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Figure 1: Earth s atmosphere is divided into layers, which have various characteri
stics.
Source: NOAA Aeronomy Laboratory, 1998
The ozone found in our atmosphere is formed by an interaction between oxygen
molecules (composed of two oxygen atoms) and ultraviolet light. When ultraviolet
light
hits these oxygen molecules, the reaction causes the molecules to break apart in
to single
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atoms of oxygen (UV light + O2 --> O + O). These single atoms of oxygen are very
reactive, and a single atom combines with a molecule of oxygen to form ozone (O3
),
which is composed of three atoms of oxygen (2O + 2O2 --> 2O3).
The ozone layer is essential for human life. It is able to absorb much harmful u
ltraviolet
radiation, preventing penetration to the earth s surface. Ultraviolet radiation (U
V) is
defined as radiation with wavelengths between 290-320 nanometers, which are harm
ful
to life because this radiation can enter cells and destroy the deoxyribonucleic
acid (DNA)
of many life forms on planet earth. In a sense, the ozone layer can be thought o
f as a
UV filter or our planet s built in sunscreen (Geocities.com, 1998). Without the ozone
layer, UV radiation would not be filtered as it reached the surface of the earth
. If this
happened, cancer would break out and all of the living civilizations, and all spe
cies on
earth would be in jeopardy (Geocities.com, 1998). Thus, the ozone layer essential
ly
allows life, as we know it, to exist.
In order for scientists to evaluate how much ozone is in the layer, a unit of me
asurement
called the Dobson Unit is employed. A Dobson Unit is a measurement of how thick
a
specific portion of the ozone layer would be if it were compressed into a single
layer at
zero degrees Celsius with one unit of atmospheric pressure acting on it (standar
d
temperature and pressure - STP). Thus, one Dobson Unit (DU) is defined as .01 mm
thickness at standard temperature and pressure. Figure 2 shows a column of air o
ver
Labrador, Canada. Since the ozone layer over this area would form a 3 mm thick s
lab,
the measurement of the ozone over Labrador is 300 DU.
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II. Ozone depletion: Who is responsible?
It is important to recognize the sources of ozone depletion before one can fully
understand the problem. There are three main contributors to the ozone problem:
human
activity, natural sources, and volcanic eruptions (See Figure 3).
Figure 3: Humans cause more damage to the ozone layer than any other source.
Source: Geocities.com, 1998
Human activity is by far the most prevalent and destructive source of ozone depl
etion,
while threatening volcanic eruptions are less common. Human activity, such as th
e
release of various compounds containing chlorine or bromine, accounts for
approximately 75 to 85 percent of ozone damage. Perhaps the most evident and
destructive molecule of this description is chloroflourocarbon (CFC). CFCs were
first
used to clean electronic circuit boards, and as time progressed, were used in ae
rosols and
coolants, such as refrigerators and air conditioners. When CFCs from these produ
cts are
released into the atmosphere, the destruction begins. As CFCs are emitted, the m
olecules
float toward the ozone rich stratosphere. Then, when UV radiation contacts the C
FC
molecule, this causes one chlorine atom to liberate. This free chlorine then rea
cts with an
ozone (O3) molecule to form chlorine monoxide (ClO) and a single oxygen molecule
(O2). This reaction can be illustrated by the following chemical equation: Cl +
O3 --> O2
+ ClO. Then, a single oxygen atom reacts with a chlorine monoxide molecule, caus
ing
the formation of an oxygen molecule (O2) and a single chlorine atom (O + ClO -->
Cl +
O2). This threatening chlorine atom then continues the cycle and results in furt
her
destruction of the ozone layer (See Figure 4). Measures have been taken to reduc
e the
amount of CFC emission, but since CFCs have a life span of 20-100 years, previou
sly
emitted CFCs will do damage for years to come.
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Figure 5: On average, the size of the ozone hole is larger than many countries.
Source: Geocities.com, 1998
The hole above Antarctica has clearly proven to be detrimental. Plankton, organi
sms that
live on carbon, light, and nutrients such as nitrogen, are near the bottom of th
e food
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chain, and are accustomed to low levels of UV. In December of 1994, on the islan
d of
Bacharcaise off Antarctica, increased levels of UV radiation decreased the numbe
r of
photoplankton dramatically. Photoplankton are the main source of food for krill,
which
in turn are the main source of food for various birds and whales in the Antarcti
c region
(See Figure 6).
Figure 7: UV-B, the most harmful radiation to humans and plants, has a wavelengt
h of
280-315 nanometers, as measured on the electromagnetic spectrum.
