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Catalyst Manufacturing

Science and
Engineering
Consortium (CMSEC)
Rutgers University
New Jersey, U.S.A.

Rutgers Catalyst Manufacturing Science and Engineering Consortium (CMSEC)


Rutgers
Catalyst
Consortium
since 2003

Current and Past


Industrial
Members:
Albemarle
Chevron
Haldor Topsoe
Exxon-Mobil
BASF
Grace
Evonik
UOP
Johnson Matthey
CRI/Criterion Inc.

Projects:
Impregnation of
Catalysts
Drying of
Supported
Catalysts
Powder
Segregation
Powder Flow,
Handling and
Characterization
Calcination
Mulling and
Extrusion
Slurry Mixing
Continuous
Powder
Blending
Contact:
Prof. Ben Glasser
Tel: 848-445-4243
bglasser@rutgers.edu

While a large segment of the US industry,


including the petroleum, chemical,
pharmaceutical, automotive, and energy
industries makes and/or uses catalysts, there
has been no academic program focusing on
the operations required to make catalytic
materials. Thus, catalyst manufacturing
processes are often designed relying on
empiricism, leading to uncertain/suboptimal processes, decreased quality, and
increased cost. By combining the substantial
level of expertise in particle technology,
optimization, multi-scale simulation,
catalysis and molecular modeling available
at Rutgers, we are developing and promoting
science-based methods for designing and
optimizing catalyst manufacturing methods
and processes such as impregnation, drying,
slurry mixing, extrusion, calcination, etc.
This is integrated with a number of
educational activities including research
training of undergraduate students, graduate
students and postdoctoral fellows in the area
of Catalyst Manufacturing. A combination of
experiments and computer models has been
used to improve the understanding and
performance of the unit operations used to
make catalysts. This knowledge, and the
resulting methods and practices, have been
transferred to Industrial partners to help
transform this important segment of the
global economy into a science-driven
enterprise. The specific goals of the
consortium are:
To create a world-wide prime Center of
Excellence in catalyst manufacturing
research.
To enhance fundamental understanding
of catalyst manufacturing operations.
To develop new technology for efficient
catalyst manufacturing.
To provide a research, development, and
education resource for industry.
The consortium was founded on October 1,
2003. The Rutgers faculty that are currently
participating in the consortium and their
expertise areas are: Benjamin J. Glasser
(drying, fluidized beds), Johannes G.
Khinast (drying, catalysis), Fernando J.
Muzzio (particle technology, mixing), Arthur
Chester (industrial liaison, catalyst
preparation), William Borghard
(calcination, catalyst preparation), Silvina
Tomassone (impregnation, interfaces),
Alberto Cuitino (particle technology,

compaction), and Rohit Ramachandran


(particle technology, agglomeration).
The annual fee for membership in the
consortium is $35,000. These are
unrestricted funds for research. The
consortium members (companies and
faculty) meet every 6 months (October and
March) for project reviews. In the October
meeting, the consortium decides on
continuing with current projects or starting
new projects. Where consensus is not
possible, a vote is taken, with each company
getting one vote. Copies of the slides from
the talks at the consortium meeting are
made available to the consortium members.
In addition, each project provides a written
report on progress every six months.
A list of possible manufacturing operations
of interest to the consortium is given below:
Powder blending, Powder sampling,
Calcination, Slurry Mixing, Pellet
compaction, Roller Compaction, Powder
segregation, Catalyst drying, NonNewtonian Liquid Mixing, Powder
Flow/Handling, Multiphase Flow/CFD,
Dispersion of solids, Impregnation, Mulling,
Extrusion , Nano-templating, Fluidized bed
coating, Granulation, Catalysis, Spray
Drying, Atomization, Flash/Rotary
Drying/Calcination, Plow-shear mixing,
Liquid-Solid Separation
(Filtration/Flocculation), Precipitation
Catalysts.
Projects that are currently funded by
CMSEC are:
Impregnation of Catalysts
Drying of Supported Catalysts
Calcination
Powder Flow, Handling and
Characterization
Sensing of Mulling Operations
Projects that have been funded by
CMSEC in the past include:
Powder Segregation
Mulling/Extrusion of Catalyst Supports
Slurry Mixing
Continuous Powder Blending
A description of projects that have been
funded by CMSEC follows.

