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NielsPedersen
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CombustibleDust
FireandExplosion
Fundamentals
FireTriangle
Air
O2
Fuel
HC
Igniter
>MIT
Deflagration
Dustinsuspension
Air
O2
Fuel
HC
Igniter
>MIT
ExplosionPentagon
Confinement
Air
O2
Fuel
HC
Igniter
>MIT
Background
OrganicDustFiresandExplosions:
Massachusetts
(3killed,9injured)
NorthCarolina
(6killed,38injured)
Kentucky
(7killed,37injured
MetalDustFireandExplosion:Indiana
(1killed,1injured)
OrganicDustFireandExplosion
Jahn Foundry, Springfield, MA
Massachusetts
Fireinafoundryshellmoldingmachine:
Causedaprimaryexplosionin
ductscontainingheavy
depositsofPhenol
formaldehyderesin dust.
Resultedin
a dust cloud from ledge
dust deposits outside the
ducts and
an explosion in the plant
area.
3 dead, 9 Injured
9
OrganicDustFireandExplosion
Massachusetts
Causal factors
Housekeeping tocontrol
dustaccumulations;
Ventilationsystem
design;
Maintenance ofovens;
and,
Equipmentsafety
devices.
1
0
OrganicDustFireandExplosion:NorthCarolina
Afireattheplantcaused
dusttobedispersedand
explodeintheceiling
space
6werekilled,38injured
Plantandnearbybuildings
wereseverelydamaged
1
1
ExperienceintheGrainHandlingIndustry
Inthelate1970s,graindustexplosionsleft59peopledead
and49injured.
1
2
ExperienceintheGrainHandlingIndustry
In1987,OSHApromulgatedtheGrainHandlingFacilities
standard(29CFR1910.272)stillineffect.
1
3
1
4
ImperialSugarCompany,PortWentworthGA.
ExplosionandFire
Feb.7,2008
13DeadandNumerousseriousinjuries
1
5
ExamplesofCombustibleDustIncidents
CASCADINGEXPLOSIONS
Dustexplosioninaworkarea
Dust
Some event
disturbs the
settled dust
into a cloud
Dust cloud is
ignited and
explodes
SecondaryDeflagrationispropagated
throughthedustclouds
Secondary
deflagration bursts
from the building
DEFLAGRATION
DEMONSTRATION
BasicComDust data
Thehazardismanageablewithproperengineeringdesigns
usingtheproductspecificdata
Dataisestablishedthorough:
1. Actualtestofproductsused/producedinaspecific
process dusttestdata
29
DefinitionsofDustTestData
DustClass(ST)
ST0,ST1,ST2,ST3
VolumeNormalizedRateofPressureincrease(Kst)
Thedeflagrationindexofadustcloud.
RateofPressureRise(dP/dt)
Theincreaseinpressuredividedbythetimeintervalnecessaryforthat
increasetooccur.
MaximumRateofPressureRise[(dP/dt)max]
Theslopeofthesteepestpartofthepressureversustimecurve
recordedduringdeflagrationinaclosedvessel.
30
DefinitionsofDustTestData
MaximumPressure(Pmax)
Themaximumpressuredevelopedinacontaineddeflagrationofan
optimummixture.
MinimumExplosiveConcentration(MEC)
Theminimumconcentrationofacombustibledustcloudthatis
capableofpropagatingadeflagrationthroughauniformmixtureof
thedustandairunderthespecifiedconditionsoftest.
MinimumIgnitionEnergy(MIE)
Theminimumamountofenergyreleasedatapointinacombustible
mixturethatcausesflamepropagationawayfromthepoint,under
specifiedtestconditions.
DefinitionsofDustTestData
MinimumIgnitionTemperature(MIT)
Minimumignitiontemperatureofahotsurfacecapableofcausing
ignitionofdustinsuspension.
LayerignitiontemperatureorAutoIgnitionTemperature(AIT)
Temperatureatwhichadustlayerignitesonahotsurface(1/2
thicknesstestbase)
LimitingOxygenConcentration(LOC)
Todeterminethehighestoxygenconcentrationatwhichignitionofa
disperseddustatambienttemperatureandpressureisnot possible.
