BO CO THC HN

PHNG PHP O QUANG NH LNG Fe3+, Cu2+ BNG

BNG 1: NH LNG Fe3+, = 471nm
STT

Th tch Fe3+ (ml)

1
2
3
4
5
6
7
8

Nng Fe3+ (mol)

hp th A
0.2
0.00008
0.418
0.4
0.00016
0.893
0.6
0.00024
1.270
0.8
0.00032
1.735
1
0.0004
2.146
1.2
0.00048
2.599
0.6
?
1.261
0.6
?
1.283

Bng 2: nh lng Cu2+, =610 nm

STT

th tch Cu2+ (ml)

1
2
3
4
5
6
7
8

nng Cu2+ (mg/ml) hp th A

3
0.06
0.052
5
0.1
0.087
10
0.2
0.175
15
0.3
0.262
20
0.4
0.348
25
0.5
0.434
15
?
0.259
15
?
0.262

cu 1: nng trn nhn ca dung dch X ?

ta c phng trnh ng chun: y= 4070x-0.031 , R2= 0.993

mt quang trung bnh o c ca mu X (7,8) : Atb= (1.129+1.129)/2=1.129
thay A=y vo pt ng chun suy c x: nng dd o: 1.129=4070x- 0.031 => x= 2,85.1
vy nng Fe3+ trn nhn : 2,85.10^-4 .25/0,6= 0,0118M

cu 2: tm nng mol

ca dung dch Y(7,8) ?

ta c phng trnh ng chun: y= 0.8297x+0.0123 , R2= 0.9997

thay A=y vo pt ng chun suy c x: nng dd o: 0.265=0.08297x- 0.0123 => x=3,3

vy nng Cu2+ trn nhn : 3,3422.50/15=11.14 (mg/ml)

BO CO THC HNH BI 2

e3+, Cu2+ BNG PHNG PHP O QUANG PH HP THU UV-VIS

3.000
2.500

f(x) = 5403.2142857143x - 0.0027333333

R = 0.9993930927

2.000
Column D

1.500

Linear (Column D)
1.000
0.500
0.000
0

0.0001

0.0002

0.0003

0.0004

0.0005

0.0006

s ph thuc ca A v nng Fe3

0.5
0.45
f(x) = 0.8685135135x + 0.0005198198
R = 0.9999766546

0.4
0.35
0.3

Column D

0.25

Linear (Column D)

0.2
0.15
0.1
0.05
0
0

0.1

+1.129)/2=1.129
4070x- 0.031 => x= 2,85.10^-4 (mol/l)

0.2

0.3

0.4

0.5

0.6

s ph thuc ca A v nng Cu2+

0.08297x- 0.0123 => x=3,3422(mg/ml)

HP THU UV-VIS

Column D
Linear (Column D)

ca A v nng Fe3+

Column D
Linear (Column D)

A v nng Cu2+

BO CO THC HN

PHNG PHP O QUANG NH LNG Fe3+, Cu2+ BNG

BNG 1: NH LNG Fe3+, = 471nm
STT

Th tch Fe3+ (ml)

1
2
3
4
5
6
7
8

Nng Fe3+ (mol)

hp th A
0.2
0.00008
0.31
0.4
0.00016
0.65
0.6
0.00024
0.942
0.8
0.00032
1.192
1
0.0004
1.569
1.2
0.00048
1.988
0.6
?
1.129
0.6
?
1.129

Bng 2: nh lng Cu2+, =610 nm

STT

th tch Cu2+ (ml)

1
2
3
4
5
6
7
8

nng Cu2+ (mg/ml) hp th A

3
0.06
0.058
5
0.1
0.099
10
0.2
0.18
15
0.3
0.26
20
0.4
0.344
25
0.5
0.427
15
?
0.265
15
?
0.265

cu 1: nng trn nhn ca dung dch X ?

ta c phng trnh ng chun: y= 4070x-0.031 , R2= 0.993

mt quang trung bnh o c ca mu X (7,8) : Atb= (1.129+1.129)/2=1.129
thay A=y vo pt ng chun suy c x: nng dd o: 1.129=4070x- 0.031 => x= 2,85.1
vy nng Fe3+ trn nhn : 2,85.10^-4 .25/0,6= 0,0118M

cu 2: tm nng mol

ca dung dch Y(7,8) ?

ta c phng trnh ng chun: y= 0.8297x+0.0123 , R2= 0.9997

thay A=y vo pt ng chun suy c x: nng dd o: 0.265=0.08297x- 0.0123 => x=3,3

vy nng Cu2+ trn nhn : 3,3422.50/15=11.14 (mg/ml)

BO CO THC HNH BI 2

e3+, Cu2+ BNG PHNG PHP O QUANG PH HP THU UV-VIS

2.5
2
f(x) = 4070.3571428572x - 0.0312
R = 0.9933059852

1.5

hp th A

Linear ( hp th A)

0.5
0
0

0.0001

0.0002

0.0003

0.0004

0.0005

0.0006

s ph thuc ca A v nng Fe3

0.45
f(x) = 0.8297297297x + 0.0122702703
R = 0.9996547575

0.4
0.35
0.3
0.25

hp th A

0.2

Linear ( hp th A

0.15
0.1
0.05
0
0

0.1

+1.129)/2=1.129
4070x- 0.031 => x= 2,85.10^-4 (mol/l)

0.2

0.3

0.4

0.5

0.6

s ph thuc ca A v nng Cu2+

0.08297x- 0.0123 => x=3,3422(mg/ml)

HP THU UV-VIS

hp th A
Linear ( hp th A)

ca A v nng Fe3+

hp th A
Linear ( hp th A)

0.6

A v nng Cu2+