Source: Nilsson, 1996
When UV radiation hits the skin, it can cause the cell to lock up and scramble or
delete
DNA information. This action causes confusion in the DNA, and the body loses con
trol
of the growth and division of the cell. If the conditions are right, the cell ma
y become
cancerous. It is important to note that not all affected cells turn into skin ca
ncer, for
many can repair themselves. However, continual exposure to UV radiation increase
s the
risk of skin cancer due to cumulative damage of the DNA.
Skin cancer can be divided into two categories: melanoma and non-melanoma. The
melanoma form of skin cancer is the more dangerous of the two. This type of canc
er has
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the ability to spread quickly throughout the body and invade other cells. On the
other
hand, non-melanoma skin cancer is not to be taken lightly either, but is a less
serious
form of the disease. Non-melanoma skin cancers are not usually life threatening,
and
removal is relatively routine. However, treatment does include radiation therapy
or
surgery. The concern of many is that sunburn may lead to increased risk of acqui
ring skin
cancer. Some forms of cancer are associated with sunburn, while other forms are
not.
Melanoma skin cancer is a form that sunburns may play a leading role in. Jan van
der
Leun, a Dutch scientist, explains that, light hitting the outer layer of the skin
, the
epidermis, triggers the production of some substances which diffuse into the der
mis
below. The dermis is filled with blood vessels, and the chemical substances caus
e them
to dilate, making the skin red and warm to the touch (Nilsson, 83).
The bottom line is that UV ray exposure increases the risk of skin cancer. Howev
er,
controversy lies around the question of whether or not the depletion of the ozon
e layer
will lead to more sunburns, and in turn, more skin cancer. Some scientists sugge
st that
the skin will gradually adapt to higher UV-B levels as the ozone gradually deple
tes
(Nilsson, 83). The opponent to this theory would state that the thinning of the
ozone
layer would lead to more human UV-B exposure. This increased UV-B exposure would
,
in turn, increase the damage to the DNA making it difficult for the cell to corr
ect the
damage before it divides. This damage accumulates over time and increases the ch
ances
that a cell will turn cancerous. In addition, since UV-B radiation damages the i
mmune
system, it is much more likely that a cell will turn cancerous. In animal studies
,
immunosuppressive effects caused by UV-B have indeed been shown to play an
important role in the outcome of both melanoma and non-melanoma skin cancers
(Nilsson, 105). Furthermore, Nilsson (81) states that for the non-melanoma skin
cancers, the evidence is compelling and there are estimates that each percentage
decrease
in the stratospheric ozone will lead to a two percent increase in the incidence
of these
cancers. Thus, if the ozone depletes by ten percent over a certain time period, 2
50,000
more people would be affected by these cancers each year (Nilsson, 81).
Due to controversy in the scientific community, it is difficult to clearly state
whether or
not ozone depletion will lead to an increased risk of skin cancers, but scientis
ts agree on
the fact that UV-B radiation plays a large role in the formation of cancer. Thus
, it may
very well be that as the UV filter we call the ozone layer thins, the increased am
ount of
UV-B radiation posed on human skin may contribute to an increased amount of skin
cancer. Yet, one can only weigh all the evidence and speculate, for science has
yet to
provide a cut and dry answer for society to base its judgments on.
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V. Ozone depletion and immuno-suppression
Ozone depletion is also suggested to cause immuno-suppression. This theory was f
irst
explored in the 1960s when guinea-pigs, who were exposed to an allergen, showed
a
lowered immune system response after they had been irradiated with UV (Nilsson,
101).
In addition, another study showed that UV radiation had the same effect on anima
ls as X-
ray treatment and chemical immuno-suppression. Logically, all three factors supp
ressed
the immune system.
Scientists Edward de Fabo and Frances Noonan conducted a study to investigate ex
actly
which portion of the UV spectrum has the power to suppress the immune system. In
this
experiment, de Fabo and Noonan employed filters that were able to separate UV ra
diation
wavelength by wavelength. They subjected mice to UV rays and measured the effect
s at
precise intervals on the UV range. When de Fabo and Noonan started to match the p
arts
of the spectrum that gave the most immuno-suppression with the absorption spectr
a of
different compounds in the skin, they found an almost perfect match UCA, the
compound previously thought of as sunscreen (Nilsson, 102). Nilsson (107) describ
es
urocanic acid (UCA) as antenna-like because it attracts UV rays. When UV radiati
on hits
the skin, it causes UCA within the skin to change molecular structure from trans
-UCA to
cis-UCA. This transformation interacts with a number of cells in the skin and se
nds a
signal to the immune system, causing it to hinder its reaction. If the UVA has c
aused
damage to the DNA, then the possibility exists for a cancer growth (See Figure 8
).
