznf'kZr fp=k esa CykWd A dks fojke...........................

Sol. Ws + Wg = 0
fn;s x;s xzkQ esa dqy foLFkkiu 'kwU; gSA
1
1
k(x 0 h)2 kx 02 Mgh 0

2
2
1 2
1
k x 0 + Mgh = k(x0+h)2
2
2
A particle is projected with certain...........................
Sol. As (pwafd)
t1
2u sin
g
and (rFkk)
t2
2ucos
g
2Mg
2x0 ]
k
2Mg
2x0 ]
k
t1t 2
4u2 sin cos

2
2u2 sin 2
2
2R
g
If position x & time t of a particle moving...........................
;fn x v{k ds vuqfn'k xfr'khy d.k dh...........................

Sol.
dqy foLFkkiu
0
0
fy;k x;k le; t
,d d.k dks {kSfrt ry ls fdlh osx...........................
Maximum downward displacement = [
33.
vkSlr osx =
36.
2Mg
h=
2x0
k
uhps dh rjQ vf/kdre foLFkkiu = [
Net displacement 0
0.
Time taken
t
x3 t3
1
2
dx
3x 2
3t 2
dt
37.
A cricketer hits a ball with a velocity...........................
fdsVj xasn dks {kSfrt ls 60 dks.k...........................

Sol.
ux 25cos 60o 12.5 ms1

uy 25 sin 60o 12.5 3 ms1
t2
Time taken by the ball to cover 50 m distance
x2
50 m
dx
x 2 (2t) t 2 2x
dv
dt
dt
x4
nwjh dks r; djus esa xsan }kjk fy;k x;k le;
50m
50m
4s
ux
12.5ms1
Vertical distance covered by the ball in 4 s,

4 s esa
xsan }kjk /okZ/kj r; nwjh
SOLJACT2240814-6
h uy t
Sol. The resultant force will be along y-direction if the resultant of
1 2
gt
2
12.5 3 4
the components along x-direction is zero. If F is the force

needed along OX, then
1
9.8 (4)2
2
ifj.kkeh cy y-fn'kk ds vuqfn'k gS] vr% x-fn'kk ds vuqfn'k

ifj.kkeh cy dk ?kVd 'kwU; gksxkA ;fn OX ds vuqfn'k vko';d
50 3 78.4 = 86.6 78.4 = 8.2 m

38.
vfrfjDr cy F gks rks
A block of mass 2 kg is kept at rest at...........................
F 1cos 60o 2cos 60o 4 cos 60o
2 kg nzO;eku
or (;k)
dk CykWd ?k"kZ.k xq.kkad 0.2...........................
Sol. WF + Wf = K
(x
2x 5)dx ( mg 3) K 0
42.
F (4 1 2)cos 60
1
0.5 N.
2
A pendulum bob is suspended from the...........................
izkjEHk esa fojke esa fLFkr dkj dh Nr ls...........................
K = 33 12 = 21 J
Sol.
39.
Two boys are standing at the ends A...........................
nks yM+ds tehu ij fcUnq A rFkk B...........................

Sol. Two boys stand at the points A and B separated by distance a.
nksuksa yM+ds a nwjh ij fLFkr nks fcUnqvksa A rFkk B ij [kM+s gq, gSA
C
Wpseudo + Wg + WT = K = 0
ma( sin ) (mg( cos ) 0 0
= 2tan1 (a/g) = 60
From right ABC
f=kHkqt ABC ls
43.
2 kg nzO;eku
AB2 BC2 AC2
a2 ( 1t)2 ( t)2
a2 ( 2 12 )t 2
t
A body of mass 2 kg is kept stationary...........................
oLrq dks /okZ/kj nhokj...........................
Sol.
f mg 2 10 20 N.
44.
A body takes time t to reach the ...........................
tc ,d fpdus urry ds 'kh"kZ ls...........................
a
2 12
Sol. When there is no friction,

When there is friction,
40.
A person aiming to reach exactly opposite...........................
be the speed of river water. (ekuk unh dh pky gSA)

Vbr = 0.5 m/s
a 4a '
or
gsin 4g(sin cos )

sin 4 sin 4 cos
Vr =
ls),
0.5ms1
or
sin30o
gsin 4g(sin cos )

sin 4 sin 4 cos
4 cos 3 sin
0.5 0.5 0.25 ms1
41.
1 2 1
at a '(2t)2
2
2
or
30
Clearly (fp=k
a' g(sin cos )
If the length of the inclined plane is d, then
,d O;fDr unh ds nwljs fdukjs ij fLFkr...........................

Sol. Let
a gsin
Three forces acting on a body are...........................
,d oLrq ij dk;Zjr rhu cy fp=k esa...........................
3
tan
4
tc dksbZ ?k"kZ.k ugha gS, a gsin

tc ?k"kZ.k gS, a' g(sin cos )
;fn urry dh yEckbZ d gks rks
SOLJACT2240814-7
1 2 1
at a '(2t)2
2
2
;k
a 4a '
;k
gsin 4g(sin cos )
Sol.
A
r
B
r12
gsin 4g(sin cos )
6A
r
4 cos 3 sin
or
3
tan
4
dU
0
dr
0
2B
r6
r6
2B
, ij
A
A2 A2 A2
A
B
2
2B 4B 4B
2B / A (2B / A)
Sol. Apparent weight of the body in the lift = m(gg)=0

Consequently, normal reaction and hence friction force are
r13
2B
A
A lift is moving downwards with...........................

At
12B
;k
or ;k r
,d fyV uhps dh rjQ xfr'khy...........................
voLFkk ij),
dU
0 (ds fy,)
dr
For
sin 4 sin 4 cos
45.
At equilibrium (lkE;
sin 4 sin 4 cos

;k
both zero.
fyV esa oLrq dk vkHkk"kh Hkkj = m(g g) = 0

blfy, vfHkyEc cy rFkk ?k"kZ.k cy nksauksa 'kwU; gksxsaA
50.
A particle is moving in a spiral path...........................
,d d.k fpdus {kSfrt ry ij...........................

