Total No. of Questions: [Total No. of Printed Pages—s T—8053A1 CHEMISTRY (Hindi & English Versions) Time : 3 Hours. Maximum Marks = () ait we4 eet safe) (2) FA wate 1 8 6 aH wea yer 2 te an E gen ares ges oot ol eee eT 30 We (3) TR wate 7 4 o2’ae cee ee 3 Se an S cen Wee 50 Te Se a ea 4) yeomie 34 7 aewee Te 4 de aE aq wee we oo st aba 7s we 2) (5) We esis 18 3 22 7H WE A ‘ATaI 150 Wee ZI wre cen yee wet ot ot ae 6) We WH ame sek ate ante me 2 Instructions : 1) Attempt all questions. 2) From Question Nos. 1 to 6 each question carries 2 marks. Answer each question in maximum of 80 words. (3) From Question Nos. 7 to 12 each question carries 3 marks. Answer each question in maximum of 50 words. (4) From Question Nos. 13 to 17 each question carries 4 marks. Answer each question in maximum of 75 words. (5) From Question Nos. 18 to 22 each question earries 5 marks. Answer each question in maximum of 150 words. (6) Marks have been shown against each que: K—1—T—8058A1 P.T.O.atin a arnt [O,| & TTR aT Tafa 2 Write the value of bond order of Oxygen moleeule ion 10,1 3.7 on SE a aT Give any four applications of heat of combustion: Teeter atest w afiata afiieset ¥ 2H (b) 2NH,—#5N, +8H, (ec) NH,NO, > N, + 21,0 (@) 2NO + 0, + 2NO,, K-1—T—8053A1(3) 16. afates war afraid & aba. eaaT, () (CoClen),. NHI (=) KIP,| (7) JAgONH,).ICL 3) INKCO)! 4 Write IUPAC names of the following coordinate compounds/ions : (a) (CoCKen), NH} bd) KIPU,) () [AgNH,), [Ni(CO),|- 2a aera = fees ot ata aire Ft seem fete) gaat Fe fea aia 8? Fast See aE? aie eT aa ST aT TS ETT BE Write the definition of molecular conductance of electrolytic solution. By which symbol it is expressed ? What is its unit ? What is the effect of dilution on molecular conductance ? z faarm, are fees we aah frase PR aes EB? ate sere ales fea 4 ASE! 14242 What are solutions, ideal solutions and non-ideal solutions ? Explain in detail with suitable examples. 79. 34 sae Heat Sa fafan st waa sh ae: yatta at Fira 1 fata s, wor, § coment) Peewee) 3p fee AH ATA 953.86 J mol! 1 sara yaw A seth afters ai TAT 95.5°C aa sitau an wae fe a oh een ofa Saha Eh prera] K-1—T—805541 PTO.(6) Name the state variables that determine the spontaneity of a process. For the following transition Soxhombiel AIT is 353.85 J mol. Calculate the entropy of transition at 95.5% which form is more in order. and state 20. Fraaiaa state at servo ates we stay, ud Taree (&) asi aaa (a) wea do CD fe afuie (a) aris (3) WEE PUTT | 5 Explain the following reactions with example and give chemical equations also: (a) Benzoin condensation (b} Aldo! condensation (e) Perkin reaction (@— Todoform reaction (e) Friedal-Craft’s reaction saat (Or) warren F efea wis aaa a fale er avi fees fest & are aifae Ce) ayer arf faa (a) aff a cari aac (T) faia an Stam aoa 241 Describe the laboratory method for the préparation of othylamine un: following points : (a) Labelled diagram of apparatus K-1T—8053A1(b) Equations of reaction (c) Brief description of the method. 