a. Prepare a graph showing P vs x1 and P vs y1 for T = 348.

15 K (75
Acetonitrile (1)
Nitrometana (2)

T=
ln P1 sat

A
14.2724
14.2043

B
2945.47
2972.64

C
-49.15
-64.15

348.15
4.42132977

P1 sat

83.2068575

sat

3.73725775

P2

41.9827049

P1 sat

P2 sat

ln P2

83.2068575 41.9827049
83.2068575 41.9827049
83.2068575 41.9827049
83.2068575 41.9827049
83.2068575 41.9827049
83.2068575 41.9827049
83.2068575 41.9827049
83.2068575 41.9827049
83.2068575 41.9827049

x1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8

sat

P
Y1
41.9827049
0
46.1051202 0.18047205
50.2275354 0.33131969
54.3499507 0.4592839
58.472366 0.56920466
62.5947812 0.66464692
66.7171965 0.74829455
70.8396117 0.82220666
74.962027 0.88798941

83.2068575 41.9827049
83.2068575 41.9827049

0.9
1

79.0844422 0.94691408
83.2068575
1

SAAT KOMPOSISI
KONSTAN
X1=Y1
P(kPa)
0.6
0.6
0.6
0.6

45
59.74055
66.71522
80

SAAT TEKANAN KONSTAN 1 DAN Y = 0,6

59.74055
0.6
59.74055 0.43404425
SAAT TEKANAN KONSTAN 2 DAN X = 0,6
66.71522
0.6
66.71522 0.74829455
100
80
80 Subcool
f(x)
= 41.224152519x + 41.9827049461
66.7152266.71522
f(x)ed
=
27.5642727987x^2
12.3648648575x
+ 42.5343636333
59.74055 59.74055
=1
R Liquid
=R
0.9988273488
60
P(kPa)

45

40
20
0
0

0.2

0.4

0.6

0.8

X1,Y1
BUBBLE LINE

Linear (BUBBLE LINE)

DEW LINE

Polynomial (DEW LINE)

CONSTANT COMPOSITION

COSTANT PRESSURE 1

CONSTANT PRESSURE 2

= 348.15 K (75 C)

Keterangan :
menggunakan persamaan bubble line:
y = 41.224x + 41.983
dimana
x= fraksi (X1 atau y1)
y= tekanan (P)
X1= 0.6
jika,
maka,
sehingga,

P= 66.7174
Y1= 0.7482945497
menggunakan persamaan dew line:

y = 27.564x2 + 12.365x + 42.534

Y1= 0.6
jika,
maka,
sehingga,

P= 59.87604
X1= 0.43404425

b. Prepare graph showing t vs x1 dan t vs y1 for P=70kPa

A
14.2724
14.2043

Acetonitrile (1)
Nitrometana (2)

untuk P=
70 kPa
T1 sat = 342.9946
T2 sat= 362.7336
T(K)
362.7336
359.15
355.15
351.15
347.15
343.15
342.9946

lnP1

C
-49.15
-64.15

P2sat

X1

ln 4.248495

P1sat

4.8795 131.5604
4.7709 118.0235
4.6467 104.2384
4.5192 91.7611
4.3883 80.5012
4.2538 70.3719
4.2485 70.0001

SAAT KOMPOSISI KONSTAN

X1=Y1
T(K)
0.6
362.7336
0.6
359.15
0.6
347.15
0.6
343.15

B
2945.47
2972.64

lnP2
4.2485
4.1276
3.9890
3.8467
3.7003
3.5497
3.5437

70.0000
62.0260
54.0031
46.8368
40.4583
34.8021
34.5960

0.0000
0.1424
0.3184
0.5156
0.7378
0.9895
1.0000

Y1
0.0000
0.2401
0.4742
0.6759
0.8484
0.9948
1.0000

SAAT TEKANAN KONSTAN 1 DAN Y = 0,6

352.728
0.6
352.728
0.4351
SAAT TEKANAN KONSTAN 2 DAN X = 0,6
349.572
0.6

0.6

342.9946

349.572

0.7473

Untuk T konstan pada x1 = 0,6 dan P = 70 kPa dievaluasi dari bubble line menggunakan metode iterasi.
dengan persamaan :
dimana

P1sat dan P2sat ditentukan dengan Antoine Equation

Iterasi
a'
1.971

P2sat
44.229

lnP2sat
3.789

T (K)
ln a
a
349.5714 0.678555 1.971027

a'-a
0.000

Untuk T konstan pada y1 = 0,6 dan P = 70 kPa dievaluasi dari dew line menggunakan metode iterasi.
dimana

metode iterasi sama dengan di atas, tetapi menggunakan rumus T sebagai berikut

a
1.948

P1sat
96.534

lnP1sat
4.570

T (K)
352.728

DEW LINE
BUBBLE LINE
CONSTANT COMPOTITION
CONSTANT TEMPERATURE 2

ln a
0.66657751

a
1.948

a'-a
0.000

Polynomial (DEW LINE)

