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The document discusses the viscosity properties of chocolate as a non-Newtonian fluid. It explains that non-Newtonian fluids have viscosities dependent on shear stress and rate of shear rather than just temperature and pressure. Chocolate exhibits thixotropic behavior where viscosity decreases under shear stress such as heating. While cocoa butter and chocolate liquor themselves are Newtonian, the addition of sugar and milk particles causes chocolate's non-Newtonian qualities by increasing intermolecular attractions between particles under stress.
Originalbeschreibung:
Propiedades reológicas del chocolate. Exposición en inglés
The document discusses the viscosity properties of chocolate as a non-Newtonian fluid. It explains that non-Newtonian fluids have viscosities dependent on shear stress and rate of shear rather than just temperature and pressure. Chocolate exhibits thixotropic behavior where viscosity decreases under shear stress such as heating. While cocoa butter and chocolate liquor themselves are Newtonian, the addition of sugar and milk particles causes chocolate's non-Newtonian qualities by increasing intermolecular attractions between particles under stress.
The document discusses the viscosity properties of chocolate as a non-Newtonian fluid. It explains that non-Newtonian fluids have viscosities dependent on shear stress and rate of shear rather than just temperature and pressure. Chocolate exhibits thixotropic behavior where viscosity decreases under shear stress such as heating. While cocoa butter and chocolate liquor themselves are Newtonian, the addition of sugar and milk particles causes chocolate's non-Newtonian qualities by increasing intermolecular attractions between particles under stress.
MARVEL NATURAL PRODUCT OF CHEMISTRY Ginger Tannembaum, Chocolate: a marvel natural product of chemistry, Journal Chemical Education, vol. 81 no. 8, August 2004, 1131-1135 Fidel Romero-Ramrez
CHOCOLATE AND VISCOSITY
Non-Newtonian fluids contain solid
particles that result in the viscosity being related not only to temperature and pressure, but to shear (tangential force per area) applied as well.
There are three general
types of non-Newtonian fluids: shear thinning (thixotropic), shear thickening (dilatant), and those in which the viscosity depends not only on the rate of shear but its duration.
The thixotropic nature of
chocolate can be demonstrated by warming a Hersheys Kiss at 40C for 30 minutes on a Petri dish. Generally heating reduces viscosity and increases flow properties.
Since cocoa butter and
chocolate liquor are essentially Newtonian fluids, the addition of sugar and milk solids must cause the deviant behavior.
As the number of particles
increases, the intermolecular attractions increase, producing clumps or aggregates.
REFERENCES
Ginger Tannembaum, Chocolate: A marvel natural product
of chemistry, Journal Chemical Education, vol. 81 no. 8, August 2004, 1131-1135