46.
Two particles having mass M...........................

M rFkk m nzO;eku
Sol. At any instant (fdlh
ds nks d.k R...........................
r = t
Sol. As time period is same, angular velocity must be the same.
pwafd vkorZ dky leku gSA blfy, dks.kh; osx Hkh leku gksxkA
47.
Also
v r
ac 2r 2 t & at
a ac2 a2t 1 2 t 2
Sol. Change in momentum (losax
esa ifjorZu)
m ( m) 2m.
Part-III
Chemistry
The bob of mass m is attached to...........................

m nzO;eku
dk xksyd yEckbZ dh...........................
52. 170 g of AgNO3 solution containing
Sol.
AgNO3 ds 170 g foy;u

Sol.
AgNO3 + HCl
Mmoles
mg
1
mv 2
2
V 2g
ar = v2/ = 2g
17 x 1000
170
mass of AgCl =
AgCl + HNO3
80 (LR)
80
x 143.5 = 11.48 g
1000
AgNO3 + HCl AgCl + HNO3
gyfeyheksy
at = 0
17 x 1000 80 (LR)
170
a ar2 a2t 2g
49.
dv

dt
A particle is moving in a circle with...........................
,d d.k o`k ij ,d leku pky...........................
48.
le; ij)
AgCl dk
nzO;eku =
80
x 143.5
1000
= 11.48 g
If the potential energy of two molecules...........................
;fn nks vq.kvksa dh fLFkfrt tkZ dks ...........................
53. A photon of energy E
,d E tkZ okyk ,d QksVksu

SOLJACT2240814-8
13.6(2)2
Sol.
E=
+ KE1
13.6(2)2
and rFkk 2E =
+ KE2
12
2 <
1
2
1.5 P .V2 = PV
1
2
KE 1
KE 2
ry
rz
V
1 .5
V2 =
1
<
2
1
V=
V
3
3
% deh =
V
V
25C rki
100 =
1
3
100 = 33.33%
rFkk 1 atm
1
MY
=
5
MX
Sol. Molecular speed
Mz
1
=
6
My
gy- vk.kfod xfr
Mx
=
Mz
2
3
V = V
rz
rx =
59. A gas mixture at 25C
nks xSlsa X rFkk Y ds folj.k dh nj

Sol.
100 = 33.33%
ckW;y ds fu;e ls
54. The rate of diffusion of two gases
rx
ry
1
3
vc u;k nkc = P + 0.5 P = 1.5 P
KE2 > 2KE1

<
100 =
gy- ekuk xSl dk izkjfEHkd nkc o vk;ru P vkSj V gSA
lehdj.k (i) rFkk (ii) ls
KE 1
KE 2
V
V
% decrease =
.....(ii)
From (i) and (ii),
2
1
V=
V
3
3
V = V
.....(i)
1
molecular mass
Mx
My
My
= 5 6 = 30.
Mz
v.kqHkkj
60. The number of oxygen atoms

Al2O3 ds 20.4 g esa
55. In the given figure, mercury columns
Sol. Mole of Al2O3 =
fn;s x;s fp=k esa izR;sd 10 cm
mifLFkr vkWDlhtu
20.4
= 0.2
102
No. of oxygen atoms = 0.6 NA

Now in 5.4 g of water
No. of moles of hydrogen = 0.3 2 = 0.6
No. of H-atoms = 0.6 NA
gy- Al2O3 ds eksy =
20.4
= 0.2
102
vkWDlhtu ijek.kqvksa dh la[;k = 0.6 NA

Sol.
vc] ty ds 5.4 g esa

gkbMkstu ds eksyks dh la[;k = 0.3 2 = 0.6
Pgas = Patm 10 10 = 75 10 10 = 55 cm of Hg. (Hg dk 55
gkbMkstu ijek.kqvksa dh la[;k = 0.6 NA
cm)
56. If at constant temperature and fixed amount of gas
68. Which of the following oxy anions
fuEu esa ls dkSuls vkWDlh _.kk;uksa dks
;fn fu;r rki ij] xSl dh fuf'pr ek=kk ysdj

Sol. Let the Initial pressure and volume of the gas is P and V,
Now
New pressure is = P + 0.5 P = 1.5 P
From
Boyles law
1.5 P .V2 = PV
V2 =
V
1 .5
2
3
Sol.
V
At the points shown in the figure, the probability of finding the

e is the same due to symmetry of the orbital.
SOLJACT2240814-9
vkd`fr esa n'kkZ;s fcUnqvksa ij] d{kd ds lefer gksus ds dkj.k

bysDVkWu ds ik;s tkus izkf;drk leku gksrh gSA
69. Which of the following is nonplanar molecule
fuEu esa ls dkSulk vleryh; v.kq gS

Sol. Since pwfd
Sol.
C
H
b
b
=
2a
2a
Since
71. Which of the following is the hybridisation
b
>0
2a
pwfd
fuEu esa ls dkSuls fodYi esa OPCl3, OSF4
O
||
P
Sol.
Cl
O
||
Cl
3
sp
b2 4ac b2 4ac
=
a
a
Cl
b2 4ac
< 0( b2 4ac > 0 and vkSj a > 0)
a
F
sp3d2
3.
If x, y, z R such that x + y + z = 2,
;fn x, y, z R bl izdkj gS fd x + y + z = 2,
Sol.
72. Which of the following is octahedral
x+y+z=2
x2 + y2 + z2 + 2(xy + yz + zx) = 4
fuEu esa ls dkSulk v"VQydh; ;kSfxd
xy + yz + zx = 1
using x3 + y3 + z3 3xyz ds
2
mi;ksx ls
= (x + y + z) (x + y + z xy yz zx)
Sol.
8 3xyz = 2(6 + 1)
xyz = 2
xy + yz + zx = 1
squaring oxZ
PAPER-2
Part-I
Mathematics
1.
djus ij
(xy)2 + (yz)2 + (zx)2 + 2xyz (x + y + z) = 1

(xy)2 + (yz)2 + (zx)2 = 9
x2 + y2 + z2 = 6
Which of the following
squaring oxZ
3
vlfedk cos(2x + /6) <
dks
2
djus ij
x4 + y4 + z4 + 2 ((xy)2 + (yz)2 + (zx)2) = 36
4.
If
sin cos cos sin
;fn sin cos cos sin rc

Sol. sin (
Sol.
11
,
6 6 6
2x +
2x
2.
cos
11

2n , 2n
6
6
6
2x +
cos ) sin sin

2
sin
2
(cos sin )
2n, 2n 3
(cos sin )2
n, n 6 , n
1
4
1 2 sin .cos
If the given graph is of f(x) = ax
sin 2
3
4
1
4
sin 2
3
4
;fn f(x) = ax2 + bx + c dk vkjs[k