There is a great deal of evidence to show that high concentrations (ppm) of ozon
e,
created by high concentrations of pollution and daylight UV rays at the earth s su
rface,
can harm lung function and irritate the respiratory system.[16][23] A connection
has also
been shown to exist between increased ozone caused by thunderstorms and hospital
admissions of asthma sufferers.[24] Air quality guidelines such as those from th
e World
Health Organization are based on detailed studies of what levels can cause measu
rable
health effects.
A common British folk myth dating back to the Victorian era holds that the smell
of the
sea is caused by ozone, and that this smell has bracing health benefits.[25] Neith
er of
these is true. The characteristic smell of the sea is not caused by ozone, but by
the
presence of dimethyl sulfide generated by phytoplankton, and dimethyl sulfide, l
ike
ozone, is toxic in high concentrations.[26]
The United States Environmental Protection Agency has developed an Air Quality i
ndex
to help explain air pollution levels to the general public. 8-hour average ozone
concentrations of 85 to 104 ppbv are described as Unhealthy for Sensitive Groups ,
105
ppbv to 124 ppbv as unhealthy and 125 ppb to 404 ppb as very unhealthy .[27] The
EPA has designated over 300 counties of the United States, clustered around the
most
heavily populated areas (especially in California and the Northeast), as failing
to comply
with the National Ambient Air Quality Standards.
Health Effects of UV Radiation
Overexposure to UV radiation is the main cause of skin cancer. UV rays can trigg
er the
development of skin cancer by creating changes in the cells of the skin. In some
cases,
the UV rays cause direct damage to the cells. Tans and sunburns, for example, ar
e both
signs that UV rays have damaged the skin. In other cases, UV rays can cause skin
cancer
indirectly, by weakening the immune mechanisms in skin and the rest of the body.
Most often, skin cancer is the result of overexposure to UV rays from the sun. T
here are
three types of skin cancer: basal cell carcinoma, squamous cell carcinoma, and m
alignant
melanoma. The last one can be fatal if not treated early. Many studies of skin c
ancer
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show links between malignant melanomas and an individual s intolerance to sun
exposure. The studies indicate that people who have suffered severe and frequent
sunburns during childhood are at greater risk of developing melanoma. The featur
es most
closely associated with intolerance to sun exposure include fair or freckled ski
n, blue
eyes, and light-coloured or reddish hair.
The two other types of skin cancer tend to develop later in life on areas of ski
n that have
been exposed repeatedly to the sun, such as the face, neck, or hands. Basal and
squamous
cell carcinomas progress slowly and rarely cause death because they usually do n
ot
spread to other parts of the body.
Overexposure to ultraviolet radiation has also been linked to a number of other
health
effects, including sunburns, cataracts, premature aging of the skin, and weakeni
ng of the
immune system.
Minimizing Your Risk
There is no quick fix for the ozone layer. Once they get into the environment, o
zone-depleting chemicals
disintegrate very slowly, so they are likely to be with us for a long time. Whil
e governments around the world
deal with the source of the problem, it is important to take steps to avoid over
exposure to ultraviolet radiation.
These guidelines will help you protect your family from the sun s harmful rays:
Seek shade if you are taking part in outdoor activities when the UV index is thr
ee
or higher.
Cover up. Wear long-sleeved shirts, long pants, gloves, and a broad-brimmed hat
or visor. Avoid see-through clothing when possible.
Avoid sunbathing for the purpose of tanning, especially between 11:00 a.m. and
4:00 p.m. in the summer when the sun s rays are strongest.
Use sunscreen lotion and reapply it often, as directed on the label. Look for a
broad spectrum sunscreen with a sun protection factor (SPF) of at least 15.
Wear sunglasses that screen out ultraviolet radiation. Your eyes have no built-i
n
defence against the sun, and damage to the eye from UV rays can lead to
cataracts.
Do not think you are safe just because the sky is cloudy. The sun s harmful rays
can get through fog, haze, and light cloud cover.
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Children Need Extra Protection
Children and teenagers have more sensitive skin than adults, so they need extra
protection
if they are going to be out in the sun for a long time. Sunburn may increase the
risk of
skin cancer later in life, so it is best to get children used to wearing protect
ive clothing
and sunscreen lotion from the start.
At the very least, young children should wear a sunhat, T-shirt, and shorts. Whe
n you put
sunscreen on children, pay special attention to the parts that are most exposed,
including
their ears, face, neck, shoulders and back, knees, and the tops of their feet. A
void using
sunscreen on babies. Cover them and keep them in the shade instead.
It is important to protect against ultraviolet radiation all year round; not jus
t in the
summer. You can continue to enjoy outdoor activities, as long as you take steps
to protect
yourself when the UV index is three or higher to avoid sunburns and overexposure
.
