Beruflich Dokumente
Kultur Dokumente
Ermanno Amata
Istituto di Astrofisica e Planetologia Spaziali
INAF
Via del fosso del cavaliere, 100
00133 Roma
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
particle
source
Scattered
particles
Most particles go
straight through
The idea was that, although atoms are too small to be seen even by making use of microscopes, it should be
possible to infer their spatial structure by looking at the way small bullets are scattered by it.
The bullets were particles, which, as we now know, are nuclei of Helium deprived of their two electrons.
Each time an particle hit the fluorescent screen, it produced a small flash.
particles
It was thought that most particles would not be deflected at all through the foil, as shown in the upper figure.
Instead, Rutherford observed that a significant, although
small, number of particles was severely deflected: 1 over
8000 was even scattered backwards (lower figure).
Building on his experimental data, he proposed a
thouroghly new atomic model, in which the positive
nucleus was very small (r ~ 10-14 m), while electrons were
distributed over a larger sphere (r ~ 10-10 m).
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
However, as we shall see in while, Rutherfords model was not flawless either
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
Millikans experiment
Microscope
Oil drops
s
+
High voltage difference
Between 1907 and 1911 Robert A. Millikan obtained a reliable measurement of the electron charge.
Oil droplets are sprayed into the upper chamber. Some droplets gain an electrical charge, positive or negative,
because of friction against the pipe wall.
In the lower chamber (connected to the upper one by a hole) the experimenter has the possibility to apply a
uniform vertical electric field E between the two horizontal plates of a capacitor. If V is the potential
difference applied to the capacitor plates, the electric field intensity will be
E = V/s
where s is the distance between the plates. In the drawing, E in directed upwards.
As soon a the droplet enters the lower chamber through the hole, the experimenter can switch on the electric
field. The droplet can then behave in one of three different ways:
- just go on falling with no further acceleration (if the droplet happens to be neutral);
- experience an downward acceleration (if it is negatively charged);
- slow down, stop or even start to move upwards (if it is positively charged).
The mass of the droplet can be determined by measuring its diameter through the microscope.
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
FP = -mg;
FA = -6rv.
The droplet charge q is unknown. The third formula is Stokes law, so that is the air
viscosity, r is the droplet radius, v is its speed.
FE
FP
FA
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
-e
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
This formula tells us that the potential energy goes to 0 as r goes to infinity. Moreover, U becomes strongly
negative when r 0. This means that, in order to move an electron from the vicinity of the nucleus to
infinity, we must give it energy.
We also notice that the absolute value of U is twice that of K. We can now calculate the total energy of the
electron. In conclusion, the total energy of the electron is
The electron total energy is negative, which means that the atom is in a bound state.
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
In 1911 Niels Bohr realised that the planetary model had a severe flaw, which could
in no way be corrected within the framework of classical electromagnetism. In fact,
according to electromagnetic theory, a charge which undergoes a change of velocity
(acceleration) must emit electromagnetic radiation.
Now, although the electron of Rutherfords hydrogen has a constant angular velocity,
its linear velocity changes continuously in direction. In fact, we have just seen that it
is subjected to a centripetal acceleration provided through the second law of
dynamics by Coulombs force.
Therefore, if Rutherfords electron starts from a certain orbit with a given radius and
speed, which is dynamically stable according to Newtons mechanics, it will
immediately start to emit electromagnetic radiation and, as a consequence, to loose
energy, spiralling towards the nucleus, on which it will fall within about 10-7 s.
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
Bohrs atom
To solve the problem, Bohr put forward two new bold hypotheses:
- radii of electron orbits are quantised;
- an electron moving on any permitted orbit will not emit any radiation.
The second hypothesis ensures that the atom is stable.
The first one rules that not only the radius, but also the velocity and thus the
total energy of electrons are quantised.
The quantisation of orbit for the hydrogen atom was written by Bohr as
2rnpn = nh,
where n = 1, 2, 3, (principal quantum number), rn is the orbit radius and
pn is the electron momentum on that orbit.
Of course, h is Plancks constant!
As a side note, we may recall that, although Bohr introduced the
quantisation of atomic orbit, he still did not believe that photons were real!
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.
time
1850
1860
1870
1880
1890
1900
1910
1920
1930
Special relativity
General relativity
Plancks law
UV & IR spectral lines
Lenards photo-el effect
Plum Pudding Model
Millikan measures e
Rutherfords exper. & atom
Bohrs atom
Franck-Hertz experiment
Old quantum meachanics
Compton effect
Quantum mechanincs
Lectures delivered at the Liceo Scientifico Statale Bruno Touschek, Grottaferrata, on February 16, 17 and 18, 2015.