Impregnation of Catalysts

spraying of water droplets on a flowing powder bed


and the allowance of catalyst support particles to
absorb the water, thus increasing weight and
density; Figure 1 shows an example of fluid spraying
onto a powder bed.
Furthermore, cohesive
properties have been taken into account and allow
for a linear increase as a function of maximum
support capacity. Experimental techniques are used
to validate computational models by measuring

Catalyst impregnation is a crucial process in the


preparation of industrial catalysts. In this process,
metal salts or complexes are dissolved in a typically
aqueous solution and contacted with a porous oxide
catalyst support such as alumina (Al2O3) or silica
(SiO2). During a contact time of typically 30-60
minutes the metal is adsorbed from the solution
onto the high surface area support. The
catalyst is dried and further pretreated to
transform the metal from its precursor
state into its active form. Generally, the
process of impregnation is performed in
rotating vessels with one or more nozzles
that distribute the solution with the
metal precursor into the catalyst
support. The process is typically referred
to as dry impregnation as the amount of Figure 2: Experimental impregnation study using 3 x 6 mm
liquid sprayed onto the catalyst bed is alumina pellets dyed for a concurrent mixing/impregnation study.
kept at a minimum, and thus, the bed
continues to operate as a granular bed.
water content as a function of time in specific spray
The ability to control dry impregnations and
zones.
In addition, mixing experiments are
establish effective models for large batches can
performed to better understand the relationship
significantly reduce the amount of time required per
between spray flow rate and its effect on the
batch while simultaneously achieving a more
catalysts bed distribution; an example is shown in
homogeneous distribution of solution.
Figure 2. The main goals of this project are to
establish 1) how mixing and flow are affected when
the particles have a certain degree of moisture or are
In this work, a
saturated with liquid, 2) whether the liquid is
combination study
homogeneously distributed into the powder bed and
incorporating
a
3) the extent and distribution of dead zones for a
series
of
given impregnator configuration and 4) to establish
experiments as well
a scalable model that can be quickly applied to
as particle dynamic
impregnation processes for optimal mixing and
simulations
are
liquid distribution.
performed using a
double
cone
impregnator
in
order to obtain a
deeper

Drying of Supported Catalysts


understanding of
the mixing and Figure 1: Particle dynamic
Supported catalysts are essential components in a
simulation of double cone
impregnation
variety of industrial processes, ranging from
mechanisms.
A impregnator. A fan shaped
catalytic converters to production of new drugs. The
spray pattern is shown.
computational
performance of a catalytic process is intimately
study is performed using the discrete element
related to the catalyst design - uniform, egg-yolk,
method (DEM).
Commercial software (EDEM,
egg-shell and egg-white metal profiles. It is generally
DEMSolutions Inc.) is used to facilitate technology
believed that the metal profile is controlled by the
transfer. Algorithms are being used to allow for the

conditions that are applied during impregnation


where the metal contacts the solid support for the
first time. However, experiments have shown that
drying may also significantly impact the metal
distribution within the support. Therefore, to
achieve a desired metal profile we need to
understand both impregnation and drying.
Controlling the drying conditions can enhance
catalyst performance.
The goal of this project is to develop a
fundamental understanding of unit operations
during catalyst preparation, and predict, control
and optimize metal distribution and dispersion of
supported catalysts. Therefore, we can provide our
partners with efficient tools to monitor and
control the final quality of supported catalysts. In
this work we have developed a theoretical model
for
drying
which
we
have
validated
experimentally. In this model, we have taken into
account heat transfer from the hot air to the wet
support, solvent evaporation in the support,
convective flow towards the support external
surface due to the capillary force, and metal
diffusion and metal deposition due to adsorption
and crystallization (see Figure 3a). In general, the
convective flow is the main driving force to
transport the metal component and the solvent
towards the support external surface (t=500s in
Figure 3b), while the back-diffusion causes metal
to transport towards the support center (t=1000s
in Figure 3b). Experiments have been carried out
to measure the distribution and dispersion of
metal in catalyst supports in order to validate our
modeling work. In Figure 3c, the metal profiles
after drying are plotted from the support center to
the surface for Ni/Alumina catalysts, where
symbols represent experimental data and solid
lines represent simulation results. It is clear that a
nearly uniform distribution is observed for low
drying temperature while egg-shell profiles can be
greatly enhanced with increasing the drying rate.
In this project, we have examined the distribution
and dispersion of Nickel, Copper, Barium, and/or
Palladium on Alumina and Silica. We are interested
in investigating the importance of the physical
properties of the solid support (porosity, pore size
distribution, particle size) and liquid solution (pH,
ionic
strength,
initial
metal
precursor

concentration), and the nature of interactions that


exist between the dissolved metal and the solid
support (physical adsorption, crystallization, ion
exchange, film-breakage, pore-blockage) on the
distribution and dispersion of the active metal.