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DISCUSSION
Regardless of the details of the arguments, it is obvious that the depletion of
the ozone
layer is a serious problem that poses many consequences to society. Although sci
entific
controversy exists, the possibility seems high that the depletion of the ozone l
ayer will
prove detrimental if action is not taken. For example, research shows the strong
possibility of a number of health risks associated with increased UV-B exposure
as a
direct result of the thinning ozone layer. These health risks include skin cance
r, immunosuppression,
cataracts, and snowblindness.
Furthermore, the possibility that increased UV-B radiation results in lower crop
yields
should provide a wake up call to those who feel the thinning ozone layer is not a
problem. For if we are not able to breed UV-B resistant plants, the world s food s
upply
would become dramatically decreased, resulting in higher levels of famine and
malnutrition.
Studies from Antarctica tell society that increased UV radiation can directly af
fect the
food chain. Recall the decrease in food supply as a result of reduced levels of
photoplankton in Antarctica. This may seem like an isolated, non-significant, an
d remote
problem; however, this incident illustrates the dangers of reduced food supply a
nd
alteration of the food chain as a result of the thinning ozone layer. Even thoug
h the
photoplankton were located at the bottom of the food chain, the whole chain was
affected. In the future, problems like this could potentially affect the global
food web and
result in an overall decrease in food supply. Thus, realize that the dangers pos
ed by
ozone depletion are real now, and will be in the future, if action is not taken.
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Take Action: Teamwork does the trick
Although the earth will be able to heal itself if the CFC level continues to stay
as it is,
the depletion of the ozone layer is still a problem that society should be conce
rned with.
In order for earth to repair the damage humans have posed on the ozone layer, so
ciety
must take an active role. There are many tasks individuals can involve themselve
s in to
help combat the problem of ozone depletion. First of all, one can simply check p
roduct
labels for ozone friendly status. Many companies have gone to great lengths to r
emove
CFCs from their products. These products do not do as much damage to the ozone l
ayer,
and thus, are denoted as ozone friendly. A collaborative effort by society not usi
ng
products with CFCs is a major step toward the healing of the ozone layer.
Unfortunately, many products still used in society are detrimental to the ozone
layer. For
example, CFCs marketed under the trade name Freon are used in appliances with
refrigerants such as refrigerators and air conditioners. When individuals must d
ispose of
products with refrigerants in them, certain actions must be taken in order to pr
event the
CFCs from escaping from the disposed product. For example, when an agency, such
as a
waste hauling company, comes to pick up the unwanted appliance, check to make su
re
refrigerant-recovery equipment is used by the agency. This equipment allows for
the
disposal of refrigerants without damage to the ozone layer.
Society can also help the problem of ozone depletion through education, as well
as
through various donations. If individuals contribute time or money to environmen
tal
agencies focused on healing the ozone layer, the agencies will be able to organi
ze
activities promoting the understanding of the ozone problem. If society is educa
ted
through these means, more individual efforts will be taken to make ozone smart
decisions such as using ozone friendly products.
Although thinning ozone may not directly affect the generation growing up today,
future
generations depend on the actions taken now. Thus, it is important for society t
o
recognize that the thinning ozone layer is a problem and to take action in order
to ensure
the safety and survival of future generations.
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SUMMARY
The ozone layer is essential for protecting society from harmful UV radiation by
acting as
a filter. However, this protective layer has been thinning due to three main sou
rces:
human activity, natural sources, and volcanoes. Human activity is responsible fo
r the
most damage to the ozone layer, thus, society should recognize that much can be
done to
prevent ozone layer damage.
In 1985, in a region over Antarctica, the yearly polar vortex had caused the ozo
ne layer to
deplete so greatly, that it could be classified as a hole. In 1996, this hole wa
s large enough
to cover Antarctica.
The depletion of the ozone layer does not come without problems. Scientific rese
arch
has suggested the probability that increased UV-B radiation as a result of the t
hinning
ozone layer leads to increased cases of skin cancer, immuno-suppression, catarac
ts, and
snow blindness due to radiation damage of the DNA. Additionally, experiments have
shown a correlation between increased UV radiation and crop damage due to UV
radiation damaging the plants DNA. Some scientists, however, feel that this will
not be
a problem in the future due to the possibility of breeding UV resistant crops an
d plants.
Many national governments and agencies recognized the problem of ozone depletion
, and
therefore, united in 1987 to sign the Montreal Protocol. This agreement was
implemented to decrease CFC levels in order to help protect the thinning ozone l
ayer.
Clearly, ozone depletion is a dangerous problem due to possible disease outbreak
s and
famine as a result of increased UV-B radiation. However, society can collectivel
y
attempt to combat this problem by relatively simple means such as education and
the
practice of ozone smart behavior. For if society acts now, future generations will
be
handed a safe and healthy planet.
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