Sample 1

Volume
0
1
2
3
4
5
6
6.2
6.4
6.6
6.8
7
7.2
7.4
7.6
7.8
8
8.2
8.4
8.6
8.8
9
9.2
9.4
9.6
9.8
10
11
12
13
14
15
16
16.2
16.4
16.6
16.8
17
17.2
17.4
17.6

pH

Vm
11.08
10.65
10.37
10.17
9.97
9.78
9.56
9.51
9.46
9.41
9.35
9.28
9.21
9.11
9.02
8.92
8.79
8.61
8.29
7.92
7.65
7.43
7.31
7.25
7.14
7.09
6.97
6.67
6.46
6.26
6.06
5.82
5.53
5.46
5.39
5.27
5.13
4.86
5.27
3.28
2.98

D1
0.5
1.5
2.5
3.5
4.5
5.5
6.1
6.3
6.5
6.7
6.9
7.1
7.3
7.5
7.7
7.9
8.1
8.3
8.5
8.7
8.9
9.1
9.3
9.5
9.7
9.9
10.5
11.5
12.5
13.5
14.5
15.5
16.1
16.3
16.5
16.7
16.9
17.1
17.3
17.5
17.7

Vd
-0.43
-0.28
-0.2
-0.2
-0.19
-0.22
-0.25
-0.25
-0.25
-0.3
-0.35
-0.35
-0.5
-0.45
-0.5
-0.65
-0.9
-1.6
-1.85
-1.35
-1.1
-0.6
-0.3
-0.55
-0.25
-0.6
-0.3
-0.21
-0.2
-0.2
-0.24
-0.29
-0.35
-0.35
-0.6
-0.7
-1.35
2.05
-9.95
-1.5
-0.95

D2
1
0.15
2
0.08
3
0
4
0.01
5
-0.03
5.8
-0.05
6.2 4.4409E-014
6.4 -4.996E-014
6.6
-0.25
6.8
-0.25
7 4.4409E-014
7.2
-0.75
7.4
0.25
7.6
-0.25
7.8
-0.75
8
-1.25
8.2
-3.5
8.4
-1.25
8.6
2.5
8.8
1.25
9
2.5
9.2
1.5
9.4
-1.25
9.6
1.5
9.8
-1.75
10.2
0.5
11
0.09
12
0.01
13
0
14
-0.04
15
-0.05
15.8
-0.1
16.2
0
16.4
-1.25
16.6
-0.5
16.8
-3.25
17
17
17.2
-60
17.4
42.25
17.6
2.75
17.8
2.25

17.8
18
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
20
21
22
23
24
25
26

Sample 2
Volume (mL)pH
0
1
2
3
4
5
6
7
7.2
7.4
7.6
7.8
8
8.2
8.4
8.6
8.8
9
9.2
9.4
9.6

2.79
2.69
2.56
2.49
2.41
2.35
2.3
2.26
2.22
2.18
2.15
2.12
2
1.92
1.85
1.8
1.75
1.7

17.9
-0.5
18.1
-0.65
18.3
-0.35
18.5
-0.4
18.7
-0.3
18.9
-0.25
19.1
-0.2
19.3
-0.2
19.5
-0.2
19.7
-0.15
19.9
-0.15
20.5
-0.12
21.5
-0.08
22.5
-0.07
23.5
-0.05
24.5
-0.05
25.5
-0.05
13 0.06538462

Vm
11.13
10.74
10.48
10.26
10.07
9.89
9.7
9.47
9.43
9.37
9.3
9.24
9.16
9.08
8.98
8.86
8.73
8.53
8.29
7.94
7.65

D1
0.5
1.5
2.5
3.5
4.5
5.5
6.5
7.1
7.3
7.5
7.7
7.9
8.1
8.3
8.5
8.7
8.9
9.1
9.3
9.5
9.7

18
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
20.2
21
22
23
24
25
19.25
6.5

Vd
-0.39
-0.26
-0.22
-0.19
-0.18
-0.19
-0.23
-0.2
-0.3
-0.35
-0.3
-0.4
-0.4
-0.5
-0.6
-0.65
-1
-1.2
-1.75
-1.45
-0.85

-0.75
1.5
-0.25
0.5
0.25
0.25
1.1102E-014
6.6613E-015
0.25
1.1102E-014
0.05
0.04
0.01
0.02
0
2.2204E-016
-0.00923077
0.00502959

D2
1
0.13
2
0.04
3
0.03
4
0.01
5
-0.01
6
-0.04
6.8
0.05
7.2
-0.5
7.4
-0.25
7.6
0.25
7.8
-0.5
8 -8.882E-015
8.2
-0.5
8.4
-0.5
8.6
-0.25
8.8
-1.75
9
-1
9.2
-2.75
9.4
1.5
9.6
3
9.8
1.25

9.8
10
10.2
10.4
10.6
10.8
11
12
13
14
15
16
17
18
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
20
20.2
20.4
20.6
20.8
21
21.2
21.4
21.6
21.8
22
23
24
25
26
27
28