dispersed gas
(hot gas + vapor solvent)

heat
supplied by the hot gas

precipitated
or adsorbed
solute

solvent
evaporation

solid
support

liquid phase
(solvent +metal)
convective
back-diffusion
flow
dissolved solute
(salt or metal) (capillary flow)

(a)
Metal Profile
after impregnation
t=0s

t=500s

t=100s

End of drying
t=1000s

(b)

(c)
Figure 3: (a) drying mechanism, (b) simulation of the
evolution of the metal distribution during drying, (c)
comparison of simulation and experiments for drying of
Ni/Alumina catalysts.

Powder Segregation

separated material can be as much as 90% pure in


either example.

In the production of catalysts, granular materials


In this project, we focus on developing a predictive
and powders (e.g. silica, alumina) which differ in
understanding
of
conditions
under
which
size, density, shape and surface properties are often
segregation
will
and
will
not
occur
in
tumblers,
blended together. When such granular materials or
shear cells, and discharge devices.
We are
powders are transported, tumbled or discharged,
particularly
interested
in
providing
measurement
they often exhibit a tendency to spontaneously
techniques to establish in advance whether a
separate. The goal of this project is to investigate
material will separate, and in engineering control
the segregational tendencies of granular materials
approaches to modify either equipment or material
and powders used in catalyst manufacturing. We
choices to minimize segregation in catalysis
seek especially to evaluate segregation in side-byoperations.
side simulations and experiments, matched by size,
interaction properties and
geometry. The specific aims
of this project are: 1) to
generate
a
predictive
understanding
of
segregation mechanisms 2)
to provide strategies for
deliberate control over
segregation vs. mixing
states 3) to generate
predictive rules for when
segregation or mixing will
occur.
More
broadly,

through the execution of


this project, we seek to
(a)
(b)
analyze
the
interplay
between
particle Figure 4: Spontaneous granular segregation. (a) Separation of differently sized
interactions on the small- grains occurs in a double cone blender (shown at top). Depending on fill level
scale and aggregate and and rotation speed, multiple segregated outcomes are possible: small-out, shown
at left-bottom, small-in, at right-bottom, or half-and-half, shown at right-bottom.
mixing states on the macroThe mechanism here for ideal, laboratory, materials is relatively well understood
scale, thus improving the and relates to a competition between inertia of the tumbling particles and sifting
control
over
particle of the smaller particles beneath the larger. (b) Separation of mechanically
properties and additive identical particles can also occur due to minor changes in surface coatings, as
choices that optimize flow illustrated in this example where differences in surface dyes on irregular silica
causes strong spontaneous segregation during feeding.
and mixing performance.
Solids separate based on differences in size, shape,
density or surface composition. As two examples, in
Figure 4(a) we show separation of spherical particles
tumbled in a double cone blender, and in Figure 4(b)
we show separation of irregular silica particles fed
from a vibratory feeder. In the latter example, the
grains are identical in size, shape and bulk
composition, but differ in surface coating leading to
promote spontaneous electrostatic separation. In
both cases, the segregation mechanism is subtle, but
the result is profound and indisputable: the

Powder Flow, Handling and


Characterization
The goal of this project is to develop a fundamental
understanding of granular and powder flow and
shear properties, so that the behavior of
intermediate and final catalyst products during
manufacturing and processing can be predicted and
controlled. The techniques and
methods investigated in this project
could provide our partners with
valuable tools and ideas to
efficiently design and scale catalyst
manufacturing processes.

techniques. This project is also set to investigate the


ability of the characterization methods to predict the
powders process behavior by examining the flow
from bench scale hoppers. The study has found that
there is a discernible correlation between the
measurement techniques (shown in Figure 5) in
characterization of catalyst blends. We also
confirmed
that
the
generally
accepted

Powders and granular materials can


be found in many processing steps
in catalyst manufacturing; they
exhibit a variety of flow patterns,
and their state and behavior differs

from application to application.


