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S OF THE
MOLE
__
1 mole Mg
__
24.3 g Mg
(2.32)
58.5 g NaCl
__
__
1 mole NaCl
(202 g)
STOP
HERE
Percent Composition
Recall that every chemical compound
has a definite composition - a
composition that is always the same
wherever that compound is found.
The composition of a compound is
usually stated as the percent by mass
of each element in the compound.
Percent Composition
The percent of an element (X) in a
compound can be found in the
following way.
%X=
(molar mass of X) (# X s)
molar mass of compound
x 100
Example
Determine the percent composition of
chlorine in calcium chloride (CaCl2).
First determine the number of atoms
of each element. A mole of calcium
one mole of
chloride consists of ______
two moles of
calcium ions and ______
chloride ions.
Two Cl has
a mass of
_____
35.5 x 2 =
71.0 g.
______
111.1
CaCl2 has a mass of 40.1 + 71.0 = ______
g.
% Cl =
( 35.5 g) ( 2 Cl ions)
111.1 g
x 100
X 100
% Cl in CaCl2 = 63.9%
Problem
9.Determine the percent composition of
carbon in sodium acetate (NaC2H3O2).
%X=
x 100
( 12.0 g) ( 2 Cs)
82.0 g
X 100
(% C = 29.3%)
Problem
10. Calculate the percent composition
aluminum of aluminum oxide (Al2O3).
52.9% Al
Problem
11. Determine the percent composition of
oxygen in magnesium nitrate, Mg(NO 3)2.
64.7% O
Problem
12. Determine the percent composition of
sulfur in aluminum sulfate, which has the
formula Al2(SO4)3.
28.1% S
Problem
13. Determine the percent composition of
oxygen in zinc nitrite, which has the
formula Zn(NO2)2.
40.7% O
STOP
HERE
Problem
14. Determine the percent water in
CuSO4 5 H2O (s).
% H2O =
% H2O =
18.0 (____)
5
(_____)
molar mass of hydrate
x 100
x 100
Problem
14. Determine the percent water in
CuSO4 5 H2O (s).
% H2O =
(18.0) (5)
molar mass of hydrate
x 100
1 Cu = 63.5
249.7 = molar mass
1 S = 32.1
of the hydrate
4 O = 16.0 x 4
5 H2O = 18.0 x 5
% H 2O =
( 18.0 g) ( 5 H2Os)
249.7 g
X 100
% H2O = 36.0%
Problem
15. Determine the percent water in
MgCO3 5 H2O (s).
51.6% H2O
Problem
16. Determine the percent water in
LiClO4 3 H2O (s).
33.7% H2O
Empirical Formula
You can use percent composition data to
help identify an unknown compound by
determining its empirical formula.
The empirical formula is the simplest
whole-number ratio of atoms of elements
in the compound. In many cases, the
empirical formula is the actual formula
for the compound.
Empirical Formula
The formula for glucose is C6H12O6.
The coefficients in glucose are all
divisible by 6.
The empirical formula of glucose is
CH2O.
Problem
17. Determine the empirical formula for
Tl2C4H4O6.
TlC2H2O3
Problem
18. Determine the empirical formula for
N2O4.
NO2
Empirical Formula
from Percent Composition
The percent composition of an unknown
compound is found to be 38.43% Mn,
16.80% C, and 44.77% O. Determine
the compounds empirical formula.
Because percent means parts per
hundred parts, assume that you have
100 g of the compound.
Empirical Formula
from Percent Composition
Then calculate the number of moles of
each element in the 100 g of
compound.
Empirical Formula
from Percent Composition
The number of moles of manganese
may be calculated as follows.
Given: 38.43% Mn
38.48 g Mn 1 mol Mn
54.9 g Mn
= 0.7009 mol Mn
Empirical Formula
from Percent Composition
The number of moles of carbon may be
calculated as follows.
Given: 16.80% C
16.80 g C
1 mol C
12.0 g C
= 1.400 mol C
Empirical Formula
from Percent Composition
The number of moles of oxygen may be
calculated as follows.
Given: 44.77% O
44.77 g O
1 mol O
16.0 g O
= 2.798 mol O
Empirical Formula
from Percent Composition
The results show the following
relationship.
mol Mn : mol C : mol O
0.7009 : 1.400 : 2.798
Empirical Formula
from Percent Composition
To obtain the simplest whole-number
ratio of moles, divide each number of
moles by the smallest number of moles.
0.7009 mol Mn
0.7009
= 1 mol Mn
Empirical Formula
from Percent Composition
1.400 mol C
0.7009
2.798 mol O
0.7009
= 2 mol C
= 4 mol O
Empirical Formula
from Percent Composition
The mole ratio for the compound is:
1 Mn : 2 C : 4 O
The empirical formula for the compound
is MnC2O4.