Sample 3

7.48
7.36
7.27
7.18
7.09
7.03
6.98
6.71
6.5
6.45
6.14
5.93
5.68
5.29
5.17
4.95
4.6
3.65
3.09
2.86
2.69
2.62
2.53
2.43
2.4
2.35
2.3
2.27
2.22
2.2
2.16
2.13
2.1
2.08
1.99
1.91
1.85
1.79
1.74
1.72

9.9
-0.6
10.1
-0.45
10.3
-0.45
10.5
-0.45
10.7
-0.3
10.9
-0.25
11.5
-0.27
12.5
-0.21
13.5
-0.05
14.5
-0.31
15.5
-0.21
16.5
-0.25
17.5
-0.39
18.1
-0.6
18.3
-1.1
18.5
-1.75
18.7
-4.75
18.9
-2.8
19.1
-1.15
19.3
-0.85
19.5
-0.35
19.7
-0.45
19.9
-0.5
20.1
-0.15
20.3
-0.25
20.5
-0.25
20.7
-0.15
20.9
-0.25
21.1
-0.1
21.3
-0.2
21.5
-0.15
21.7
-0.15
21.9
-0.1
22.5
-0.09
23.5
-0.08
24.5
-0.06
25.5
-0.06
26.5
-0.05
27.5
-0.02
14 0.06142857

10
10.2
10.4
10.6
10.8
11.2
12
13
14
15
16
17
17.8
18.2
18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
20
20.2
20.4
20.6
20.8
21
21.2
21.4
21.6
21.8
22.2
23
24
25
26
27
20.75
7

0.75
4.2188E-014
-1.998E-014
0.75
0.25
-0.03333333
0.06
0.16
-0.26
0.1
-0.04
-0.14
-0.35
-2.5
-3.25
-15
9.75
8.25
1.5
2.5
-0.5
-0.25
1.75
-0.5
1.1102E-014
0.5
-0.5
0.75
-0.5
0.25
0
0.25
0.01666667
0.01
0.02
0
0.01
0.03
-0.00603175
0.00438776

Volume (mL)pH
0
1
2
3
4
5
5.2
5.4
5.6
5.8
6
6.2
6.4
6.6
6.8
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21

Vm
10.95
10.55
10.26
10
9.71
9.37
9.3
9.18
9.03
8.87
8.64
8.2
7.86
7.55
7.35
7.24
6.82
6.51
6.27
5.99
5.78
5.57
3.39
2.44
2.2
2.05
1.95
1.88
1.81
1.76

D1
0.5
-0.4
1.5
-0.29
2.5
-0.26
3.5
-0.29
4.5
-0.34
5.1
-0.35
5.3
-0.6
5.5
-0.75
5.7
-0.8
5.9
-1.15
6.1
-2.2
6.3
-1.7
6.5
-1.55
6.7
-1
6.9
-0.55
7.5
-0.42
8.5
-0.31
9.5
-0.24
10.5
-0.28
11.5
-0.21
12.5
-0.21
13.5
-2.18
14.5
-0.95
15.5
-0.24
16.5
-0.15
17.5
-0.1
18.5
-0.07
19.5
-0.07
20.5
-0.05
10.5 0.08380952

Vd

D2
1
2
3
4
4.8
5.2
5.4
5.6
5.8
6
6.2
6.4
6.6
6.8
7.2
8
9
10
11
12
13
14
15
16
17
18
19
20
15.5
5.25

0.11
0.03
-0.03
-0.05
-0.01666667
-1.25
-0.75
-0.25
-1.75
-5.25
2.5
0.75
2.75
2.25
0.21666667
0.11
0.07
-0.04
0.07
0
-1.97
1.23
0.71
0.09
0.05
0.03
4.4409E-016
0.02
-0.01338095
0.00798186

Trial 1
12
10
8
pH

Column B

4
2
0
0

10

15

20

25

30

Volume HCl Added (mL)

1st Derivative
4
2
0
-2
Vm

10

15

20

25

Column D

-4
-6
-8
-10
-12
D1

2nd Derivative
60
40

30

2nd Derivative
60
40
20
0
Vd

10

15

20

25

30

Column F

-20
-40
-60
-80
D2

Trial 2
12
10
8
pH

Column B

4
2
0
0

10

15

20

25

Volume HCl Added (mL)

1st Derivative
0
-0.5

10

15

20

25

30

30

1st Derivative
0
-0.5

10

15

20

25

30

-1
-1.5
-2
Column D

Vm -2.5
-3
-3.5
-4
-4.5
-5
D1

2nd Derivative
15
10
5
0
0

Vd

10

15

-5
-10
-15
-20
D2

20

25

30

Column F

Trial 3
12
10
8
6

pH

Column B

4
2
0
0

10

15

20

25

VOlume HCl Added (mL)

1st Derivative
0
0

10

15

20

25

-0.5
-1

Column D

Vm
-1.5
-2
-2.5
D1

2nd Derivative
4
3

2nd Derivative
4
3
2
1
0
Vd

-1

10

15

-2
-3
-4
-5
-6
D2

20

25

Column F

Column B

30

Column D

Column F

Column B

30

Column D

Column F

Column B

25

Column D

Column F