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Science and
Engineering
Consortium (CMSEC)
Rutgers University
New Jersey, U.S.A.
Projects:
Impregnation of
Catalysts
Drying of
Supported
Catalysts
Powder
Segregation
Powder Flow,
Handling and
Characterization
Calcination
Mulling and
Extrusion
Slurry Mixing
Continuous
Powder
Blending
Contact:
Prof. Ben Glasser
Tel: 848-445-4243
bglasser@rutgers.edu
Impregnation of Catalysts
dispersed gas
(hot gas + vapor solvent)
heat
supplied by the hot gas
precipitated
or adsorbed
solute
solvent
evaporation
solid
support
liquid phase
(solvent +metal)
convective
back-diffusion
flow
dissolved solute
(salt or metal) (capillary flow)
(a)
Metal Profile
after impregnation
t=0s
t=500s
t=100s
End of drying
t=1000s
(b)
(c)
Figure 3: (a) drying mechanism, (b) simulation of the
evolution of the metal distribution during drying, (c)
comparison of simulation and experiments for drying of
Ni/Alumina catalysts.
Powder Segregation
modeling
and
models can simulate a number of cases to arrive at
Figure 7: Axial snapshot of
simulation
optimal values of such parameters and the associate
problems. Ability to color coded particles in the
effect on the output particles.
use extended user calciner from simulation.
(blue: low temperature ;
The following are the key observations from the
defined
dynamics
green: intermediate and
studies performed in this project so far.
allows
complex red: high temperature)
calculations such as
1) Detailed studies of heat transfer mechanisms
interparticle
and
in rotary calciners were done using DEM
particle-boundary heat and mass transfer. Such
simulations validated with experimental
models allow detailed studies spanning a wide
data. The vessel rotation speed was found to
parametric space and elucidate the effect of the
have no significant impact on the heat
various
critical
parameters
such
as
mixing
rates,
Figure 8: Particle dynamic simulation of heating of particles in a rotary continuous calciner.
calciner wall
Mulling/Extrusion of
Catalyst Supports
Mulling/Extrusion is one of the most efficient
techniques for producing objects with constant cross
section and with high symmetry such as rods, tubes,
honeycomb structures and channels. The extruded
products find applications in catalyst supports, heat
exchanger tubes etc. Most catalysts used in the
petrochemical and petroleum industries consist of
metals supported on -alumina pellets or spheres.
The -alumina is formed by calcination of boehmite
(-alumina monohydrate, AlOOH) at 500-550C.
Boehmite is one of the most widely used precursors
Slurry Mixing
The goal of this project is to study the mixing
dynamics of slurries used to make catalyst supports.
It is important to have homogeneity throughout the
mixing domain so that all the catalyst supports have
the same properties. To this end, it is necessary to
characterize exactly what is going on inside these
high solids loading, low moisture fluids. This will
help optimize available systems as well as potentially
help toward designing new ones.
In this project, we have produced experiments and
simulations to assess rates, optimal conditions, and
(a)
(b)
(c)
(d)
Figure 10: Typical experiments and simulations of catalysis mixing. (a) Stirred tank geometry using
pitched blade impellers. Both experiments and simulations share the same geometry, and both use nonNewtonian fluids exhibiting the same power law stress-strain rate dependence. (b) Computational
Fluid Dynamic (CFD) simulation of dye mixing in Poincare section: i.e. intersections of fluid
trajectories striking a plane through the center of the tank (hatched plane in panel (a)). Notice that a
compartment of flow is present near the central axis of the tank, within which mixing is slow and
contained. (c) 3D CFD of flow following injection of a bolus of material near bottom of tank. The
bolus (red) is transported around the tank as the impellers turn, but vertical transport is considerably
slower. (d) Multiple dye injection experiment performed to validate simulations confirms that there is
a central compartment (red dye) that is separated from a second outer compartment (green dye).
Mixing within either compartment is comparatively fast, however mixing between compartments is
considerably slower. This compartmentalization persists across scales in both simulations and
experiments.
scaling relations for the mixing of slurries of
- Computational Fluid Dynamic simulations
materials relevant to catalysis manufacture.
were performed to analyze mixing rates,
Research focused on mixing in tanks stirred with
dependencies on injection location (for
pitched blade impellers, and materials studied
example of binders or other additives), and
include zeolite, kaolin, and power-law nonscale-up behaviors of slurry mixing.
(a)
(b)
(c)
ContactInformation:
ProfessorBenjaminGlasser,DirectorCMSEC,bglasser@rutgers.edu
Dr.ArthurChester,IndustrialLiaisonCMSEC,achester@rci.rutgers.edu
DepartmentofChemicalandBiochemicalEngineering
RutgersUniversity
98BrettRoad
Piscataway,NJ088548058,USA
Phone:(848)4454243;Fax:(732)4452581
Website:http://sol.rutgers.edu/catalyst