Constantes de Antoine

presin en KiloPa y T en C

Sistema:
A1
A2
A3

Acetonitrilo(A)
14.2724
2945.47
224

Nitrometano(B)
14.2043
2972.64
209

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Benceno(A)
13.8858
2788.51
220.79

Etilbenceno(B)
14.0045
3279.47
213.2

Constantes de Antoine
presin en KiloPa y T en C

Sistema: 1-Clorobutano(A) Clorobenceno(B)

A1
13.96
13.9926
A2
2826.26
3295.12
A3
224.1
217.55

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Acetona(A)
14.5463
2940.46
237.22

Acetonitrilo(B)
14.2724
2945.47
224

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

n-Pentano(A)
13.8183
2477.07
233.21

n-Heptano(B)
13.8587
2911.32
216.64

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Benceno(A)
13.8858
2788.51
220.79

Tolueno(B)
13.9987
3096.52
219.48

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

Constantes de Antoine
presin en KiloPa y T en C

Sistema: 1-Clorobutano(A)
A1
13.96
A2
2826.26
A3
224.1

Benceno(B)
13.8858
2788.51
220.79

Constantes de Antoine
presin en KiloPa y T en C

Sistema:
A1
A2
A3

n-Pentano(A)
13.8183
2477.07
233.21

n-Hexano(B)
13.8216
2697.55
224.37

Sistema:
A1
A2
A3

n-Hexano(A)

Trietilamina(B)

lnP sat A1

Benceno(A)
13.8858
2788.51
220.79

A2
T A3
51.9
38.8561276

13.3088148005

Etilbenceno(B)
14.0045
3279.47
213.2

SEPARACIN FLASH
CONSTANTES EC. PRESIN DE VAPOR
Sistema:
Benceno(A)
Tolueno(B)
C1
83.107
76.945
C2
-6486.2
-6729.8
C3
-9.2194
-8.179
C4
6.9844E-006
5.3017E-006
C5
2
2

P en Pascal
T en K

Cp gas en Joule/kmol K
T en K

Calor latente de vaporzacion

en Joule/kmol
Tr es tempe reducida

CpL en Joule/kmol K
T en K

CONSTANTES EC. CP DE GASES IDEALES

C1 4.44200000E+04
5.81400000E+04
C2 2.32050000E+05
2.86300000E+05
C3 1.49460000E+03
1.44060000E+03
C4 1.72130000E+05
1.89800000E+05
C5 -6.78150000E+02 -6.50430000E+02

CONSTANTES EC. CALOR LATENTE DE VAPOR

C1 4.53460000E+07
4.95070000E+07
C2 3.90530000E-01
3.77420000E-01
C3 0.00000000E+00
0.00000000E+00
C4 0.00000000E+00
0.00000000E+00
C5 0.00000000E+00
0.00000000E+00

CONSTANTES EC. CP DE LQUIDOS

C1 1.29440000E+02
1.40140000E+02
C2 -1.69500000E+02 -1.52300000E+02
C3 6.47810000E-01
6.95000000E-01
C4 0.00000000E+00
0.00000000E+00
C5 0.00000000E+00
0.00000000E+00
Para benceno use la ec I
Para tolueno use la ec I

Presin crtica, MPa

Temperatura, Kelvin

Pc=
Tc=

4.895
562.5

4.108
591.75

1bar=
1atm=
1atm=
1atm=
1atm=

100 Kpa
760 mm Hg
14,696 psi
1,01325 bar
101,325 Kpa

C
218 103.333333

Ingresa
Presin , KPa=
Tempe, C=

50
102.155

Compuesto zF
A
B

Ingresa
Presin , KPa=
Tempe, C=

Pvapor, KPa
K
0.2 190.633013025 3.812660261
0.8 79.0027781113 1.580055562

101.325
106.4
Compuesto zF
A
B

Pvapor, KPa
K
0.2 213.221088728 2.104328534
0.8 89.5709976822 0.883997016

T refer. ,C

PUNTO DE BURBUJA
zF*K
0.7625320521
1.2640444498
2.0265765019
-1.0265765019

PUNTO DE ROCIO
zF/K
0.0950421936
0.90498043
1.0000226236
-2.26236E-05

y
0.2 0.762532052
0.8 1.26404445
1 2.026576502

x
0.2 0.095042194
0.8 0.90498043
1 1.000022624

F, Kmol/h =
zF(A)=
PF, KPa=
TF, C=
Pv A Kpa
Pv B Kpa
suma(z*K)
suma(z/K)
HlA, KJoule/kmol
HlB, KJoule/kmol
lambdaA Kjoule/kmol
lambdaB Kjoule/kmol
HvA Kjoule/Kmol
HvB, Kjoule/kmol
Hm liq Kjoule/kmol
Hm vap Kjoule/kmol
HF

Condiciones del separador ISOTRMIC

P, KPa =
101.325
T, C =
104
100
0.2
101.325
85
117.44930297
45.903660345
0.5942540229
1.9384147815
982.71047866
1847.1659446
30535.444213
34859.022453
31518.154692
36706.188397
1674.2748514
35668.581656
1674.27