SOLJACT2240814-10
5.
The least positive solution of
sin 2x =
3 3
cot
sin 2x =
3 3
Sol. cot
From the figure
3 dk U;wure
x cos ( + 30) = d
..(i)
x sin = 1 d
..(ii)
Dividing (i) by (ii), we have
3
3 cot =
sin 2x = n +
3 3
3
sin 2x = 3 3 n +
2
squaring equation (ii) and putting the value of cot , we have

x2=
n = 0
8.
sin 2x =
x =
2
6
1 2
(4d 4d + 4)
3
d2 d 1
3
If 4a2 + 9b2 c2 + 12ab = 0 then a
;fn 4a2 + 9b2 c2 + 12ab = 0 rc fdu

4a2 + 9b2 c2 + 12ab = 0
Sol.
6.
1 d
1 d
Tangents are drawn to the circle x2 + y2 = 32
(2a + 3b)2 c2 = 0
,d fcUnq A, x-v{k ij fLFkr gS] ls o`k x2 + y2 = 32 ij
(2a + 3b c) (2a + 3b + c) = 0
either
Sol.
;k
2a + 3b c = 0
comparing with ls
or ;k
2a + 3b + c = 0
rqyuk djus ij ax + by + c = 0
or ;k
x = 2,
x=2
y = 3,
y=3
points fcUnq (2, 3),or

9.
;k
(2,3)
If 2|OA| = |OB|
;fn 2|OA| = |OB| rc

|OA| = a
Sol. Let ekuk

OA =
4 2 sec
BC = 2OB =
(ABC) =
.
4
gksxk tc sin2 vf/kdre gS vr% =
2b2 = c
10.
c>0
ewyks ds ;ksx = b > 0 ls vkSj fp=k ls c < 0

11.
12.
The distance between the two parallel lines
nks lekUrj js[kkvksa ds e/; nwjh 1 bdkbZ gSA fcUnq

B
If P is any point on the curve
If A (2, ), B (4, ) and C
;fn A (2, ), B (4, ) vkSj

Sol. Orthocentre of ACH and BCH are at B and A respectively.
distance =
Sol.
60
5 1
(4 2)2
2 2
Hindi ACH vkSj BCH dk
30+
60+
1, 4
L1
c>0
;fn o ij dksbZ fcUnq P gS
A (8, 0) or (8, 0)
1d
fpUg
Sol. From sum of roots = b > 0 & from figure c < 0
OA = 8
7.
c + 2b2 = 0
Sign of b, c respectively
b, c ds
1
64
dk {ks=kQy OA BC =
tks fd U;wure
2
sin 2
ewy a, 2a gS
a + 2a = b and rFkk ( a). (2a) = c
1
64
Area (ABC) =
OA BC =
which is minimum
2
sin 2
when sin2 is maximum at =
roots of x + bx + c = 0 are a, 2a
x2 + bx + c = 0 ds
8 2 cosec
|OB| = 2a
2 2 units
yEcdsUnz e'k% A vkSj B gSA
L2
C
SOLJACT2240814-11
5 1
(4 2)2
2 2
nwjh =
13.
2 2 bdkbZ
17.
For
x R , 12 sin x 5 cos x = 2y2 8y + 21
lHkh x R ds fy, 'y' dk okLrfod eku

Sol.
If given progression is H.P. of
122 52 12 sin x 5 cos x 122 52
;fn fn;s x;s vleku in

Sol. (A)
13 2y 2 8y 21 13
2cos(x y)cos(x y)
cos x =
cos(x y) cos(x y)
2y 2 8y 21 13
2(cos2 x sin2 y)
2cos x cos y
2y 2 8y 21 13
cos x cos y = cos x sin y

2
&
sin y = cos x(1 cosy)

2
y
y
y
4sin
cos2
= 2cos2x sin2
2
2
2
2y 2 8y 8 0
&
2y 2 8y 34 0
y 2 4y 4 0
&
y 2 4y 17 0
| cosx sec
(y 2)2 0
y
y
| = 2 (If sin
= 0 then for y = 2nall
2
2
y R ( D 0)
(y 2)2 0
terms are same)

| cosx sec
18.
ds fy, lHkh in leku gS)

14.
Let Tr denote the rth term of a
ekuk Tr ,d G.P. ds r osa in dks nf'kZr
If given progression is
Sol. Given that fn;k
;fn nh xbZ Js<+h xq.kkskj

Sol. (A)
y2
(y - 2)2 = 0
y
y
| = 2 (;fn sin
= 0 rc lehdj.k y = 2n
2
2
cos2x = cos(x + y) cos(x y)

=
cos x = cos2x sin2y

sin y = 0 y = n,n
cos x
r =
= 1 or ;k 1
cos(x y)
Tm n =
2
1
2 2
AR
m n
2 =
1
mn
1
mn
The value of 'a' for which

'a' dk
og eku ftlds fy, lehdj.k
19.
ekuk vkSj ewy gS
Sol.
+ = a 2
If the line segment joining P (1, 3)
;fn fcUnq P (1, 3) vkSj Q (5, 7) dks
Sol. Let and are the roots
PQ =
4 2
Area of PQR =
= a 1
1
PQ . RL
2
2 + 2 = ( + )2 2
PQR dk
= (a 2)2 2(a 1) = (a 1)2 + 5
{ks=kQy =
a=1
16.
and vkSj Tn = ARn1
m2
m n
1
n2
A2Rm+n2 =
sum = 1 1 = 0
15.
x; gS Tm = ARm1 =
1
PQ . RL
2
The number of real roots
lehdj.k ecosx ecosx 4 = 0 ds
Sol. ecosx = t
t = ecosx = 2
since pwafd e
cosx
t2 4t 1 = 0
1
,e . So number of real roots is blfy,
e
okLrfod ewyksa dh la[;k 0 gSA
1 4 2
. RL
2
2 = 2
2 h
[ RL = h]
SOLJACT2240814-12
h=
< radius of the circle o`k
k = 1, 2, 4, 8
dh f=kT;k
But (8, k) must also lie inside the circle
ijUrq (8, k) o`k ds vUnj fLFkr gks ldrk gSA
RL < AH
x2 +y2 = 125
Hence there will be 4 such points R , two on arc PAQ and
64 + k2 125 < 0
two on arc PBQ
k2 < 61
bl izdkj 4 fcUnq R bl rjg ds gksxsaA nks pki PAQ esa vkSj nks
20.
6 values
k can be equal to 1 , 2, 4
pki PBQ esa gksxsa
6 eku
k = 1 , 2, 4
If 3sinx + 4cosx = 5 where
;fn 3sinx + 4cosx = 5 tgk
Part-II
Physics
Sol. Given that 3sinx + 4cosx = 5