(a)
(b)
Since there is a lack of fundamental
understanding of powder behavior, Figure 5: Images of (a) Gravitational Displacement Rheometer (GDR)
multiple
problems
can
be and (b) shear cell module.
encountered during production,
characterization methods, such as shear cell, have
such as jamming of hoppers, sub-standard blending
range limitations, when evaluating extremely
performance, and weight variability of final products
cohesive or very free-flowing powders and such
due to segregation and/or agglomeration. Scale-up
methods are not always applicable in the case of
can also be a challenge, since the lack of constitutive
unconfined flow conditions. It is also of interest to
equations for granular materials forces most scaleinvestigate how various material factors change the
up efforts to follow the trial-and-error route. There
flow properties of the catalytic powders, such as
are numerous methods to characterize the flow
presence of moisture or flow-modifying agents.
properties of granular materials, such as
avalanching testers, fluidizers, shear cells, indicizers,
density methods, angle of repose, etc.; however,
most of them are application-specific, and it is not
clear, how they correlate with each other or with
process performance. For this reason, the use of
Calcination
most of these testers is restricted to a specific
application, for which they were designed, and any
Calcination is a thermal treatment process applied
attempts to apply the results of such experiments to
to ores and other solid materials in order to bring
a different application frequently result in process
about a thermal decomposition, phase transition, or
problems.
removal of a volatile fraction. Calciners can be of
In this work, we have created a family of standard
catalyst materials, spanning a wide range of flow
properties from very cohesive to free-flowing. We
then used the characterization equipment to
investigate the flow properties of these materials and
to determine the correlations between the

batch type as well as continuous type. Calcination is


a crucial operation in catalyst manufacturing.
Developing better process level understanding of
this operation can significantly improve the quality
of the end product as well as save energy and
material costs. However due to the nature of the

operations, it is not always practical to do detailed


and baffle effects on heat transfer, effect of radiation
experimental studies.
There are limitations
due to material and
device availability, high
temperature
requirements, sampling
issues,
time
and
personnel related costs.
Computer
modeling
and
process
simulations have made

great progress in recent


years. It is now possible
(a) (b)
to
design
realistic
models of devices and Figure 6: (a) Side view of the aluminum calciner. 10 thermocouples were inserted
simulate
their within the calciner through the Teflon made side-wall. (b) shows the complete
performance at actual experimental set-up. Calciner rests on the computer controlled rollers. The
thermocouples were connected to the Omega 10 channel data logger, which is hooked
scale.
The
discrete
to the computer.
element method (DEM)
heat and material wetness. Experimental studies can
based force models have also received significant
be performed to validate the simulation methods as
enhancements which not only ensure better dynamic
was done in the case of a rotary calciner as shown in
modeling but also
Figure 6. The corresponding simulation results are
allow for heat and
shown in Figure 7.
humidity
transfer
algorithms.
A
In addition to rotary calciners, continuous calciners
commercial
DEM
can also be studied using such simulations as shown
software
package
in Figure 8. The parametric space and flow/mixing
called EDEM by
dynamic is partly different for a continuous calciner.
DEMSolutions Inc.
The device tilt angles, rotation speed, particle size
has simplified such
and wetness determine the flow behavior. DEM

modeling
and
models can simulate a number of cases to arrive at
Figure 7: Axial snapshot of
simulation
optimal values of such parameters and the associate
problems. Ability to color coded particles in the
effect on the output particles.
use extended user calciner from simulation.
(blue: low temperature ;
The following are the key observations from the
defined
dynamics
green: intermediate and
studies performed in this project so far.
allows
complex red: high temperature)
calculations such as
1) Detailed studies of heat transfer mechanisms
interparticle
and
in rotary calciners were done using DEM
particle-boundary heat and mass transfer. Such
simulations validated with experimental
models allow detailed studies spanning a wide
data. The vessel rotation speed was found to
parametric space and elucidate the effect of the
have no significant impact on the heat
various
critical
parameters
such
as

mixing
rates,
Figure 8: Particle dynamic simulation of heating of particles in a rotary continuous calciner.
calciner wall

transfer at both low and high Froude number


regimes. The fill level had a moderate effect
on heat transfer, suggesting that higher
fill levels might be effective in practice.

in the preparation of catalytic supports, high


temperature ceramics and composites.