Pv
Benceno(A) 200.212639
Tolueno(B)
83.4672285
Q Kjoule/h

2449897.56

el separador ISOTRMICO: no hay vlvula

Fracc V/F

K
zF*K
zF/K
1.97594512 0.39518902 0.10121739
0.8237575
0.659006 0.9711596
1.05419502 1.07237698

0.31508182 Nuevo V/F

0.31508182

g
g^2/zF
x
y
0.14928386 0.111428347
0.2
0.38
-0.14928385 0.02785709 0.84703663 0.69775277
3.631E-010 -0.13928543 1.04703663 1.07775277

Hl
Lambda
Hv
1465.20556
29393.6 30858.805551
2571.23098 33760.578 36331.8089826
2470.96793
37076.9666083
H mezcla
H mezcla

SEPARACIN FLASH
CONSTANTES EC. PRESIN DE VAPOR
Sistema:
n-Hexano(A)
n Octano(B)
C1
104.65
96.084
C2
-6995.5
-7900.2
C3
-12.702
-11.003
C4
1.2381E-05
7.1802E-006
C5
2
2

P en Pascal
T en K

Cp gas en Joule/kmol K
T en K

Calor latente de vaporzacion

en Joule/kmol
Tr es tempe reducida

CpL en Joule/kmol K
T en K

CONSTANTES EC. CP DE GASES IDEALES

C1
C2
C3
C4
C5

CONSTANTES EC. CALOR LATENTE DE VAPOR

C1 4.45440000E+07
5.51800000E+07
C2 3.90020000E-01
3.84670000E-01
C3 0.00000000E+00
0.00000000E+00
C4 0.00000000E+00
0.00000000E+00
C5 0.00000000E+00
0.00000000E+00

CONSTANTES EC. CP DE LQUIDOS

C1 1.72120000E+02
2.24830000E+02
C2 -1.83780000E+02 -1.86630000E+02
C3 8.87340000E-01
9.58910000E-01
C4 0.00000000E+00
0.00000000E+00
C5 0.00000000E+00
0.00000000E+00
Para benceno use la ec I
Para tolueno use la ec I

Presin crtica, MPa

Temperatura, Kelvin

Pc=
Tc=

4.895
562.5

4.108
591.75

1bar=
1atm=
1atm=
1atm=
1atm=

100 Kpa
760 mm Hg
14,696 psi
1,01325 bar
101,325 Kpa

C
230

110

Ingresa
Presin , KPa=
Tempe, C=

101.325
89.46

Compuesto zF
A
B

Ingresa
Presin , KPa=
Tempe, C=

Pvapor, KPa
K
0.45 185.127626835 1.827067622
0.55 32.7535065978 0.323251977

101.325
110.5
Compuesto zF
A
B

Pvapor, KPa
K
0.45 316.405421773 3.122678725
0.55 65.1040031066 0.642526554

1.22482308
124.123125

T refer. ,C

PUNTO DE BURBUJA
zF*K
0.8221804301
0.1777885875
0.9999690176
3.098243564836E-005

PUNTO DE ROCIO
zF/K
0.1441070439
0.8559957505
1.0001027944
-1.02794E-04

y
0.45 0.82218043
0.55 0.177788588
1 0.999969018

x
0.45 0.144107044
0.55 0.855995751
1 1.000102794

F, Kmol/h =
zF(A)=
PF, KPa=
TF, C=
Pv A Kpa
Pv B Kpa
suma(z*K)
suma(z/K)
HlA, KJoule/kmol
HlB, KJoule/kmol
lambdaA Kjoule/kmol
lambdaB Kjoule/kmol
HvA Kjoule/Kmol
HvB, Kjoule/kmol
Hm liq Kjoule/kmol
Hm vap Kjoule/kmol
HF

Condiciones del separador ISOTRMIC

P, KPa =
101.325
T, C =
95
100
0.45
101.325
80
142.05346829
23.280969116
0.7572523439
2.7147264923
2408.7851721
2906.1264945
30295.163424
38908.255314
32703.948596
41814.381808
2682.3228994
37714.686863
2682.32

Pv
Benceno(A) 214.623418
Tolueno(B)
39.6107512
Q Kjoule/h

1534933

el separador ISOTRMICO: no hay vlvula

Fracc V/F

K
zF*K
zF/K
2.11816845 0.9531758 0.21244769
0.39092772 0.21501025 1.4069097
1.16818605 1.61935739

0.24695277 Nuevo V/F

0.24695277

g
g^2/zF
x
y
0.39429675 0.34548873
0.2
0.38
-0.39429675 0.2826726 0.64737267 0.25307592
-7.462E-010 -0.62816132 0.84737267 0.63307592

Hl
Lambda
Hv
3148.63639 29429.3161 32577.9525028
3771.00566 37948.4976 41719.5032168
3070.9733
22937.8237671
H mezcla
H mezcla

SEPARACIN FLASH
CONSTANTES EC. PRESIN DE VAPOR
Sistema:
n-Hexano(A)
n Octano(B)
C1
104.65
96.084
C2
-6995.5
-7900.2
C3
-12.702
-11.003
C4
1.2381E-05
7.1802E-006
C5
2
2