3sinx + 4cosx = 5 fn;k
or
;k
x;k gS
23.
3sinx = 5 4cosx
squaring both sides (nksuksa
m nzO;eku
rjQ oxZ djus ij)
fcUnq A ij
or 25 cos x 40cosx + 16 = 0
cosx =
djus ij)
mgR =
4
5
then rc
ds ,d NksVs CykWd dks R..................
Sol. At point A
9 sin2x = 25 + 16cos2 x 40cosx

On solving (gy
A small block of mass m is released..................
1
mv 2A VA 2gR
2
N1
sinx =
3
3
and vkSj tanx =
4
5
m
mg
we have to find value of 2sinx + cosx + 4 tanx

2sinx + cosx + 4 tanx
dk eku gksxk
N1 mg = mar =
3 4
3
=2
+
+ 4.
=5
4 5
4
21.
16a
1 4a
b2 4ac
4a
mgsin60
b2 4ac
2
4a
1 4a2
N2 mg cos 60 =
N2 =
Number of integral values of k for
k ds
iw.kkd ekuksa dh la[;k ftlds
Sol. The slope of the chord is m =
8
thok dh izo.krk m =
k
8
k
Fnet =
24.
VB gR
vB2
R
N2
So, max value always less than 2(when a 0)

22.
1
mVB2
2
Now, max(ax2 + bx + c) =
mg(R cos 60) =
4
1 4a
N1 = mg + 2mg = 3mg
fcUnq B ij
If (b2 4ac)2 (1 + 4a2) < 64a2, a < 0 and
(b2 4ac)2
mVA2
R
At point B
;fn (b2 4ac)2 (1 + 4a2) < 64a2, a < 0 rFkk

Sol.
ar
mgcos60
mg
mVB2
R
3mg
2
mVB2
mg
R
Which of the following statement(s) ..................
fuEu esa ls dkSuls dFku..................

Sol. If some of the forces are non conservative then work done
by all the forces is not equal to work done by resultant force
during same displacement of object.
SOLJACT2240814-13
;fn dqN cy vlaj{kh gks rks oLrq ds leku foLFkkiu ds nkSjku
blh izdkj bl fLFkfr ds fy, ge ikrs gSa N3 =
lHkh cyksa }kjk fd;k x;k dk;Z] ifj.kkeh cy }kjk fd;k x;s dk;Z
4
4
mg +
ma
5
5
ds cjkcj ugha gksrk gSA

25.
A block of mass m is placed on a wedge..................
nzO;eku dk ,d xqVdk ,d ost..................
m
Sol.
and vkSj
(1)
(d)
ma (tM+Roh;
mgsin37
3
3
g+
a
5
5
Similarly for this case get N4 =
4
4
mg
ma
5
5
blh izdkj bl fLFkfr ds fy, ge ikrs gSa
macos37
b3 =
cy)
N4 =
masin37
mg mgcos37
4
4
mg
ma
5
5
Balancing forces perpendicular to incline

N = mg cos37 + ma sin37
ur ry ds yEcor~ cyksa dks larqfyr djus ij

N = mg cos37 + ma sin37
N1 =
4
3
mg +
ma
5
5
and vkSj b4 =
and along incline mg sin 37 ma cos 37 = mb1
26.
,oa ur ry ds vuqfn'k mg sin 37 ma cos 37 = mb1
3
4
b1 =
g
a
5
5
mg mgcos37
vkSj b2 =
N2 =
(3)
4
3
mg
ma
5
5
3
4
g+
a
5
5
4
3
mg
ma
5
5
x=
kx 2
= mg(2x)
2
4mg
(maximum elongation)
k
tkZ laj{k.k ls
blh izdkj bl fLFkfr ds fy, ge ikrs gSa
and
x=
4
3
Similarly for this case get N2 =
mg
ma
5
5
N2 =
ds CykWd dks fojkekoLFkk..................
Sol. By energy conservation
cy) ma
macos37
mgsin37
(2)
Block of mass m is released from..................

m nzO;eku
masin37 N
( tM+Roh;
3
3
g
a
5
5
kx 2
= mg(2x)
2
4mg
(vf/kdre lkj)
k
at equilibrium kx = 2mg
x=
2mg
k
lkE;koLFkk ij kx = 2mg x =
2mg
k
So vr%, (K.E.)max
= mg(2x)
Similarly for this case get
1 2
2mg 1 2mg
kx = 2mg
k
2
k 2 k
2m2 g2
1 2
mv max =
k
2
4
4
N3 =
mg +
ma
5
5
vmax =
2g
m
.
k
SOLJACT2240814-14
27.
One end of an ideal spring..................
From horizontal equilibrium of blocks N1 = N2 = F. If motion
vkn'kZ fLizax fLizax fu;rkad k..................
of any block occurs, there has to be relative motion of both

blocks. Hence at just equilibrium there will be limiting friction
Sol. Maximum work done by the spring = maximum loss in P.E.

of the spring =
at both interfaces, therefore f1= f2= F. The FBD are as
1 2
kx
2
shown.
CykWdksa dks {kSfrt lkE;koLFkk esa j[kus ds fy, N1 = N2 = F vc
The block will have maximum KE when the spring is in its

undeformed state i.e., P.E =0 state
;fn fdlh CykWd dh xfr gksrh gS rks Hkh CykWdksa ds e/; dksbZ
When spring does negative work the kinetic energy of the
lkis{k xfr gksxh (ckf/kr xfr) A vr% Bhd lUrqyu ds fy, nksauks
block will decrease.
ds lEidZ ry esa lhekUr ?k"kZ.k dke djuk pkfg,A vr%
While moving away from the wall the P E of the spring first
f1= f2= F, FBD fp=k
decreases and then increases and therefore the K.E of the
esa nf'kZr gSA
block first increases and then decreases.
fLax }kjk fd;k x;k vf/kdre dk;Z = fLax dh fLFkfrt tkZ esa
vf/kdre gkfu =
1 2
kx
2
f2
tc fLax viuh vf/kd`r voLFkk esa gs rc CykWd dh xfrt tkZ
T1 + f1 = 15 g (1)
vf/kdre gksxh P.E =0 voLFkk
f1 = f2 (2)
and
tc fLax /kukRed dk;Z djrh gS rks CykWd dh xfrt tkZ
rFkk f1 + 25g+ f2 = 2T1
(3)
Solving (1), (2) and (3)
?kVsxhA
(1), (2) rFkk (3) dks
tcfd nhokj ls nwj xfr dj jgh fLax dh fLFkfrt tkZ igys

F=
?kVrh gS rFkk fQj c<+rh gSA vr% CykWd dh xfrt tkZ igys
gy djus ij
125
N
4
c<+rh gS rFkk fQj ?kVrh gSA

33.
29.
Frictional force acting..................
CykWd C ij dk;Zjr~ ?k"kZ.k..................
Ball A is projected from ground..................
fp=kkuqlkj xsan A dks tehu ls..................