2). tm %, 3a Gera cae ote aise) : Ce) cries on, wife uneegee & aa feat Hee (3) wrirsrE Aaa HWS fen aT e m1) aif sree ara fen ao = (a) OC a A ys USSR Kings A tes Fe ~ What happens, when (Give chemical equations only) : (a) Diethyl ether reaeis with Acetic anhydride (h) Formaldehyde reacts with Ammonia (ce) Avetone reacts with Methyl magnesium iodide cd) Avetaldehyde reacts with dry Hydrogen chloride at temperatu (ec) Benzaldehyde reacts with Aniline ? swat (Or) Explain only by chemical equations of the following changes : (a) Formic acid into Acetic acid (b) Acetic acid into Formic acid K-1—T—8053A1 PTOK- c) Formaldehyde into Acetaldehyde d) Acetaldehyde into Formaldehyde lel Aver ne into Acetone. free waa us aefraa it ar ae a FAHY BASTST | Explain Tyndall ef and Brownian movement with appropriate diagram, waat (Or) rain a re sar aed $7 ates Soe qe squint a aula aitam What do you understand by Adsorption ? Describe its five main applications S063A1Total No. of Questions—22] T—8053B1 CHEMISTRY (Hindi & English Versions) ‘Time : 3 Hours Maximum Marks : 75 ) at a ra si [Total No. of Printed Pages—8 (2) 7 wale 1S 6 me Wee Wa 2 ate we WN eee Sar aT ei 30-9 #1 (3) WH wee 7 3 12 ce ea 3 ae ae 50 eee @) Te eee 3417 7 gees var ae me ae ae ae aa as eT ‘aT 150 We EI (6) Jere we ae cee ste emg ag 1 Instructions : (1) Attempt all questions. (2) Prom Question Nos. 1 to 6 each question carries 2 marks, Answer question in maximum of 80 words. (3) From Question Nos. 7 to 12 each question carries 3 marks: Answer question in maximum of 50 words. From Question Nos. 18 to 17 each question earries 4 marks. Answer question in maximum of 75 words. From Question Nos. 18 to 22 each question carries 5 marks. Answer question in maximum of 150 words. (6) Marks have been shown against each question. K-1—T—8053B1 aan Were SH SAS yea We each each each each P.T.0.1. GR SES SH (OF S eRe A om fafa) Write the value of bond order of super oxide ion lo,1- 2. ates gfe are free & wae FT TE Teer e? What density of the crystal is changed due to Schottky defect ? 3. US 9 FT ee ST oT aT) Caleulate the molality of pure water. Write four applications of Gibbs-Helmholtz derivation. aire frases ws aera des FS aa fafiac Write two differences hetween Nuclear fission and Nuclear fusion. 6. atefie torn fee qed 87 as ct seer ST) What are acidic dyes ? Give any two examples. ial cui at Aen ara afer U4 Ysietes freer war pb a afelia 2 wpe a ad ae Calculate the number of alpha and beta particles emitted when ,,U?* undergoes radioactive disintegration to form ,,Pb2". 8. Feith fees ara a SP, arnt ferftan, (=) dae (a) dae safes deat Write differences on the basis of the following points between S: molecule ; (a) Hybridisation (b) Bond-angles () Geometry and structure. K-1—T—8053B13) 9. am mgt wd Sas cer gas ae at Ser a fam or eT aE EP Why Alkali métals and their salts give different colours in the flame of Bunsen’s burner ? saat (Or) fotan) What are Inter halogen compounds ? Write the kinds, properties and examples of inter halogen compounds, 10. aici sera eit 2, fara ests sees ue we 2? SE da srs ae aise) 3 Why water is neutral, but hydrogen sulphide is weak acid ? Give any three suitable reasons. 11. Sao asi ete: fanart fof Write six properties of transition elements. srt (Or) TA GEES! F tia yee sede fata) Write three uses of Lanthanides and Actinides each, air at im fa agai & am, gees wl site fake Write names of three copper alloys, composition and their uses samedi * faery ai grate orem a1 often tafe Ll gare ee Saha BRT oO fear ait 8? eee sed an 27 grat aT IA Te TMT BL AT Ta ygaT BP Tde bez Write the definition of equivalent conductance of electrolytic solution By which symbol it is expressed ? What is its unit ? What is the effect of dilution on equivalent conductance ? K— 805381 P.T.0.