4383 Final Exam Review Packet 1, Write the names of the following elements: a.Cl b. Li eM aT - vat iod« Chlorine Lithium — Magnesium ne ©. Cr fAg g. Au h. Zn, Chromium silver gd Zac 2. Write the chemical formulas for the following: a iron Feb. cobalt C,, c.sulfur S d.carbon C e.phosphorus P f.potassium [< gin Sa h. sodium Na 3. Identify the following element, compound, homogeneous mixture or heterogeneous mixture: a. liquid bromine b. sugar ¢. lemonade chicken soup. E < Hom Mix hetero ik 4. Identify the following as examples of physical or chemical change: a. freezing of ice p b. salt dissolving in water P c. burning of a match C 4. tamishing of silver e-explosion of hydrogen gas (Cf. evaporating water 5, Complete the following table: ‘Atomic | Mass Number | Numberof | Number of | Number of | Charge Number Protons | electrons | neutrons 2B 35 aa 7a 73 o asd 0 asx 7 BA © 0 GO 30 BE 30 +2 34 50 2Y 36 46 =a 6. Write the electron configuration for each of the following. What is the highest occupied energy level? How many unpaired electrons are present? aca (20€7) u fetas® dpe 3 3p! 1s" /4/ 0 GS) Co LATE) + Wsacaptasrapeystad?/4/ 3 Ast t) &S (/oe-) jshastape3s?.ge! / 3/ a (42, 7)7. Which element ends in the following configurations: re vs? Au «58 Cm d. 2p Oo e.3s! No £42 Zp 8. Define each — 4 quantum numbers... oe their symbol and their possible values. prinupal g.a.= N= which c-/s focafed i, Ah orbitel gb 9 pihrch subene! I Yupe pg hd te Q' magnetic gn= me which orb! Fal mn Pbtec! evsiam spin n= S=direchon fe spin + S= +h oc” 9. Identify the 4 quantum numbers for elements whose differentiating electron is in: a.3sl GQ, 0/0) he ae a b.4a7 44,7! 1 A) ot (5, a ‘h) e aan @ (4 3- ~ayh) + 10, What element will have the following 4 quantumn numbers: 2.2.00,4) as'oras* Li or Be b.G,1-1,%) Spor Sp" Tn ortve (4204) Ud%o-Yd? Nb or Pd 4.(5,3,-2,%) 553 or 6e7 Th, a- OS 11. Which element O or Bis larger according to: a. atomic size? a b. ionic size? (B*3, &) c. ionization energy? d. electronegativity? -gativity’ 12, Which elemeit F or I. is larger according to: a. atomic size? {> D. ionic si a c. ionization energy? - d. electronegativity? i13, Write the names of te following ionic compounds and acids: LiCl fithium chloride b Ma3No (ragnesium nitride C.Fe03 iron (itt) eid — a Culy cop er Liiodide, ener ammonium broucles Hy00s lithium Carbonate. i Prso, lead Cit) sulPate. —n'snovog)4 Hin Civ) nitrate i:HgPog phosphoric acid j.tys hyde sulfuric acid k. HC3H30> acetic acid Lucio; chlocic acid 14, Write the formulas for the following compounds: a-soiym clrde AJ | b, oe ™, ahesphide CrP ©. a ee fs d emt GagNa . ‘droxid £ rubidium chromate moe eM, on, munich chrom mat ee Rb, GeOy copper) nose . ann h ig forget Polmads)4 ih kite oi j. chlorie acid eens Ha Helos! HC1O3 k. nitrous acid 1. carbonic acid We No,’ HNO, Ht Co 3* Hy COs 15. Draw the following electron dot structures and identify a name of its 3-D VSEPR shape: aN BCC of a ue ne! chs ae Nea gr -e-¢ linear 6 I Q5.| ret: Tetrahedre.|16, Identify the following as nonpolar, polar or ionic bonds: Electronegativities: 0-35 $-25 Si-18 C130 F-40 Na--0.3, He24 C25 Se-24 P21 Br-3.0 N-3.0 a.C—F lar b. H-N ola c.Na—cl 1on'e aS 4orhs i al-BOz 64 ff /3-300=2-7 17. Identify 5 differences between ionic and covalent compounds: Tonic Properties Covalent Properties between metal + nonmetl | between only non metals transfer of e~ chaning of 'e- : all solids Grystaliine) all 3 phases exis high melting [boiling #3 | low mp /p Ited/| Non conducters . conduch when red intile can Favm single, douple ? ple bond § 18. Convert 3.4 x 103 kg to cg: B.4x 10K (000 y 100cg = 3-4 x LOX 6g 3 | 19. Convert 5.627 mL : 4 (megaliters): 3 $627 mL, IL yIMb_ = 5.627 x10 ML 1 [000mL © \x10% L 20. In lab, you weigh a solid and find its mass to be 35.82 g. You measure 50.0 mL of water ina graduated cylinder and carefully drop the mass into the cylinder. The new volume in the cylinder is 62.8 mL. Calculate the density of your solid. Va Ga. ae — §0.0mL = /2.8mL = M.. 35:889_ 9.205 D= 72.8 mL nt. 21. Calculate as density of a rectangular block of metal which weighs 74.28 g and is 1.50 em wide, 2.18 cm high, and 8.52 cm long. Ve 80cm x aR ERG a Yew? ays Me HS a-bb 9] err: 22. How many sorties of NaC oad igh 42.8 2? ANae) Wa. BqNatl y Wot Wott boat Ae 141 x10 ples ——* Siyyiacl Imo! Nac Natl J23, What the volume of 528 x 1024 particles of Oy at STP? ; rt. ag.4lOa _ F.B8K10 part On Ninel Oo. a ny, aie /7b6L0, | .0a.x10 *part.O5 24. What is the mass of 5.42 L of CO2 at STP? EMAL COy y lmol_CO> rral CO 14-8 a = 10. og CQ, *90. Glad, = |mol CO, 25. Complete, balance and identify each oe of reaction: Synths Yin + Oo > INagO a 3 Syterre > Me + N22 > Mg,Na decomp «. QAB > ARV +38 hecomp 4 Qr03> — Py +502 sR e. als fac" > LigO a Mg SQ: Merara's MgCl * Wa GR & tak y ahel + Bry etsy DR 4 agnds + Ky > Agr + i NO, Gomtust i, Qe +70 > YCO, + GAO Combust j. cyity + 7 > YCO2+ 64,0 26. Use the following equation to answer these questions: Nar +30, > Qano; . a. How many particles of Aly03 are produced from 4.82 L or 02 at STP? 4,8ALOg Imol Oa y Ame! Als, 6.08 310" pert ADs « Bioxid 1 “Zaqboy” Smo Q "Imo! bs port. AsO b, How many grams of Al are needed to react with 3.28 x 1022 pats of On? Bx 0, 48 = 3.08y ie ‘pact + es a r ciel Bt ar | Alogfll OLY 1O m0! me! pat °Limit: Reach, How many grams of A205 ae produced fog 31.8 of Al and 4505 gO3? 3k 33g A Amt Al (mel Ale 03 Jou Be wakes (60.14 4 Aly 03) “aearaht” Geel Al emol tl 03 45. 020s, lms mol Os mba g (oleleg AAlrOs = 95-694 Alo; 21.Gilenthe feainpropions”| 2 — Wmel ALOs 2Ca + OD => 2.Ca0 Go + mo > Ca(OH)2 3.Ca(OH)2 + 2 H3PO4 <> Cax(PO4)2_ + 6 HO How many L of 0» at STP are needled to produce 55.4 g Cax(PO4)9? S54 glass Imol Cag lPOy a. y Bel CaCoWa y lore C20 y T “is 8yCag0)g. lol Cey(PO “maa” ) Comal On. y224L Oa. Amol CaO Ime! 03 G00 L Oy 28. Using your knowledge of the kinetic theory, identify which state of matter is being described in each of the following: a. particles are held together by strong attractive forces. S b. particles flow randomly but in a limited area. (0 ¢. particles are spread as far apart as possible. 4. particles have no attractive or repulsive forces. 4 ¢. particles only move around fixed points. S 8: particles can easily be affected by even slight changes in pressure or temperature, h. particles have a definite volume but not a shape. i, particles have fixed orderly structures. “S pale GK ot worm the cans. =) 29. When measuring gases, what are you really measuring when you measure volume? When ‘you measure pressure? When you measure temperature? Volume = volume ef container pressure = Force of Collisions between particles Temperdure = avera kinehe, energy of porhees (speed )30. Identify the parts of the phase diagram: —> Temperature Energy added 31. Use your knowledge of gas laws to answer the following: a, If the pressure of a gas is increased at constant temperature, the volume will: P* VL b. Ifthe temperature of a gas is decreased at constant pressure, the volume will TY Vue c. Ifthe temperature of a gas is increased at constant volume, the pressure will: TDP? € Ifthe temperate is decreased and the volumes need the pressure wil, vPY VT PL 32. If 455 mL of gas at 755 mmHg is = to a pressure of 425 mmHg. ae is the resulting volume? V455mL PLVR ve V=HS5mL yl35emly = 308mL P7155 menlts Ya. me ly P d4asmmiy 33. If 6.2 L of gas at standard temperature