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3 Entropy

Warm Up

Which is there more of in nature?

A) Organization

B) Chaos

1.3 Entropy

Clicker Quiz

Kinetics and
Equilibrium

11.1 Reaction Rates


11.2 Equilibrium

1.3 Entropy

Clicker Quiz #1

A 5.0-gram sample of zinc and a 50.milliliter sample of hydrochloric acid


are used in a chemical reaction.
Which combination of these samples
has the fastest reaction rate?

A. a zinc strip and 1.0 M HCl(aq)


B. zinc powder and 1.0 M HCl(aq)
C. a zinc strip and 3.0 M HCl(aq)
D. zinc powder and 3.0 M HCl(aq)

1.3 Entropy

Clicker Quiz

Given the potential energy


diagram of a chemical reaction:
Which arrow represents the
potential energy of the reactants?

1.3 Entropy

Clicker Quiz

In a chemical reaction, the


difference between the potential
energy of the products and the
potential energy of the reactants
equal to the
A. activationisenergy
B. heat of reaction
C. kinetic energy
D. rate of reaction

1.3 Entropy

Clicker Quiz

Given the equation representing a


reaction at equilibrium:
Which change causes the
equilibrium to shift to the right?
A. decreasing the concentration of
H2(g)
B. increasing the concentration of N2(g)
C. decreasing the pressure
D. increasing the temperature

1.3 Entropy

Notes

11.3 Entropy
Essential Question: What makes a
reaction spontaneous?
Mastery Skill: I can evaluate
changes in entropy given a
chemical equation.

1.3 Entropy

Notes

Chaos
Entropy is the measure of disorder in
a system.
The law of disorder states: systems
naturally prefer increasing disorder or
randomness.

1.3 Entropy

Notes

Entropy Examples
Higher phase

Division/disorganization
*More products than reactants

Increase temperature

1.3 Entropy

Notes

Spontaneous Reactions
A spontaneous reaction occurs naturally and
favors the formation of products.
Decrease in enthalpy (-H)
Increase in entropy (+S)
but, but
not
spontaneous!

11.3 Entropy

#1

Which list of the phases of H2O is arranged


in order of increasing entropy?

A. ice, steam, and liquid water


B. steam, liquid water, and ice
C. ice, liquid water, and steam
D. steam, ice, and liquid water

11.3 Entropy

#2

The entropy of a sample of H2O


increases as the sample changes from a

A. gas to a liquid
B. liquid to a gas
C. gas to a solid
D. liquid to a solid

1.3 Entropy

Practice

Note: This question may require the use


of theReference Tables for Physical
Setting/Chemistry.
At STP, a sample of which element has
the highest entropy?

A. Na(s)
B. Br2(l)
C. Hg(l)
D. F2(g)

1.3 Entropy

Practice

Given the balanced equation


representing a reaction:
2H2O(l) + 571.6 kJ 2H2(g) + O2(g)
What occurred as a result of this
reaction?

A. Energy was
increased.
B. Energy was
increased.
C. Energy was
decreased.
D. Energy was
decreased.

absorbed, and entropy


released, and entropy
absorbed, and entropy
released, and entropy

1.3 Entropy

Practice

Which sample has


thelowestentropy?

1.3 Entropy

Practice

Given the balanced equation shown in


the diagram:
Which statement best describes this
A. It is endothermic
and entropy
process?

increases.
B. It is exothermic and entropy
increases.
C. It is endothermic and entropy
decreases.
D. It is exothermic and entropy
decreases.

1.3 Entropy

Practice

Which reaction has the greatest


increase in entropy?

1.3 Entropy

Practice

Illustrate
Create a comic strip using the
fictional character Entropy Man or
Entropy Woman
Describe how they change the
entropy of their environment!

3 Entropy

Reflect

11.3 Mastery Skill: I can


evaluate changes in entropy
given
a chemical
equation.
Profession
Practition
Apprentic Novice-1
Quantity

al-4

er-3

e-2

Most-All
questions
answered
correctly

Most-All
questions
answered
correctly

Some-Most
questions
answered
correctly

Few-No
questions
answered
correctly

Some
annotation or
problem
solving, but not
much.

Very little
besides final
answer is
written.

Work is
incomplete.

Descript Annotating and


problem solving
ion
always used.

Rate yourself on the front page of your packet too!

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