Problem
19. Determine the empirical formula of the
following compound.
31.9 g Mg, 27.1 g P
Problem
The number of moles of magnesium
may be calculated as follows.
Given: 31.9 g Mg
31.9 g Mg
1 mol Mg
24.3 g Mg
= 1.31 mol Mg
Problem
The number of moles phosphorous may
be calculated as follows.
Given: 27.1 g P
27.1 g P
1 mol P
31.0 g P
= 0.874 mol P
Empirical Formula
from Percent Composition
The results show the following
relationship.
mol Mg : mol P
1.31 : 0.874
Empirical Formula
from Percent Composition
To obtain the simplest whole-number
ratio of moles, divide each number of
moles by the smallest number of moles.
0.874 mol P
0.874
= 1 mol P
Empirical Formula
from Percent Composition
1.31 mol Mg
0.874
= 1.5 mol Mg
Empirical Formula
from Percent Composition
The mole ratio for the compound is:
1.5 Mg : 1 P
You cannot have a fraction, so multiply
both numbers by 2.
3 Mg : 2 P
The empirical formula for the compound
is Mg3P2.
Problem
20. The composition of an unknown acid
is 40.00% carbon, 6.71% hydrogen, and
53.29% oxygen. Calculate the empirical
formula for the acid.
CH20
Problem
21. The composition of an unknown ionic
compound is 60.7% nickel and 39.3%
fluorine. Calculate the empirical formula
for the ionic compound.
NiF2
Problem
22. The composition of a compound is
6.27 g calcium and 1.46 g nitrogen.
Calculate the empirical formula for the
compound.
Ca3N2
Problem
23. Find the empirical formula for a
compound consisting of 63.0% Mn and
37.0% O.
MnO2
STOP
HERE
Molecular Formulas
For many compounds, the empirical
formula is not the true formula.
A molecular formula tells the exact
number of atoms of each element in a
molecule or formula unit of a compound.
Molecular Formulas
The molecular formula for a compound
is either the same as the empirical
formula or a whole-number multiple of
the empirical formula.
Molecular Formulas
In order to determine the molecular
formula for an unknown compound, you
must know the molar mass of the
compound in addition to its empirical
formula.
Molecular Formulas
Then you can compare the molar mass
of the compound with the molar mass
represented by the empirical formula as
shown in the following example
problem.
Problem
24. The molecular mass of benzene is
78 g/mol and its empirical formula is
CH. What is the molecular formula for
benzene?
Problem
As stated in the problem, the molecular
mass of benzene is known to be
78.0 g/mol.
78.0 g/mol
13.0 g/mol
=6
Problem
25. The simplest formula for butane is
C2H5 and its molecular mass is about
60.0 g/mol. What is the
molecular formula of butane?
60.0 g/mol
29.0 g/mol
=2
Problem
26. What is its molecular formula of
cyanuric chloride, if the empirical
formula is CClN and the molecular
mass is 184.5 g/mol?
C3Cl3N3
Problem
27. The simplest formula for vitamin C is
C3H4O3. Experimental data indicates
that the molecular mass of vitamin C
is about 180. What is the molecular
formula of vitamin C?
C6H8O6
Problem
28. Maleic acid is a compound that is
widely used in the plastics and textiles
industries. The composition of maleic
acid is 41.39% carbon, 3.47%
hydrogen, and 55.14% oxygen. Its
molar mass is 116.1 g/mol. Calculate
the molecular formula for maleic acid.
Problem
The number of moles of carbon may be
calculated as follows.
Given: 41.39% C
41.39 g C
1 mol C
12.0 g C
= 3.449 mol C
Problem
The number of moles of hydrogen may
be calculated as follows.
Given: 3.47% H
3.47 g H
1 mol H
1.0 g H
= 3.47 mol H
Problem
The number of moles of oxygen may be
calculated as follows.
Given: 55.14% O
55.14 g O
1 mol O
16.0 g O
= 3.446 mol O
Problem
As stated in the problem, the molar
mass of maleic acid is known to be
116.1 g/mol.
116.1 g/mol
29.0 g/mol
=4
Problem
29. The composition of silver oxalate is
71.02% silver, 7.91% carbon, and
21.07% oxygen. If the molar mass of
silver oxalate is 303.8 g/mol, what is
its molecular formula?
Ag2C2O4
Problem
30. The composition of a compound is
85.6% carbon and 14.4% hydrogen.
If the molar mass of the compound is
42.1 g/mol, what is its molecular
formula?
C3H6