2) Average wall-to-solid heat transfer


coefficient was estimated based on
experimental observations for use in
simulations.
3) The addition of baffles in the rotary
calciner was found to have a significant
effect on the heat transfer due to
improvement
in
the
mixing.
Furthermore, heated baffles enhanced
the calcination significantly as compared
to adiabatic baffles.
4) Radiation from the calciner walls was
found to have a significant effect on Figure 9: Porosity analysis obtained from Non-Local
calcination. Walls with higher emissivity Density Function Theory (NLDFT).
affected the average bed temperature as
In this project, a laboratory high shear mixer was
well as the distribution of temperature in the
used to prepare the pre-extrusion samples, which
particle bed. Cohesion in the particle also
were then extruded with a simple Carver press;
had a significant effect on the temperature
powders and extrudates were characterized both
uniformity of the bed. In highly cohesive
prior to and after calcination as a function of mixing
cases, the particle drying happened in two
time by a variety of techniques, including FTIR,
distinct time-separated regimes as opposed
Powder XRD, high resolution porosimetry and
to linear drying in free flowing materials.
paricle size analysis, among others. Not much
A short study on continuous calciners was
performed. The effect of speed was found to be
significant.

Mulling/Extrusion of
Catalyst Supports
Mulling/Extrusion is one of the most efficient
techniques for producing objects with constant cross
section and with high symmetry such as rods, tubes,
honeycomb structures and channels. The extruded
products find applications in catalyst supports, heat
exchanger tubes etc. Most catalysts used in the
petrochemical and petroleum industries consist of
metals supported on -alumina pellets or spheres.
The -alumina is formed by calcination of boehmite
(-alumina monohydrate, AlOOH) at 500-550C.
Boehmite is one of the most widely used precursors

literature is available with regards to the


fundamental chemistry occurring during alumina
mulling prior to extrusion using a high shear mixer.
The purpose of the high speed granulation is to
improve the properties of the feed powder. It can
improve handling properties of a powder, reduce
dust formation, eliminate segregation of two
powders, improve powder solubility, and improve
the extruded product properties-porosity and
strength. Powder XRD line widths suggested that
crystallite size was increasing during the high shear
mixing operation, even though average particle sizes
were significantly decreasing. Of particular interest,
porosimetry indicated that the very high shear
(Fukae) mixer used in the lab produced a bimodal
pore distribution, whereas a larger scale industrial
mixer (Eirich) did not, as shown in Figure 9.

Slurry Mixing
The goal of this project is to study the mixing
dynamics of slurries used to make catalyst supports.
It is important to have homogeneity throughout the
mixing domain so that all the catalyst supports have
the same properties. To this end, it is necessary to
characterize exactly what is going on inside these
high solids loading, low moisture fluids. This will
help optimize available systems as well as potentially
help toward designing new ones.
In this project, we have produced experiments and
simulations to assess rates, optimal conditions, and

Newtonian fluid formulations. Figure 10 shows


typical results from numerous simulations and
experiments performed through the RutgersIndustry collaboration.
Findings of this research include the following.
-

Experiments reveal that zeolite and kaolin


powders do not mix well in suspension, and
appear to exhibit tendencies to separate
under vigorous agitation.
A transparent surrogate material was
developed
with
similar
rheological
characteristics to those seen in slurries of
interest.

(a)

(b)

(c)

(d)

Figure 10: Typical experiments and simulations of catalysis mixing. (a) Stirred tank geometry using
pitched blade impellers. Both experiments and simulations share the same geometry, and both use nonNewtonian fluids exhibiting the same power law stress-strain rate dependence. (b) Computational
Fluid Dynamic (CFD) simulation of dye mixing in Poincare section: i.e. intersections of fluid
trajectories striking a plane through the center of the tank (hatched plane in panel (a)). Notice that a
compartment of flow is present near the central axis of the tank, within which mixing is slow and
contained. (c) 3D CFD of flow following injection of a bolus of material near bottom of tank. The
bolus (red) is transported around the tank as the impellers turn, but vertical transport is considerably
slower. (d) Multiple dye injection experiment performed to validate simulations confirms that there is
a central compartment (red dye) that is separated from a second outer compartment (green dye).
Mixing within either compartment is comparatively fast, however mixing between compartments is
considerably slower. This compartmentalization persists across scales in both simulations and
experiments.
scaling relations for the mixing of slurries of
- Computational Fluid Dynamic simulations
materials relevant to catalysis manufacture.
were performed to analyze mixing rates,
Research focused on mixing in tanks stirred with
dependencies on injection location (for
pitched blade impellers, and materials studied
example of binders or other additives), and
include zeolite, kaolin, and power-law nonscale-up behaviors of slurry mixing.