P en Pascal
T en K

Cp gas en Joule/kmol K
T en K

Calor latente de vaporzacion

en Joule/kmol
Tr es tempe reducida

CpL en Joule/kmol K
T en K

CONSTANTES EC. CP DE GASES IDEALES

C1
C2
C3
C4
C5

CONSTANTES EC. CALOR LATENTE DE VAPOR

C1 4.45440000E+07
5.51800000E+07
C2 3.90020000E-01
3.84670000E-01
C3 0.00000000E+00
0.00000000E+00
C4 0.00000000E+00
0.00000000E+00
C5 0.00000000E+00
0.00000000E+00

CONSTANTES EC. CP DE LQUIDOS

C1 1.72120000E+02
2.24830000E+02
C2 -1.83780000E+02 -1.86630000E+02
C3 8.87340000E-01
9.58910000E-01
C4 0.00000000E+00
0.00000000E+00
C5 0.00000000E+00
0.00000000E+00
Para benceno use la ec I
Para tolueno use la ec I

Presin crtica, MPa

Temperatura, Kelvin

Pc=
Tc=

4.895
562.5

4.108
591.75

1bar=
1atm=
1atm=
1atm=
1atm=

100 Kpa
760 mm Hg
14,696 psi
1,01325 bar
101,325 Kpa

C
230

110

Ingresa
Presin , KPa=
Tempe, C=

150
103.805

Compuesto zF
A
B

Ingresa
Presin , KPa=
Tempe, C=

Pvapor, KPa
K
0.45 268.739800543 1.79159867
0.55 52.8467447845 0.352311632

150
124.36
Compuesto zF
A
B

Pvapor, KPa
K
0.45 435.307867696 2.902052451
0.55 97.6338852747 0.650892568

1.22482308
124.123125

T refer. ,C

PUNTO DE BURBUJA
zF*K
0.8062194016
0.1937713975
0.9999907992
9.200826476041E-006

PUNTO DE ROCIO
zF/K
0.1550626695
0.844993516
1.0000561855
-5.61855E-05

y
0.45 0.806219402
0.55 0.193771398
1 0.999990799

x
0.45 0.155062669
0.55 0.844993516
1 1.000056185

F, Kmol/h =
zF(A)=
PF, KPa=
TF, C=
Pv A Kpa
Pv B Kpa
suma(z*K)
suma(z/K)
HlA, KJoule/kmol
HlB, KJoule/kmol
lambdaA Kjoule/kmol
lambdaB Kjoule/kmol
HvA Kjoule/Kmol
HvB, Kjoule/kmol
Hm liq Kjoule/kmol
Hm vap Kjoule/kmol
HF

Condiciones del separador ADIABTIC

P, KPa =
50
T, C =
67.62179
100
0.45
150
95
214.62341837
39.610751227
0.7891096763
2.397272227
3148.6363918
3771.0056607
29429.316111
37948.497556
32577.952503
41719.503217
3490.9394897
37605.805396
3490.939

Pv
Benceno(A) 97.8586997
Tolueno(B)
14.3816711
Q Kjoule/h

CALCULAMOS LAS DERIVADAS DE F

Diferenc T=
0.01
T+delta T=
67.63179
Pv
Benceno(A) 97.8894359
Tolueno(B)
14.3875164

Jacobiano

-0.67809732 0.03246381
-5.05695418 -0.00961668

el separador ADIABTICO hay vlvula

67.62179

Fracc V/F

K
zF*K
zF/K
1.95717399 0.8807283 0.22992335
0.28763342 0.15819838 1.91215609
1.03892668 2.14207944

0.0402155 Nuevo V/F

0.0570356186

g
g^2/zF
x
0.41476274 0.38228473
0.2
-0.40335706 0.29581258
0.566221206
0.01140568 -0.67809732
0.766221206
G1

S LAS DERIVADAS DE FORMA NUMERICA

K
zF*K
zF/K
1.95778872 0.88100492 0.22985116
0.28775033 0.15826268 1.91137924
1.0392676 2.14123039

Jacobiano
inversa

-0.05634032 -0.1901927
29.6267035 -3.97270519

g
x
0.41501923
0.2
-0.40328892
0.566221206
0.01173032 0.03246381
G1

Vector
G

0.0114056773
0.3201580033

0.0402155

Hl
Lambda
Hv
0.38 1873.56847 30981.576493 32855.1449642
0.16286414 2275.83876 39672.654124 41948.4928872
0.54286414 1663.34186
19316.8604457
H mezcla
H mezcla

0.320158 -5.056954184
G2

Hl
Lambda
Hv
0.38 1873.97437 30981.03152 32855.0058897
0.16286414 2276.31859 39672.04606 41948.3646512
1663.69473
19316.7867123 0.32006184 -0.0096166762
H mezcla
H mezcla
G2

Producto
JG

-0.0615343153
-0.9339807426

Nuevo V/F
Nuevo T

0.1017498153
68.555770743