(4) 14. reife cases afta & anh q die (#) KIPtINEL)CL (@) NalCo(CO),) (7) [NiDMG),] (a) NalAu(CN),1 Write IUPAC name of the following coordinate compounds (a) K(PUNH,JCL (b)- Na{Co(CO},] (©) INi(DMG (@)— NatAu(CN),] (a) thats 22 Write the equations for the synthesis, properties and uses of the following polymers : (a) Terylene (ob) PVC, saat (Or) SUR oat S ar agers a aia seer aed STE Classify polymers on the basis of interparticle forces with examples 16, frafetaa we Aten feminat fate : (#) stare da (a) sires K—1—T—8053B1Write short notes on the following : (a), Immune system (b) Antibodies. wat (Or) What are Carbohydrates ? Write their functions and Far atta wi ad fafa 1 sification. afiten a aie fa aed 22 fa stated at atte ar Freier (#) HB, +1, > 2HL fe () NH, N,+3H, (1) NHNO, > N, + 2H,0 (3) 2NO + 0, > 2NO,. What is Order of Reaction ? Determine the order of reaction of the following reactions (a) Hy,+1,> ut (>) 2NH, (e) NH,NO, > N, + 2H,0 (@) 2NO + 0, 2NO,. 38. = ea 2, 3a (Sas Tate ore dfs) : (&) sean ex, tetfer trees $ wa fra HoT F (a) wifes, oid & oe fea Sete afea Scie actess & aa fren ae t (a) titiecers 0°C am we sedi aehuss a fen sea = (S) wairsers, K—1—T—8053B1 P.T.O.(6) What happens, when (Give chemical equations only) : (a) Diethyl ether reacts with acctic anhydride (b) Formaldehyde reacts with ammonia (c) Acetone reacts with methyl magnesium iodide (d) Acetaldehyde reacts with dry hydrogen chloride ai 0°C temperature (e) Benzaldehyde reacts with aniline ? sweat (Or) (@) via ope 4 teifer op (3) tifea ora 8 vifts ora (7) whitsess 8 titicsese (a) ta Explain only by chemical equations of the following changes : (a) Formic acid into acetic acid . (b) Acetie acid into formic acid (©) Formaldehyde into acetaldehyde (a) Acetaldehyde into formaldehyde (e) Acetylene into acetone. Tae, Tae aa ait aaa fase fea wed $2 Taifes faa ed see aT AARC | 1-22 6 What are Osmosis, Osmotic pressure and Isotonie solutions ? Explain with suitable labelled diagrams and examples. AER | 24+ 20. faveq wars TS ashe aia at Tat Explain the Tyndall effect and Brownian movement with appropriate diagram. 8053B1CT) saat (Or) Sin 4 a aan seed #2? afi & she per oranda a Fifer) What do you understand by Adsorption ? Describe its five main applications. 2). SI, SESSA Us GSTs ST Cer Weed HTT: - 97, - 68.4 AM -783.4 Keal mol! =! asia ai aver Sen an alfa) (sur carats aie sear 8) Enthalpy of combustion of earbon, hydrogen and benzene are — 97, - 68.4 and ~ 783.4 Keal mol respectively. Calculate the heat of formation of benzene (Thermochemical equations are necessary) 22. fy afters =1 seem afes fate we caret wea at cis (=) eps shia (3) Firat af SAT Cl) neat at tfesees deem (3) fre atest (2) after state 5 Explain the following reactions with example and give chemical equations also (a) Rosenmund reaction (b) Cannizaro reaction (c) Gatterman Koch aldchyde synthesis d) Schimds reaction (ec) Carbylamine reaction. K—1—T—8053B1 P20.