Sie sind auf Seite 1von 11

2012 7 30

Evaluation of Corrosion Resistance of Medium Carbon


Steel Using Different Protection Methods
Firas Farhan Sayyid
Production Engineering and Metallurgy Department, University of Technology/ Baghdad
Email: firasabomohamed@yahoo.com
Ali Abdul Munim Ali
Technical College, Foundation technical/Baghdad
Email: ali_techno@yahoo.com
Wadhah Adel Tawfek
Minsitry of science and Technology/Baghdad
Email:wadhahsammaraie@yahoo.com

Received on: 19/7/2011 & Accepted on: 5/1/2012

ABSTRACT
This research involves studying the effect of some different protection methods
to increase electrochemical corrosion resistance of medium carbon steel (DIN
CK50) in 3.5% NaCl by applying coating with Cr and Sn, with addition of
inhibitors (No3, PO4 , MnO4=and SO4=) and application of cathodic protection
by sacrificial anode using Zn anode.
Evaluation of corrosion resistance after different protection methods were
measuring performed by static potential test and measurement of corrosion
parameters (potentional and current density) by Tafel extrapolation method. The
surface of protection specimens was examined by using optical microscopes.
The corrosion rate results show that using coating and inhibition methods give
good results in increasing the corrosion resistance compared with the cathodic
protection which gives an objective result depending on sacrificed pole.


( 3. 5% NaCl )( DIN CK 50 )


.(E Zn= -0.76 V)

. ) (


.

158

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

%85
] .[1

.

.





.
) (pH
].[2
) (pH ) (pH
)(
.


.
(Metal
) Surface Preparation .



.
.
[3] Lowen
. [5-4 ] Praveen
.



.

Nervana
] [6

159

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

. [7] Aramide
.%4


.



] . [8
-1 Sacrificial Anodes
-2 Impressed Current
[9 ] William

) .(1

) (1


.
:
:
)(Metal Selection
) ((DIN CK50

) . (1

160

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

) (1 .
Fe

Re
m

Cu V

Mo

Si

CR

Ni

Mn

0.3
5

0.0
3

0.21

0.24

0.14

0.8
6

0.
5
1

W.
%



) (G 71-30 ASTM
) (0.2 * 1.5 *1.5.

) (2
.
) (2

D
E


:
-1 ) (Rotating Grinding )
Grid (1000-800-500-400-250-180 .
-2 Al2O3
. 0.3
-3 : ) %2
% 98 + ( .
161

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

-4 ( Computerized optical
) microscopy /
). (2

) (2 40x

] [4 ) (B,C ) (2
:
-1 ) (Na2CO3
) (30-45 gm/L ) (Na3PO4.H2O (30-
) 45gm/L ) (NaOH (7.5-15
) gm/L
) (stainless steel 6
.
.
-2
%5 15
-3
.
). (2
-4

-5
) (20*20*20
%7

).(DC
-6 :

-1 100 /
50 / 150 / .
162

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

-2 250 /
1 / .
-7
)(3

) (3

70

25

)(Sn

25

)(Cr


)(3.5% NaCl
35 1000 .
) (pH ) (pH meter ) .(6.9
) ( potentiostat )
( MIab200of Bank Elec. ) ( Germany 3 mv./sec
) (3

) . (3

) (3

100 _+

163

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

.
A,B,C ) (2 .

) (

) ( D
.

) (4

7.49
) ( E ) (2 potentiostat
) (3 ) (4

ppm

) (4

80
80
5

) (4 A,B,C,D,E ) (5
) (5
.

)(C
)(A

)(B

)(D

)(E
) (4 .

164

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

) (

165

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

.
) (5
:
).(1

eq.wt

Icorr

0.13

)(mpy

C.R

).(5
) (5
Corrosion rate mpy

)Ecore (mV

5.94
3.5068
4.84
10.692
1.38248

-409
-498.5
-351.4
-862.4
-688.8

Icore
)(A/cm2
13.5
7.97
11.79
24.3
4.3

Specimen
sample
A
B
C
D
E


) (2

) ( 4

166

PDF created with pdfFactory Pro trial version www.pdffactory.com

30 2012 7

A E
.

) (5
10
100 _ + )_ 0.44
_ 0.17 _ ( 0.14 ) (5




.

O2 + 4e +2H2O
4OH

Fe
2e + Fe +2

.
) (5) (5 E

B
A
C

.
D

)( ) (.

-1
-2 .
-3
.
-4
.

[1] Alstom Bosch, Corrosion of Carbon Steel , keyto Metals


Steel,2000.
[2] Dieter Landolt, Corrosion And Surface Chemistry Of Metals,
EPFL Press, Italy, 2007
167

PDF created with pdfFactory Pro trial version www.pdffactory.com

2012 7 30

[3] Lowen Heim F.A "Electroplating ", Mc Graw-Hill , New York , 1978.
8- [ 4]
.1989 117-95 :
[5] Praveen, B. M., Venkatesha, T. V. Arthoba Naik, Y. and Prashantha, K.
"Corrosion Studies of Carbon NanotubesZn Composite Coating" Surface
& Coatings Technology 201, 2007, 5836-5842
[6] NERVANA A. ABD ALAMEER" Studying the Effect of Sodium
Silicate as Inhibitor on the Corrosion Rate of Carbon Steel" F.T.T.
scientific International conference In Najaf 2010
[7] Fatai Olufemi ARAMIDE "Corrosion Inhibitors of AISI/SAE Steel in a
Marine Environment", Leonardo journal of sciences 15, 2009, P.47-52 .
[8] Samuel Afolabi "Synergistic Inhibition of Potassium Chromate and sodium
Nitrite on mild Steel". Leonardo Electronics Journal of practices and
Technologies 11, 2007, P.143-145
[9] William T. Scannell and Ali Sohanghpurwala" Cathodic Protection as a
Corrosion Control Alternative" CONORR Inc. Concrete Repair Bulletin,
July 1993
[10] Kim, D. K., Muralidharan, S., Ha, T. H., Bae, J. H., Ha, Y. C., Lee, H.
G. and Scantlebury, J. D. "Electrochemical Studies on the Alternating
Current Corrosion of Mild Steel under Cathodic Protection Condition in
Marine Environments" Electrochemical Acta 51, 2006, 5259-5267.
[11] Article, Carbon Steel- Corrosion Technology Laboratory
(file//H:KSC Corrosion Technology laboratory Materials Selection.htm
3/11/2009.

168

PDF created with pdfFactory Pro trial version www.pdffactory.com

Das könnte Ihnen auch gefallen