Sol. For A and B to collide, relative motion must be along AB, i.e.
A
rFkk B ds Vdjkus ds fy,, lkis{k xfr AB ds vuqfn'k gksuh
Again horizontal range of A must be greater than 50 m. i.e.
vr% A dh {kSfrt ijkl 50 m ls T;knk gksuh pkfg,A vFkkZRk~
u
50
g
30.
Tension in the string connecting.................

B rFkk C ls
tqM+h gqbZ jLlh..................
Sol. (33 to 34 )
pkfg, vFkkZr~
34.
u 500ms1
Here (;gk)
mA g 40N
(mB mc )sin 50
Limiting friction (lhekUr
If wind is blowing in horizontal..................
3
30N
5
?k"kZ.k cy)
fB fC (mB mC )gcos 0.5 50
;fn gok {kSfrt fn'kk esa izokfgr..................
T1
Sol. Wind exerts horizontal force which cannot affect time of
T2
flight and maximum height but affects horizontal range
gok {kSfrt cy vjksfir djrh gS] tks fd m;u dky rFkk
T1
T1
vf/kdre pkbZ dks izHkkfor ugha djrh gSA ijUrq {kSfrt ijkl
4
20N
5
37
izHkkfor gksrh gSA

Hence blocks will not move (pwafd
31.
To have the complete system..................
lEiw.kZ fudk; dks LFkk;h lkE;koLFkk..................

32.
In the equilibrium state..................
lkE;koLFkk dh fLFkfr esa..................

Sol. (31 to 32)
CykWd xfr ugha djrs gSA)
T1 mA g 40W
Let (ekuk) fB
mB gcos
0.5 3 10
4
12N
5
For equilibrium of B (B
downwards (uhps
dh rjQ)
dh lkE; voLFkk ds fy,)
SOLJACT2240814-15
T2 T1 fB mB g
= 40 12 18 = 10 N.
37.
A block of mass 60 kg is..................
mg T2 2N upwards (ij dh rjQ)
fc
35.
6R
g
The particle will leave the..................
60 kg nzO;eku
d.k xksys dh vkUrfjd lrg..................
Sol. By Wnet = K.E = 0
Sol. At the position shown (iznf'kZr
N mgsin
fLFkfr ij)
mv 2
R
1
k(x02 x2) = mgx
2
1
1
200(22 x2) =
60 10x
2
2
when contact from sphere breaks.

(tc
xksys ls lEiZd NksMs+xkA)
x = 1m
Also at this moment
N=0
bl {k.k ij fmax > kx
So, block will not move so total distance travelled d = 2 + 1 = 3m.
mv 2
R
mgsin
ds ,d CykWd..................
........ (1)
By conservation of energy (tkZ
vr% CykWd xfr ugha djsxk blfy, dqy r; nwjh d = 2 + 1 = 3m
laj{k.k }kjk)
38.
Consider the system of 2 pulleys..................
fp=k esa n'kkZ;s vuqlkj nks f?kjuh..................
mg sin
N
Sol. FBD of m1
5m/s
mg
m1g
m1g T = m1.5
1
1
mu2 mv 2 mgR(1 sin ) .......... (2)
2
2
Now, FBD of B
dks gy djus ij
30o ,
gR
2
co-ordinates of the given point (fn;s
x;s fcUnq ds funsZ'kkad)
T
m2g = 5m2
2
3R R
,
(R cos , R sin )
2 2
36.
The particle after leaving the..................
xksys ls lEiZd NksM+us ds i'pkr~..................

Sol. After leaving the contact at t = 0 (t = 0
ij lEiZd NksM+us ds
i'pkr~)
T
= 15 m2
2
T = 30 m2
3
x
R v sin t
2
y
Ans.
R
1
v cos t gt 2
2
2
5m/s
m1g
d.k nqckjk xksys ls Vdjk;sxkA)
m1g T = m1.5
x 2 y 2 R2
2
m1
=6
m2
m1 dk FBD
The particle will again collide the sphere when

(tc
........(ii)
by (1) and (2)

5m1 = 30m2 =
& (rFkk)
........(i)
By constraint acceleration of B will be 5 m/sec2 upwards.
on solving (1) & (2)

(1) rFkk (2)
T = 5m1
By symmetry acceleration of block C and B will be same.
1 gR R 1 3gR
1
R
t
t gt 2 R2
2 2 2 2
2
2
2
T = 5m1
........(i)
lfEefr ls CykWd C rFkk B dk Roj.k leku gksxkA

caf/kr xfr }kjk B dk Roj.k 5 m/sec2 ij dh rjQ gSA
B dk FBD
SOLJACT2240814-16
Ru
42.
T
m2g = 5m2
2
t = 1 & t = 2s.
m1
=6
m2
Ans.
(t = 1 rFkk t = 2s
x(0) 7m,
ds nks d.k..................
| x(1) x(0) | | x(2) x(1) | | x(3 x(2) |
T1 m12 2m2 2
5 1 5 11m
43.
A block of mass 3 kg moving with..................
fp=kkuqlkj 3 kg nzO;eku dk CykWd..................
m1 2m2 5
m1
3.
2m2
2
m2
A position dependent force
fLFkfr ij fuHkZj cy F
Sol. By work energy theorem (dk;Z
1
| x 4 | ..................
2
for block not to bounce back (CykWd
mg
1
| x 4 | ..................
2
F (N)
okil ugha yksVrk gSA)
(2)
djus ij)
1
3
n=3
44.
1
2 4 2 8J
2
fp=kkuqlkj m nzO;eku dh xsUn..................

Sol. Tension in the string will be 6 mg at the lowest position.
fcUnq ij jLlh esa ruko 6 mg gSA)
velocity of the ball just after the string breaks, (jLLkh
VqVus ds Bhd i'pkr xsUn dk osx)
ms
ds vuqfn'k xfr'khy d.k..................
x 9t 2 t 3
A ball of mass m is suspended..................
u 5g 5g
The position x of a particle with..................

x-v{k
x (m)
Sol.
kx
(1)
1
3
min =
(fuEure
on solving (gy
xzkQ }kjk x-v{k ls ifjc) {kS=kQy
tkZ izes; ls)
1
1
mu2 mgx kx 2
2
2
Sol. Area under for graph intercepted is with x-axis
41.
y=5
gS)
T1 5
.
T2 2
x(3) 16m
Distance (nwjh)
T1 T2 m12
40.
x(1) 12m
x(2) 11m,
T2 m2 2 (2l)
ij oLrq fLFkj voLFkk esa vkrh gSA)
Now (vc)
Two particles of masses m1 and m2..................
given (fn;k
dx
6t 2 18t 12
dt
The body will come to rest at
m1 rFkk m2 nzO;eku
Sol.
ds vuqfn'k xfr'khy d.k..................
x 2t 3 9t 2 12t 7.
v
........(ii)
}kjk
5m1 = 30m2 =
39.
Sol.
T = 30 m2
(1) rFkk (2)
The position of a particle moving..................