(8 saat (Or) yarn 4 tela aa at fate a ac fr fer (=) sea a aniPeT fea (a) sfiien a carter aia @) fata-ar fret ot a Describe the laboratory method for the preparation of aniline under the followin points : (a) Labelled diagram of apparatus (b) Equations of reaction (c) Brief description of the method. K-1—T—8053B1 26,685Total No. of Questions—22] (Total No. of Printed Pages—S T—8053C1 (CHEMISTRY (Hindi & English Versions) ime : 3 Hours Maximum Marks : 75 frst : (baat wa ge site (2) Wea wae 18 6 om Fete oer 2 Se a1 t wen gets oe oe eT We 30 We FI (3) Teas 7 912 3H FP Te 3 ae art Te Wee eT RY ee 50 wz EI wat ta Wee we oer Fi we (3) 3 wary is B22 wa we wer s see ar boa wee eR & ate at arn 150 we %1 (6) Wee we & apt sath oie autem EI Instructions : (1) Attempt all questions. From Question Nos. 1 to 6 each question carries 2 marks. Answer each question in maximum of 80 words. (3) From Question Nos. 7 to 12 each question earries 3 marks. Answer each question in maximum of 50 words. (4) From Question Nos, 13 to 17 each question carries 4 marks. Answer each question in maximum of 75 words. (5) From Question Nos. 18 to 22 each question carries 5 marks. Answer each question in maximum of 150 word: 6) Marks have been shown against each question. K—1—T—8053C1 PLT,(2) 1 Wass a [Op] FA aan fefiaus Write the value of bond order of Peroxide ion [0,~| AgCl freee 8 eee aro sat eH eT Fz? 2 Why is Frenkel defeet found in AgCl crystal ? PPM aan @ sfentan ae Fa TE Fe Define Concentration in PPM and write its formula. 4 ea} fee ae aged fetes 2 Write four applications of Hess's law. 5. Fam wi wrptee dredefeeaar A ot ae fatal 2 Write down two differences between Artificial and Natural Radioactivity sire wae war 2) ee Gece What are Rocket propellants ? Give any two examples. fede different colours in the flame of Bunsen’s Why Alkali metals and their salts giv burner ? zaat (Or) ara farsa Hw A wea BP aR Sein ie Fe wen, TM et seers ferfiae What are Inter halogen compounds of inter halogen compounds. 2 Write the kinds, properties and examples 5. ada ci weit at faraites fagal H erae we geet atts : (#) aEETH (a) fags aa (ar & afta 3 K-1—T—8053C1Compare Boron and Aluminium under the following poin a) Allotropy b) Electric conductivity (c) Reaction with steam. sen 3 dn fa aga & am, dees Gi ae orn faa Write the name of three Steel alloys, their composition and uses. aa & am 7 suiea HOW desta & on 4 eee areeS oy F sah H—S—H ae S10 Hs ela Ee | aT? Fe I eT aT eae) 3 H—S—H bond angle of Hydrogen sulphide molecule is less than H—O—H bond angle of water molecule, Why ? Give any three main reasons Sag 12% See Fa fated) 8 oe: Sean oe et ae wR oe? Write the name of the members of 12th group. Why they are normally not considered as transition elements ? saat (Or) arates tam act sa ea S 2 What are Inner transition elements ? 8 & Uediuises fae & ava | Pb! a oaahis ee wae eR ae eS rer ait wT eM ST ATTY Caleulate the number of alpha and beta particles emitted, when ,, radioactive disintegration to form PI undergoes afatra wie fea mea 2? fas afatensit st aife a ator sta (%) Hy +1, > 2H0 (3) NH, —5N, +3H, NHN |, + N, + 2H,0 2NO + 0, 4 2NO,. S053C1(4) What is Order of Reaction ? Determine the order of reaction of the followir reactions : (a) Hy +1, > 2HI b) 2NH, +N, +3Hy, lo ON NO, > N, + 2H,0 (d) 2NO + ©, 14. Preifee ages ® deen ar iia, qa we san fafer : CH) Sra (a) wider Write the equations for the synthesis, properties and uses of the following polymers : (a) Bakelite (b) Polystyrene. saat (Or) arden 3 aero agers ar ater saree afer SiH Classify polymers on the basis of synthesis with examples. frafaten 1 afi femtinat fata : (H) ota (a) sire Write short notes on the following (a) Immune system (b) Antibodies. saat (Or) amiesge an 2? a ote wi ae fefeqs 143 What are Carbohydrates ? Write their functions and classification. K-1—T_-8053C1(5) fasifes nee Tie & arias wee a am fate: (#) [Pt(Py),] IPtCl,] (B) KIFeCN) i (9) (ColNHY,CHCI,. + (™) [Rel Write IUPAC name of the following coordinate compounds (a) [PUPy),| [PLC] (b) K{FelN)J (ec) [Fe(CO),) (d) [Co(NH.,),CHCL,, 19 Write the definition of specific conductance of Blectrolytic solution. By which symbol it is expressed ? What is its unit ? What is the effect of dilution on specific conductance ? fever wera (So arenas aie at Sa faa RE AAT Explain Tyndall effect and Brownian movement with appropriate diagram. sat (Or) afin @ ae ar aren 2? afeiom & sia ger age a at Fifa) What do you understand by Adsorption ? Describe its five main applications. aa dia %, sa (ee cara aie Sar) + (#) zevfue ta, wife Weegee * ma feat art = K—1—T—8053C1 P.T.0(6) (a) whtecess, ster & a fea arH (1) wir, Sfas aces arises & ay fen em & SOC RTH F wticia 4 feat rat? What happens, when (Give chemical equations only) : (a) Diethyl ether reacts with Acetic anhydride (bo) Formaldehyde reacts with Ammonia (c] Acetone reacts with Methyl magnesium iodide (a) Acetaldehyde reacts with dry Hydrogen chloride at 0°C temperature (ec) Benaaldehyde reacts with Aniline ? sagat (Or) CH) wits ora aan ora 4 (a) Gites aa a vite aa (1) wittresss & Uticireewe (a) Wieftsas 4 HFicsees (S cwiizeas a caer Explain only by chemical equations of the following changes 2) Formic acid into Acetic acid (b) Acetic acid into Formie acid (c) Formaldehyde into Acetaldchyde (d) Acetaldehyde into Formaldehyde (e) Acetylene into Acetone. K-1-8053C1(7) 20. 26°C TH data wa wiifecta Ft cea Tae HAT: — 1598700 Cal. a4 — 620100 Cal. #1 26°C aa 3 wifes a damn a 4 Sse ST Sees Se FI wifsat Enthalpy of combustion of benzene and acetylene are — 1588700 Cal, and = 620100 Cal. respectively at 25°C. Calculate the heat of formation of benzene from seetylene at oy sit wi wate asian at dif Explain the following reactions with example and give chemical equations also : (a) Stephen's reduction reaction (bd) Hofmann bromamide reaction (c) Musturd oil reaction (d) Hell-Volhard-Zel: y reaction (ce) Gabriel phthalimide reaction. waar (Or) vam 4 seule det aan ai fate ar aol fre forget & svar 1 sitar (a) afsiea a carte sitet ct) fafa &r ait | ried K-1L 0301 PT. 0.8) Describe the laboratory method for the preparation of Diethyl ether under the following points = (a) Labelled diagram of apparatus (b) Equations of reaction (c) Brief description of the method. ape, ane f ae we ana 8 aif oremen fara aed 8? ata, Ue sep Serer afer SET! eal What are vapour pressure, lowering of vapour pressure and relative loweri! of vapour pressure ? Explain with equations, formula and suitable examp! 805301 25,685‘Total No. of Questions—29) [Total No. of Printed Pages—8 T—8054A2 CHEMISTRY (Hindi & English Versions) Time : 3 Hours Maximum Marks : 75 2) WH wate 1a 6 we ween Ue 2 ste ate an ute wee aK Fh -sie] 30 YF) (3) Fe wale 7 312 ae cee we 3 Se 2 ae See a area 50 re = (4) Rea wale 13 817 we Wee wer 4 she ae nen yee ea sae a we AT 75 we 2) (5) WA wate 1s 3 22 ww mete vers ste aE wen wee we & ae at oe PT 150 we 2) (6) Welw WH & am sae ate aie mee Instructions (1) Attempt all questions, From Question Nos. 1 to 6 each question carries 2 marks. Answer each question in maximum