32
DefinitionsofDustTestData
ElectricalVolumeResistivity(Rv)
Themeasureofhoweasilyelectricalchargecanflowthroughthe
particulate.
ChargeRelaxationTime
Thetimeittakeforachargetodecreaseto0.37xitsinitialvalue.
PowderChargeability
Thechargeperunitmassthatcanbedevelopedonaspecificmaterial
duringprocessing
DefinitionsofDustTestData
BurnRate
Theflammabilityanddegreeofcombustibilityofmetalpowder/dust
ThermalStability
Processriskathigheroperatingtemperaturesandstorageconditions.
WaterReactivity
Amaterialthatchemicallyreactswithwater,producinganother
compoundthatcanrepresentadifferentsetoffireprotection
concerns
WaterIncompatible
Amaterialthatdoesnotchemicallyreactwithwater,butwhich
undergoesachangeofphaseorstateuponmixturewithwaterthat
rendersitpermanentlychangedorincompatiblewiththeremainder
oftheprocess
34
DefinitionofEquipmentData
VentedExplosionPressure(Pred)
Themaximumpressuredevelopedinaventedenclosureduringa
venteddeflagration
EnclosureStrength(Pes)
Uptotwothirdstheultimatestrengthforlowstrengthenclosures;for
highstrengthenclosurestheenclosuredesignpressuresufficientto
resistPred.
UltimateStrength
Thepressurethatresultsinthefailureoftheweakeststructural
componentofanenclosure.
StaticActivationPressure(Pstat)
Pressurethatactivatesaventclosurewhenthepressureisincreased
slowly(witharateofpressureriselessthan0.1bar/min=1.5
psi/min).
35
DefinitionofEquipmentData
AirMaterialSeparator(AMS)
Acollectordesignedtoseparatetheconveyingairfromthematerial
beingconveyed.
AirMovingDevice(AMD)
Apowerdrivenfan,blower,orotherdevicethatestablishesanairflow
bymovingagivenvolumeofairperunittime.
Enclosure
Aconfinedorpartiallyconfinedvolume.
Otherdefinitions
AuthorityHavingJurisdiction(AHJ)
Anorganization,office,orindividualresponsibleforenforcingthe
requirementsofacodeorstandard,orforapprovingequipment,
materials,aninstallation,oraprocedure.
Owner/Operator
Theorganizationwithfiscalresponsibilityfortheoperation,
maintenance,andprofitabilityofthefacility.
37
Establishingdataforaspecificprocess
ProcessHazardAnalysis(PHA)mustestablish:
Potentiallyhazardousprocesssections
Potentiallyhazardousareas.
Productsrequiredtobetested
Dustaccumulationareastobesampled
Sampling:
Dustondirtysideofcollector
Takefromhighpoints(beamsorotherupfacingsurfaces)
Otherareaswhereairbornedustmayhavesettled
Minimumquantity 2kg
38
Dusttesting
DeflagrationIndexKst
Kst providesthebestsinglenumberestimateoftheanticipatedbehavior
ofadustdeflagration.
CombustibledustsareclassifiedbythenumericalvalueofKst.
Kst Value
STClass
ST0
0to200
ST1
201to300
ST2
>300
ST3
ST=Staub (Germanfordust)
40
Dusttestdevice
41
Dusttests
Max P generated by
the dust
Volume normalized
rate of pressure increase
Maxvesselpressure
with vent panel
P red
Ignition source
Ignition
activation
P stat
Time
Static pressure limit
for vent panel
42
Dusttests
ST1200
P red
Ignition source
P stat
Time
43
Dusttests
300ST2200
ST1200
P red
Ignition source
P stat
Time
44
Dusttests
ST3300
300ST2200
ST1200
P red
Ignition source
P stat
Time
45
Kst
Coaldusttableinformation
Activated carbon
Browncoal
Bituminouscoal
44
So
Which
onedoI
use
143
86