X-v{k
T
= 15 m2
2
2h
5m
g
dx
18t 3t 2
dt
For maximum speed (vf/kdre
d
0 18 6t 0
dt
pky ds fy,),
t 3s.
for maximum speed, position of the particle is (vf/kdre
ds le; d.k fLFkfr)
x 9 32 33 81 27 54 m.
SOLJACT2240814-17
pky
Part-III
Chemistry
51. Which of the following statements is/are correct
fuEu esa ls dkSulk@dkSuls dFku lgh gS
45. 1st excitation potential for the H-like
Sol. (A) Across the period, size decreases as electrons are added
,d H-leku ijek.kq dkYifud ds kn'kZ

Sol. 1st excitation energy = 13.6 z2
(136. z2) = 32 eV
I.E. = 32 eV
in the same shell and nuclear charge increases by one unit
1 2 = 24 eV
2
for addition of each successive element.

In contrary, the ionization energy increases as size of atom
decreases and nuclear charge increases.
(B) Electron gain enthalpy values of halogens are exothermic
(negative) and that of noble gases are endothermic (positive)
13.6z 2
(B.E.) 3rd excited state =
42
32
=
= 2eV
16
(C)
5B
I.E. = 32 eV
3rd mksftr
- 1s2 2s2 2p2
- 1s2 2s2 2p3 half filled stable configuration, so more
stable.
(D) Isoelectronic series of ion; all have the xenon electron
configuration.
voLFkk dh (B.E.) =
2nd mkstu
- 1s2 2s2 2p1
6C
gy- 1st mkstu tkZ = 13.6 z2 = 24 eV
- 1s2 2s2 completely filled stable configuration, so
4Be
1 32 8
2nd excitation energy = 13.6 z 1

eV
=
9
32
(136. z2) = 32 eV
more stable.
3Li
tkZ = 13.6 z2
13.6z 2
42
32
10
Ionic radius
= 2eV
1
nuclear ch arg e
Atomic number : Te = 52; I = 53; Cs = 55; Ba = 56.
1 2 = 32 x
2
eV
gy- (A) vkorZ esa ck;sa ls nk;sa tkus ij vkdkj ?kVrk gS] D;ksafd leku
dks'k esa bysDVkWu tqM+rs gSa rFkk izHkkoh ukfHkdh; vkos'k izR;sd
ekxr rRo ds fy;s ,d bdkbZ c<+rk gSA tcfd vk;uu tkZ
46. According to Maxwell's distribution of molecular
c<+rh gS] D;ksafd ijek.kq dk vkdkj ?kVrk gS rFkk izHkkoh ukfHkdh;
eSDlosy ds v.kqvksa ds osx forj.k ds vuqlkj rkieku
vkos'k c<+rk gSA
Sol. At constant temperature, decrease in molecular mass causes
gSykstuksa dh bysDVkWu xzg.k ,UFkSYih "ek{ksih _.kkRed rFkk
flattening of the graph. For same molecular mass of gas,
(B)
increase in temperature causes flattening of the graph.
vf; xSlksa dh bysDVkWu xzg.k ,UFkSYih "ek'kks"kh /kukRed gksrh
From the above graph,
gSA
( Vmp )T1 ( Vmp )T2
T1
MA
<
T2
MB
T2
T1
(C)
>
MB
MA
5B
(D)
>
3 10 8
6000 10
10
Energy of photon (QksVksu
- 1s2 2s2 2p3
v)Ziwfjr LFkk;h vfHkfoU;kl gSA blfy,
vk;u dh lebysDVkWfud Js.kh] lHkh dk ftukWu ds leku
= 5 1014 S1
dh tkZ) =
12400
6000
1
ukfHkdh; vkos'k
ijek.kq ekad : Te = 52; I = 53; Cs = 55; Ba = 56.

53. A 5 g silver coin completely reacted
,d lksfM;e LVhV ykbV gYdh ihyh jks'kuh

=
- 1s2 2s2 2p2
vk;fud f=kT;k
MB
MA
48. A sodium street light gives off yellow light
- 1s2 2s2 2p1
bysDVkWfud vfHkfoU;kl gSA
( Vmp )T1 ( Vmp )T2
Sol. =
iw.kZiwfjr LFkk;h vfHkfoU;kl gSA blfy, vf/kd
vf/kd LFkk;h gSA
mijksDr vkjs[k ls,
<
6C
QyLo:i vkjs[k lery izkIr gksrk gSaA
T2
T1
- 1s2 2s2
4Be
tkrk gSA leku v.kq nzO;eku okyh xSlksa ds fy, rkieku esa o`f) ds
T2
MB
LFkk;h gSA
gy- fu;r rki ij v.kq nzO;eku esa deh ds QyLo:i vkjs[k lery gks
T1
MA
3Li
,d 5 g ds pknh ds flDds (silver coin)

Sol.
nHNO 3
6.3 1.33 10
63
25
1
=
1000 30
= 2.07 eV
SOLJACT2240814-18
1
30
nAg reacted =
3
4
1
40
mAg reacted =
1
40
56. If volume of flask B was measured
108 = 2.7 g
;fn ik=k B dk vk;ru 10 litre ekik x;k

Sol. VA =
% of Ag in coin =
2 .7
5
100 = 54%.
950
2.5
PA VA
760
nA =
=
= 0.125
1
RTA
300
12
25
1
6.3 1.33 10
gy- nHNO 3 =
=
1000 30
63
vfHkd`r Ag ds
eksy nAg
1
30
3
4
1
40
Mass of O2 = 32 0.125 = 4 gm
esa Ag dk % =
2 .7
5
80
100
1
40
nNO 2
0.02 3
2
2
) produced according to 3rd reaction
0.5
2 2 0.5
2 0.5
ni = 2 + 0.5
n = (2.5 2) = 0.5 moles

change in pressure
p =
nRT
V
nkc esa ifjorZu
= 0.5
1
12
300
= 2 atm.
6.25
60. How many of the following statements are correct
gy- fLVyhd`r n AgNO3 =