Polynomial (BUBBLE LINE)
CONSTANT TEMPERATURE 1

DEW LINE
BUBBLE LINE
CONSTANT COMPOTITION
CONSTANT TEMPERATURE 2

Polynomial (DEW LINE)

Polynomial (BUBBLE LINE)
CONSTANT TEMPERATURE 1
362.7336

365

360 f(x) = 5.6348573683x^2

- 25.304189808x
+ 362.6850213964
- 7.4256658694x^2
- 12.1465566483x
+ 362.6441485907
R = 0.9999664776
0.9997755086352.728 352.728
355
349.572
350
349.572
T(K) 345
343.15
340
335
330
0

0.2

0.4

0.6
X1Y1

0.8

1.2

AN 1 DAN Y = 0,6

AN 2 DAN X = 0,6

menggunakan metode iterasi.

jika:
P= 70
X1= 0.6
X2= 0.4

Jika :
1= a 2
P1 sat= 87.18056
1=(1 1)/
Y1= 0.747262

ggunakan metode iterasi.

NE)
RE 1

P= 70
Y1= 0.6
Y2= 0.4
1= (1 )/1
X1= 0.435081

menggunakan persamaan bubble line:

NE)
RE 1

850213964
2.6441485907

y= -7.4257x2 - 12.147x + 362.64

dimana
x= fraksi (X1 atau y1)
y=suhu(T)
X1= 0.6
jika,
maka,
sehingga,

T= 352.678548
Y1= 0.74829455

menggunakan persamaan dew line:

y = 27.564x2 + 12.365x + 42.534
Y1= 0.6
jika,
1

1.2

maka,
sehingga,

T= 59.87604
X1= 0.43404425

species 1

CO2

Henry's Law

x=

fraksi liquid

species 2

water

Raoult's Law

y=

fraksi vapour

sehingga,

diasumsikan bahwa fraksi CO2 dalam air adalah 0.01

x1
0.01
y1

0.99

H1

990 bar

P2sat

A
B
C

0.01227 bar

Antoine Equation

T(K) =

CO2

H1

P(bar)

H1

P(kPa)

H2O

6.81228
1301.679
-3.494

16.262
3799.89
-46.8

ln P 1sat

2.1577079543

P 1sat

=
=

8.6512857745 kPa
0.0865128577 bar

=
=
=

0.1846147662
1.202755009 kPa
0.0120275501 bar

ln P 2sat

(steam table)

283.15

x1

x2

0.01

0.99

maka fraksi vapor CO2 hampir murni yaitu 0.

x1

y1

x2

1
0.6

0
0.4

0
0.4

P
990
594.00481

x1

x2

1.000
0.600

0.000
0.400

0.5
0.4
0.3
0.2
0.1
0

0.5
0.6
0.7
0.8
0.9
1

0.5
0.6
0.7
0.8
0.9
1

495.00601
396.00722
297.00842
198.00962
99.010825
0.0120276

0.500
0.400
0.300
0.200
0.100
0.000

0.500
0.600
0.700
0.800
0.900
1.000

Chart Title
1200
1000

Axis Title

f(x) = 989.9879724499x + 0.0120275501

800 R = 1
600

bubble line

400

Exponential (dew line)

200 f(x) = 0.0120241122 exp( 10.2851802063 x )

R = 0.9641783691
0
0
0.2
0.4
0.6
0.8
1
1.2
Axis Title

Linear (bubble line)

dew line

990
99000

y1

x1

y2

y1

9.9121473

0.01

0.0012

0.9988

O2 hampir murni yaitu 0.9988

y2

y1

0.000
0.000

1.000
1.000

0.000
0.000
0.000
0.000
0.000
1.000

1.000
1.000
1.000
1.000
1.000
0.000

Chart Title
1200
1000

ble line

ar (bubble line)

line

onential (dew line)

Axis Title

f(x) = - 989.9879724499x + 990

800 R = 1
600

bubble line

400

Exponential (dew line)

200 f(x) = 352.2492122925 exp( -10.2851802063 x )

R = 0.9641783691
0
0
0.2
0.4
0.6
0.8
1
1.2
Axis Title

Linear (bubble line)

dew line

bubble line
Linear (bubble line)
dew line
)

Exponential (dew line)