of 30 words (3) From Question Nos. 7 to 12 each question carries 3 mar! question in maximum of 50 words. Answer each (4) From Question Nos. 13 to 17 each question carries 4 marks, Answer cach question in maximum of 75 words. (5) From Question Nos. 18 to 22 each question carries 6 marks. Answer éach question in maximum of 150 words, (6) Marks have been shown against each question, K—1—1—8054A2 P.T.O,(2) aan an 8 zee en ST on saat 2 What is Bond order ? Caleulate the bond order of N molecule. afer & Sra ST ata ee a aa fares 8 Wat NaOH 300 WH Sa H Yen 21 ea fares FT Aree a 8 gm NaOH solution. dissolved in 500 gm of water. Calculate the molali fon ga wen fer area w ofa = were Yen aera What is the relation between heat of reaction at constant pressure and constant volume 7 aye facuiaa fran See ERT SATET| 2 Explain group displacement law with an example. wisi gen aes A aan ate 3? 2 What is meant by Chromogen and Auxochrome ? afer fue Bary SH WHT T? 3 What do you understand by Breeder reactor ? aicias & sams oan & wen ere F? What are the reasons of anomalous behaviour of Beryllium ? ais oie wea a ge ve are gt ah S eeare SA ge fo en E? How is stecl obtained by Siemen and Martin's open hearth furnace process fafstre aa fafeata oe fecctnat fafee 3 Write notes on Silicates and Silicones. T8042(3) mae dare en 8? sah aa aR What is Lanthanide contraction ? What are its consequences ? saat (Or) sane vn wacres HT Ta FST Compare Lanthanides and Actinides. aii wi aaa? ar not form Pentahalide ? Give reason, Why Nitrogen do aeat (Or) aver fi CO, 48 @, saPr SiO, 3s 1 FH? Explain CO, is a gas whereas SiO, is solid. Why ? 13. Geatet war antes: arena a) ofan a saat wrest aa 4 Give definition and units of equivalent and molar conductivity, 14. stata apiargae & en cities 2? fre aif fin yam sae aT agargart wifes arr ve Pelt vet aT What is meant by half-life period ? Prove that for the first order react halflife period does not depend upon initial eoncentration. fay sonestiist aie & IUPAC = fatag () Na,[NWEDTA)] Gi) Nal{AwCN),) (ii) NH,[CrNH,)(NCS),] iv) KINWCN)) 4 K-11 805442 P.T.0.(4) Write the IUPAC name of the following coordinate compounds @) Na INEDTA)) (ii) NalAwCN),] (iii) NH, |Cr(NH,), NCS) | Gy) KINKCN),| 16 FE ageret st rr at fats, am ait sadn fare « (i) FIER (ii) Seta a Write method of preparation, properties and uses of the following polymers () Nylon 6 (ii) Terylene. Bat (Or) aera wi atte awiee ae om wz Sa fen ame? How are polymers classified based on inter particle forces ? 17. wierel fa en 2 a fire wee feesfaa erat 27 4 What is Immune system ? How is it developed ? amet (Or) aid ot ee aris & orm, oe area get act aha en ae san fae Write the name of any two steroid hormone glands by which it is secreted and its uses, 18. Sisal ers saan fers @ ary eq uemt #? fia hoop wi aaa cee Pert 2 mere caf ad ofe a opm aif) 5 What do you understand by molal boiling point elevation constant ? Derive the expression that relates molecular weight with the boiling point elevation constant. K—1—T_3054A218. FH diet @, aa G) ferry Fie ser sfewan tele an yee areaa feo ara & (i) Cate® ore siete eeretgse & sta afar ara = Gib sit 3h fete AlCl, i sake e tetten ature @ fear wat ari é Gs) sritneterr: sre 3 afr we st sreragn ema a eh ¥ (v) Whilfesers aciter & wea sfats What happens, when @) Cal ium formate and calcium’acetate are dry distilled (N) Acetic acid reacts with phosphorus pentachloride \ii) Benzene reacts with Acetyl chloride in presence of anhydrous cl, iv) Sodium salt’ of carboxylic acid reacts with sodalime (v) Formaldehyde reacts with ammonia ? saat (Or) () Fare afar (i) TS afar Gi) a ay (iv) frre af afar (v) ainehh afairer Explain the following reactions ; (i) Canniza reaction (i) Perkin’s reaction K—1—T—8054A2 P.T.O.