2nd vfHkf;k
80
100
1
40
,d ok"i'khy /kkrq DyksjkbM dk 65.25 xzke

22.4
x 65.25 = 261
5.6
= 0.02
Let the formula of metal chloride be MClx
ds vuqlkj mRiUu n O 2 =
0.02 3
2
2
rFkk vfHkf;k 3rd ds vuqlkj mRiUu ( n O 2 + nNO 2 )
MClx + Mg
M + MgCl2
Applying POAC on Cl : x
x
5.22
3.8
= 2
261
95
nMClx
=2
nMgCl2
x=4
Valency of metal = 4 Formula = MCl4
= 0.015
M + 4 (35.5) = 261
dqy xSlh; mRiknksa dk STP ij dqy vk;ru
= (0.005 + 0.015) 22400 = 448 ml.
(MAt mass of metal)
M = 119
gy% /kkrq DyksjkbM dk v.kqHkkj =
55. What is the correct relationship between
nksuks ik=kksa ds vk;ru ds e/; lgh lEcU/k

Sol. nA + nB = nTotal
22.4
x 65.25 = 261
5.6
ekuk fd /kkrq DyksjkbM dk lw=k MClx gSA

MClx + Mg
910 ( VA VB )
950 VA
900 VB
+
=
R 300
R 300
R 300
So, 4VA = VB
61. 65.25 g of a volatile metal chloride
Sol. Mol. mass of metal chloride =
= 0.015
0.02 3
2
2
Sol. Only 3rd is a correct.
= 0.015
0.015) 22400 = 448 ml.
vr%
2NO2(g)
dsoy 3rd gh lgh gSA
Total volume at STP of gaseous products = (0.005 +
fuEu esa ls fdrus dFku lgh gSa
= 0.005
O2(g)
nf = 1 + 1
= 0.02
nO2 produced according to 2nd reaction = 0.02 1

2
2
& ( nO2 +
2NO(g)
moles
mijksDr 'u esa] kIr xSlh; mRiknksa dk STP
n AgNO3 crystallized =
Sol.
100 = 54%.
54. The total volume at STP of the gaseous
Sol.
59. Calculate the change in
nkc (atm esa) esa ifjorZu Kkr dhft,
vfHkd`r Ag dk Hkkj mAg = mAg = 108 = 2.7 g

flDds
10
= 2.5 lt
4
M + MgCl2
Cl ij POAC yxkus
x
ij : x nMCl = 2 nMgCl2
x
5.22
3.8
= 2
261
95
x=4
SOLJACT2240814-19
/kkrq dh la;kstdrk = 4 lw=k = MCl4

(M/kkrq
M + 4 (35.5) = 261
Cl
CH2CH2Cl
dk ijek.kq Hkkj)
63.
cL / h
H / Ni
(a )
(c )
CHCH3
C
M = 119
62. Consider N2H4 (Hydrazine gas) and O2
fuEu vkd`fr ds vuqlkj ,d n`<+ fudk;

Sol. In compartment (A) :
N2H4(g) N2 (g) + 2H2(g)
Initial
3 atm
CHO
|
OHC C CHO + HCHO
|
CHO
a = 1 ; b = 2 = c = 2 Total, answer 5.
__________________________________
Final
3 atm
a=1;b=2=c=2
dqy mkj 5.
6 atm
__________________________________
As this H2 enters (B), it reacts with O2 present in (B)
64. How many of the following elements
fuEu esa ls fdrus rRo viuh lcls LFkk;h

Sol. Fe, Zn, Be, Pb, Co are most stable in their +2 states.
2H2 + O2 2H2O(l).
On a scale of 10 L volume, 1 atm of O2 will react with 2 atm of
Fe, Zn, Be, Pb, Co
H2; leaving only 4 atm of H2 ; if measured in a single
LFkk;h gSaA
budh +2 vkWDlhdj.k voLFkk lcls vf/kd
compartment.
N2 formed remains only in compartment (A), while H2 spreads
out to B, through Pt partition.
Sol.
pH2
fuEu esa ls fdrus _.kk;uksa ds uke esa vuqyXu
pH2
(in A) =
pH2
= 2 atm (in 20 L i.e. A + B) finally.
Sol. IO4
(in B) always
foHkkx (A) :
N2H4(g)
N2 (g)
izkjEHk esa 3 atm
+ 2H2(g)
Periodate (ijvk;ksMsV)
CH3COO
Acetate (,flVsV)
ZnO22
Zincate (ftadsV)
CO32
Carbonate (dkcksZusV)
NO3
Nitrate (ukbVsV)
Stannate (LVSusV)
OCN
Cyanate (lk;usV)
C2O42
Oxalate (vkWDlsysV)
SnO32
__________________________________
vUr esa
65. How many anions of following are named
3 atm
6 atm
__________________________________
66. How many of the following are planar
tSls gh ;g H2 (B) ij igqprk gS, ;g (B) esa mifLFkr O2 ls f;k
Sol. (i) Planar molecules : XeF2, ClF3, H2O, [XeF5], I3, BCl3,
djrk gSA
XeF4.
2H2 + O2 2H2O(l).
10 L
fuEu esa ls fdruh Lih'kht leryh;
(ii)
vk;ru ds ,d iSekus ij] 1 atm O2 dh 2 atm H2 ds lkFk
PCl5 Trigonal bipyramidal
f;k djk;h tkrh gS ; rks dsoy 4 atm H2 'ks"k jg tkrk gS (;fn
foHkkx (A) esa dsoy cuk;k x;k N2 'ks"k cp tkrk gS] tcfd Pt
ges'kk
vUrr%
pH2
(A esa) =
SF4 lh&lkW
vkd`fr
PCl5 f=kdks.kh;
(B esa)
= 2 atm (20 L esa
gy- (i) leryh; v.kq : XeF2, ClF3, H2O, [XeF5], I3, BCl3, XeF4.
(ii)
f>Yyh esa ls H2, (B) rd QSy tkrk gSA
pH2
SF6 Square bipyramidal

IF7 Pentagonal bipyramidal
,d ,dy foHkkx esa ekfir gkss)
pH2
SF4 See - Saw shape
SF6 oxkZdkj
vFkkZr~ A + B).
f}fijkfefM;
f}fijkfefM;
IF7 iapdks.kh;
f}fijkfefM;
SOLJACT2240814-20
CUMULATIVE TEST-2 (CT-2)

