1.

0.40g of an organic compound gave 0.3g of Ag Br by Carius method. Find

the percentage of bromine in the compound

2.

In which C C bond of CH3CH2CH2Br, the inductive effect is expected to be

the least?

3.

Which technique can be used for purification of iodine that contains traces
of NaCl?

4.

What is the basic principle of chromatography?

5.

How will you separate a mixture of two organic compounds which have
different solubilitys in the same solvent?

6.

Write resonance structures of

(a) CH3COO

(b) C6H5NH2
(c) CH3 NO2
(d) C6H5OH
7.

Explain why is (CH3)3 C+ more stable than CH3CH2+ and CH3+

8.

Show how hyper conjugation occurs in propene molecule.

9.

How will you bring out the following convertions ?

I) Benzene to ortho nitro bromobenzene
Ii) Acetylene to acetophenone
Iii) Ethane to ethylalcohol
Iv) Phenol to paranitrotoluene
V) Aniline to benzene sulphonic acid

10. Write brief notes on

i) Ozonolysis
ii) Decarboxylation
iii) Friedelcrafts reaction
iv) Dehydrohalogenation
v) Markovnikovs rule