(iii) Claisen’s condensation (iv) Schmidt reaction (v) Haloform reaction. 20. fag aif fe Ree ay we fer aa aa was ® fae qe sat ar ge frat wa aeaR Hed TUT Et 5 Prove that in a process taking place at constant temperature and cons pressure the lowering in free ener; by the system. 's equal to the non-expansion work done 24, sehen sr SFr Sch Saree gt AAT + @) Foes sce Gd) Sate Gii) the Ta Gy) sae Pa 5 What ig Catalysis ? Explain the following with the help of example : (i) Negative catalysts (ii) Auto-catalysts (iii) Induced catalysts Gv) Catalytic poisons staat (Or) grease fre fs st wr faa aaa AST @ fee wT Gi) ae aie Gi) oH eH Sse TA eo Fae K-1-T_8054A2(7 Explaii’ the following ipropertice of colloidal solutions with: the help of a diagram \i) Tyndall effect (ii) Brownian movement (iii) Cataphoresis or Blectrophor re, afieant got safae (@) RON 44H (i) RCONH, + Br, + KOH > iii) RNH, + CHC1, + KOH > (iv) RNO, + fH] — y) RNH, — Complete the following reactions : @ RON +48 Ui) RCONH, + Br, + KOH > (ii) RNH, + CHCL, + KOH > (iy) RNO, +(H) #45 wat (Or) rar fa sustirs, eens an aie a fon fae aifae : 4) ange ora 3 fen Gi) wit TR Te Gi) TRE alae Satay Gy) fre afacia a fen (vy) feat attecte @ fem K-1—T—8054A2 P.T.O.(8 Differentiate hetween primary, secondary and tertiary amine on the following points : (i) Reaction with nitrous acid Gi) Carbylamine test (iii) Mustard oil reaction liv) Reaction with Grignard reagent (v) Reaction with Hinsberg reagent. K-1—T—8054A2(6) Total No. of Questions. (Total No. of Printed Pages T—8054B2 CHEMISTRY (Hindi & English Versions) Time ; 3 Hours Maximum Marks : 75 ast we oe FS ao ware 1 a6 we 2 ae at aan vere wee TR a 30 We &) we wie 7 A 12 a Tee eS Sia am) Sau wee wea oe eT ae 50 wa 21 wei wie 13 8 17 ce We We 4 Sm TS aa Ue wR arm 7s sre 21 THe HY Te Wal wis 18 4 22 Ta We AS Sah mS Wal vet Wee & Sar at ae ar 150 7 yeaa w95 aS sae Se ca Am zh Instructions : ai i 6 Attempt all questions. From Question Nos. 1 to 6 each question carries 2 marks. Answer each question in maximum of 30 words. From Question Nos. 7 to 12 each question carries 3: mar question in maximum of 50 words. From Question Nos. 13 to 17 each question carries 4 marks, Answer each question in maximum of 75 words. From Question Nos. 18 to question in maximum of . Answer each swer each each question carries 5 marls words. Marks have been shown against each question, K—-1-T—8054B2 P.T.0.(2) 1. 0,30] } Fer Se Wd pais wp fafa) 3 Write the value of bond order and magnetic nature of Oxygen molecule 2. CsCl (Hitt a freee Fi Ta) aT ae a ea ? Draw the structure of CsCl (Cisium chloride) crystal. 3. 