Experiments and simulations both produce


similar
compartmentalized
flow
with
strongly separated internal and external
mixing regions. Although mixing within
each compartment is comparatively efficient,
a bottleneck between the compartments
renders mixing between compartments
nearly nonexistent.
Empirical scaling relations were produced to
permit relating bench-scale experiments to
pilot-scale and larger mixing.
It was
determined that by by varying impeller speed
as well as mixing time, one can achieve
dynamical similarity in large as well as small
mixing tanks of similar geometric ratios.

Continuous Powder Blending


In the catalyst industry, quantification of
mixing rates and mixing performance
of
powders is crucial for final product properties
and performance, and online monitoring is
always more attractive than offline approaches.
In this project a new continuous mixer was
designed and implemented to examine
homogenization of materials used in catalyst
formulations. Experiments were carried out (1)
to identify formulations of variable cohesion,
consisting of mixtures of silica, alumina, and
zeolites with various particle sizes, selected in
collaboration with our sponsors, (2) to develop
analytical methods, based on NIR spectrometry,
suited for fast and inexpensive analysis of blend
samples, and adaptable for on-line monitoring,
and (3) to examine the performance of blending
operations as a function of essential process
parameters (processing flow rate, blend
composition, agitator speed). Results of this
project include: (1) Quantification of mixing
rates and mixing performance in new
processing equipment relevant to sponsor
members was determined as a function of blend
cohesion, fill level, blender speed, and flow rate.
(2) A family of standard formulations, suitable
for examining the effects of blend cohesion in
other systems and supplemented by validated

NIR analytical methods was developed as well as


analytical methods suitable for online monitoring.
The new continuous dry blender device used in this
project is shown in Figure 11a. As material enters the
mixer, the powder passes the pathway of several
impellers. Convection is the primary source of
mixing, since a series of impellers exist around the
axial length of the horizontal cylinder. The
equipment has three innovative design features: (1)
The system considered in this study has the
flexibility of adjusting the angle at which the mixer
processes (see Figure 11a). The combination of the
blender angle and blade angle controls the degree of
back-mixing to axial convection, and determines the
number of theoretical equivalent stirred tanks
along the axis of the mixer. (2) The powder is
discharged through a screen (see Figure 11a). This
feature ensures that agglomerates are destroyed in
the mixer. By varying the mesh of this screen,
different degrees of micro-homogeneity can be
accomplished. (3) The powders leaving the mixer

(a)

(b)

(c)

Figure 11: (a) GEA Buck Systems Continuous Dry Blender


with Innovative features, (b) schematic of the continuous
mixer with two vibratory feeders, (c) image illustrating
powder hold-up inside the continuous mixer.

may also re-enter as a recycle stream. Standard


catalytic materials of varying cohesion were tested in
this work. The main observations are as follows: (1)
Mixing performance is largely limited by the quality
of the feeders. As shown in Figure 11(b), two Eriez
vibratory feeders were used to feed the powder into
the mixer. (2) Mixing quality improves with
residence time. (3) The number and spacing of
blades plays a critical role in minimizing stagnant
regions in the blender. (4) Mixing is better at higher
speeds. (5) Incline angle has an effect on
performance, but results at this point do not display
a simple trend. (6) Electrostatic agglomeration of
cohesive powders on the surface of blades was
observed. the cohesive powders then accumulated in
stagnant
regions,
strongly
affecting
the
concentration of the discharge stream (see Figure
11c).

ContactInformation:
ProfessorBenjaminGlasser,DirectorCMSEC,bglasser@rutgers.edu
Dr.ArthurChester,IndustrialLiaisonCMSEC,achester@rci.rutgers.edu
DepartmentofChemicalandBiochemicalEngineering
RutgersUniversity
98BrettRoad
Piscataway,NJ088548058,USA
Phone:(848)4454243;Fax:(732)4452581
Website:http://sol.rutgers.edu/catalyst

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