is heated to 252 °C, what is the resulting volume? V@atl = v THVT ye Gary SSK = al T a73k a7 K Tasa’c = SaSk 34. fw) serpsol can at STP is heated to 452°C, what is the resulting pressure in atm? Gen" Trt “Pa fader PAS = Bhs a See a73kK Gr ailebatm) 4sa°c= Ta5Kk 45.28 a1 or ‘gas is collected at a pressure of 125 kPa and 25.0 °C, what is the corrected volume STP? V 534m Tag kK V=584mL ASHP ATK = Funk. PSK Tak Oe POS eRe aa vn VVY36, How many moles of gas are found in a 350.0mL container at 1.02 atm and 35.0°C? (R= 0.0821 L¥atm/mol*K) PY= nN RT Lae nz PV. Guoratm) 6350L) _ O14 Imo) n? er Cowl & 308) R 081 LAY ok . paare T38° 208K 37. How much heat is needed to raise the temperature of 45.0 g of steam from 125°C to 325°C? (Cp= 1.7 Sg*C) - a *c) = 15300 T E=mlp BT = 95-05) (1-7-4 )(a00'0) 0 38. How much energy is needed to vaporize 35.3.g of acetone (CH3COCH3)?, (AHyap= 29.1 kl/mol) ots he _ 35. BqCHgCOCHs Imo ILKT_ (7.7 KI ee 5B,04 Leeol 39. Given the following reaction: ci + 60) > 6CO) + 6HZO + 348K) 1a, How much energy is released when 24.6 g of Cg 20¢ are burned? A469 Made , ite! yp BYERS ss ey 7 180.\% Imol GAya% b. Is this reaction endothermic of exothermic? exo (heat is a product) 40. Identify each statement as endothermic or exothermic? a.heat isaproduct EXO b. when a reaction occurs in a beaker and the beaker gets colder, E~JDO c.AHis positive £,0DO d freezing ofice EXO e.boilingof water E70) 41. What are three ee properties of water? What causes these properties to occur? high surface fasion ice Floads H—ber Is high ae Jow vapor Presswe 42. What is an electrolyte? What types of compounds are electrolytes? any Substance Wh: ‘ch banclucts when yo lH. LO = jonie Cmpds 7 acids 7 AH3 dissolved43. What is a nonelectrolyte? What types of compounds are nonelectrolytes?. Anything | toot doesn't sind when clissalved in MO polar ferlae. Call aonmetl empds 44. Ldentty the lon ife 9s Solus, colloid, or suspension: aicedtea So b. milk col c. liquid in snow globes. SUS d. mayonnaise Co) e. vinegar/oil dressing SUS P e kool-aid So mixture which doesn’t settle Sel o- Col fh. mixture which doesn’t scatter light (doesn’t show Tyndall Effect)? SO) i. mixture which can be separated with filtering SOS j. mixture which looks homogeneous but is really heterogeneous Col 45. What is the molarity of a solution if 48.0 g of KCI is dissolved in 500.0 mL of solution? —— Jmol KEL glo B%63me! "74554KCI 6000 L 1294 46. How oa grams of NaNO3 are dissolved in 450.0 mL of 2.5 Bi solution? 25m], 450 L = LAS moly 85:03, = Fog hao Jmol 47. Calculate the percent concentration (v/v) if 31.0 mL of alcohol is dissolved in 250.0 mL of solution? BlLOmt —— xX/00= /a.4 250.0mL 48. Calculate the molafity of a solution which has 62.0 g of I7 dissolved in 560.0 g of acetone. 20; Ta Imel __ 244 a8Rnm! 9304 / 453. 613 —7st0 Ks 49. 1£ 75.0 g of AIBr3 is dissolved into 400.0 g of water, what will the new freezing point be? (Kp= 1.86°C/m) T5iOghlOg \mrol Ales 9813590! _ Dam 1 * Alolo-665 Als 790 Ka ATs Kew n= 1¥lo"/m(-103Y(4) = 5-23 °C PP: &°-5.2a" = -5aa'e: 10 50. Use the following chart to answer the questions: Solute per 100 g of H,0 (9) Cee = 0 10 20 30 40 50 GO 70 00 90 100 Temperature (°C) a, How many grams of KC1O3 will dissolve in 100 g of water at 100°C? dg b. How many grams of KCI will dissolve in 400 g of water at 30°C? 3, 54 *Y INO, c. Which salt is least soluble at °C? [4 C10 a, 4. What type of solution (saturated, unsaturated, or supersaturated) do you have if a. 40 g of KCIO3 is dissolved in 100 g of water at 30°C? Super b. 40 g of NaNO3 is dissolved in 50 g of water at 10°C?(> $04 1» 1005) Sojuc ¢. 210 g of KNO3 is dissolved in 200 g of water at 40°C? super Game 43 1054 in 1005)