TARGET : JEE (MAIN+ADVANCED) 2016
COURSE : VIKAAS (JA)
DATE : 24-08-2014
ANSWER KEY
CODE-0
PAPER-1
MATHEMATICS
1.
8.
15.
22.
(C)
(C)
(D)
(D)
2.
9.
16.
23.
(C)
(B)
(B)
(B)
3.
10.
17.
24.
(C)
(B)
(A)
(A)
4.
11.
18.
25.
( C)
(B)
(A)
(D)
5.
12.
19.
(A)
(C)
(A)
6.
13.
20.
(B)
(B)
(A)
7.
14.
21.
(A)
(A)
(B)
30.
37.
44.
(B)
(A)
(A)
31.
38.
45.
(D)
(A)
(C)
32.
39.
46.
(A)
(D)
(C)
(A)
(A)
(C)
56.
63.
70.
(C)
(A)
(C)
57.
64.
71.
(C)
(B)
(A)
PHYSICS
26.
33.
40.
47.
(B)
(B)
(A)
(B)
27.
34.
41.
48.
(C)
(B)
(A)
(E)
28.
35.
42.
49.
(B)
(C)
(C)
(A)
29.
36.
43.
50.
(B)
(A)
(B)
(B)
CHEMISTRY
51.
58.
65.
72.
(A)
(B)
(D)
(A)
52.
59.
66.
73.
(C)
(A)
(C)
(D)
53.
60.
67.
74.
(A)
(C)
(E)
(B)
54.
61.
68.
75.
(D)
(C)
(C)
(C)
55.
62.
69.
PAPER-2
MATHEMATICS
1.
8.
15.
22.
(ACD) 2.
(AB)
9.
1
16.
6
(AD)
(A)
0
3.
10.
17.
(ACD) 4.
(D)
11.
2
18.
(BD)
(A)
1
5.
12.
19.
(ABC) 6.
(A)
13.
4
20.
(BC)
(A)
5
7.
14.
21.
(B)
(A)
2
27.
34.
41.
(AD)
(C)
(5)
(AC)
(C)
(5)
29.
36.
43.
(BC)
(A)
(3)
(ABC) 51.
(C)
58.
(5)
65.
(ABD)
(B)
(8)
PHYSICS
23.
30.
37.
44.
(ABC) 24.
(AD)
31.
(3)
38.
(6)
(ABD) 25.
(C)
32.
(6)
39.
(AC)
(C)
(3)
26.
33.
40.
(AC)
(A)
(8)
28.
35.
42.
CHEMISTRY
45.
52.
59.
66.
(BCD) 46.
(ACD) 53.
(2)
60.
(7)
(ABC) 47.
(C)
54.
(1)
61.
(C)
(A)
(7)
48.
55.
62.
(BD)
(B)
(2)
49.
56.
63.
(ACD) 50.
(B)
57.
(5)
64.
SOLJACT2240814-21

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CUMULATIVE TEST-2 (CT-2)

TARGET : JEE (MAIN + ADVANCED) 2016

COURSE : VIKAAS (JA)

HINTS & SOLUTIONS ladsr ,oa gy

;fn A1 A2 A3 leckgq f=kHkqt gS vkSj .

If variable line y = 2x + k lies between the .

;fn ,d pj js[kk y = 2x + k o`kks .

js[kk o`kksa ds e/; fLFkr gSA

centre of circles lie on opposite sides of the line

dsU] js[kk 2x y + k = 0 ds foijhr vksj fLFkr gSA

A44 A45 A43 = A4 A5 A3 = 120

Line will neither touch not cut the circle

4 sin9 sin 21 sin39 sin51 sin 69 sin81

4 sin9 sin 21 sin39 sin51 sin 69 sin81

js[kk u rks o`k dks

Li'kZ djrh gS vkSj u gh frPNsn djrh gSA

4 sin9 cos9 . sin39 cos39 sin 21 cos 21

sin18 . sin78 sin 42

sin18 sin(60 18 )sin(60 18 ) 1 1 1

(1) (2) (3)

The set of all values of a for .

Integer value of k = 10, 9, 8, 7, 6, 5, 4

ekuksa dk leqPp; ftlds .

dk iw.kkd eku = 10, 9, 8, 7, 6, 5, 4

(sin2 x cos2 x)2 2sin2 x.cos2 x a

Suppose a and b are rational .

ekuk a vkSj b ifjes; la[;k,s gS vkSj .

x2 + 4ax + 4a2 = 4a2 - 2b

If the ratio in which line y x + 2 = 0 divides .

;fn js[kk y x + 2 = 0 fcUnqvksa (3,1) vkSj (8, 9) dks

Circumradius of the triangle whose .

If two points A(p, q), B(r, s) lie on the .

;fn nks fcUnq A(p, q), B(r, s) o`k x2 + y2 = 2 ij .

p + s 2ps and q2 + r2 2qr ps + qr 2

,d f=kHkqt dh ifjf=kT;k gksxh ftlds .

vf/kdre (ps + qr) = 2.1 = 2

Radius of a circle, which touches .

,d o`k tks y-v{k dks fcUnq (0, 4) ij Li'kZ .

If (x1, y1) be the centroid of the triangle .

;fn (x1, y1) funsZ'kh v{kksa vkSj js[kk L ls .

A ray of light is sent along the line 2x 3y = 5.

,d dk'k fdj.k] js[kk 2x 3y = 5 ds .

If a,b,c,d are real numbers .

;fn a,b,c,d okLrfod la[;k,a .

slope of required ray

= 2(a2 + b2 + c2 + d2) 2 (ab + c + cd + da)

ds LHS eku U;wure gS tc ab + bc + cd + da vf/kdre gS

rFkk LHS dk U;wure eku 'kwU; ds cjkcj gSA blfy, ab + bc +

vf/kdre eku gS&

Distance between the lines .

ljy js[kk;qXe 9x2 6xy + y2 + .

If sin , sin , sin are in A.P. .

;fn sin , sin , sin l- Js- esa .

fn;s x;s izfrfcE/k ds vuqlkj

cos2 = cos cos

djus ij (i),4 sin2= sin2 + sin2 + 2 sin sin

mi;ksx djus ij, 4(1 cos cos )

= 1 cos2 + 1 cos2 + 2 sin sin

homogenising the equation x2 (a + b)x + ab = 0 with the

cos2 + cos2 4 cos cos = 2 (sin sin 1)

cos2 cos2 4 cos cos

If pth, qth, rth terms of an A.P. are .

dh lgk;rk ls lehdj.k x2 (a + b)x + ab = 0 dks le?kkr