2.825 7S (smfeay RIAN = 180) FT 30 TA BH facta fay Te Peers a tierra 3 TT TAT 2 2.82 gms of glucose (Atomic weight = 180) is dissolved in 30 gms of water Caleulate the molality of the solution. Sia spre wa) Fe? 2 What is average life period ? fer ca cea feared we oafaiea at What is the relation between heat of reaction at constant pr constant volume ? a wal ga Weer see ERT AAT! 2 Explain solid and liquid propellant with an example. What do you understand by radio carbon dating ? WE 13% cet % seagifs fears fatecs Write the electronic configuration of all the elements of Group 18 °. meat te & fain a wa an 428 ai wanize sitet Shar) 3 Give the reactions that take place in the Blast furnace during the formation of Cast iron. —T—8054B2THERE WEA FT What is Lanthanide contraction ? What are its consequences ? saat (Or) Senge tar tenes a gon eis Compare Lanthanides and Actinides. see Seas cits 4 ons sar weet #7 3 What do you understand by inter halogen compounds ? 12. 7 arm & fee aT oa HO sa ¢, safe HS 4a 2? 3 What is the reason that H,O is liquid at normal temperature whereas H,S waar (Or) aia UH ware 2 ae ee 7 What do you understand by inert pair effect ? sree wa ae feria ger 22 sae er sey 3? 4 What i them ? specific conductivity and cell constant ? What is the relation between 4. Fe sueedeiei dite? & 1UPAC am fatam : G) Na INIEDTA)| (ii) NalAwiCN),] iii) NH,[Cr(NH,),(NCS),] (iv) K[NHEN) | K—1—T—8054B2 P.T.0.(4) Write the IUPAC name of the following coordinate compounds Gi) Na, {NiEDTA)] (ii) NalAu(CN),| (iii) NH,ICnNH,)(NCS),] al raf wT uietea wtf wa Sat (sa) FT ee see #? 4 Define activation energy and threshold energy. How can activation energy (ca be calculated ? te. Fe ogee = aa ai fate, a ae evi fafa; Gi) aTeRTT 66 Gi) 1 4 Write method of preparation, properties and uses of the following polymers (i) Nylon 66 (ii) Bakelite. aaa (Or) aikenftes var adiatin ageat 7 sex ae she Differentiate betweon thermoplastic and thermosetting polymers. V7. oem Wren a art fafa 4 Write the composition and functions of blood Haar (Or) fait A, faeries B, free D oa fae Be a age #2 ae am fa Write name and deficiency disease of Vitamin A, Vitamin B,, Vitamin D and Vitamin ©. K-1—1T_8054B2(5 3 sifae fe fer ad fee ow Sa a ee foe ae a al Hee fara a organ ard ae B 5 T Prove that is a process taking place at constant temperature and constant pressure the lowering in free energy is equal to the non-expansion work done by the system. 2 Site opresi fees rR Hed E 2 gree en sees fess ae fear sere Sel Beret | 5 What are ideal and noa-ideal solutions ? Explain the solutions of positive and negative deviation with examples Gi) Wifes ary 3 Ode liv) Tetames o ules eee y) Ufa eshte S wifes aettaee 5 How will you perform the following conversions ? \i) Acetic acid to Methylamine (ii) Formic acid to Formaldebyde lili) Acetic acid to Acctone tiv) Acetamide to Ethy acetate (v) Ethyl acetate to Acetyl chloride. saat (Or) rufa ac aaa st varenen fate fr fest we BAeneC : () fete qe TaitRE Fa Gi) Tarte Sa Gil) Wr K—1—T—8054B2 P.O:(8) Bxplain laboratory preparation of Diethyl ether on the following points (i) Method and labelled diagram (ii) Chemical equation (iii) Purification i. ga eet aan ca Pei sites Fa owe What is the difference between Lyophilie and Lyophobie colloi¢ staat (Or) crates qa & aid oe orgie Write any five applications of Colloid chemistry. di) aide wa afar (ii) Beas es Bia sTteaT Gii) Hawa dees Hea Gv) ates aerass ata (wi firme afatea Explain the following reactions (i) Carbylamine reaction Gi) Hofmann’s mustard oil reaction iii) Gabriel's phthalimide synthesis (iv) Hofmann’s bromoamide reaction iv) Schmidt's reaction. K-1—T—8054B2amar (Or) Complete the following reactions : G) GH,NO, + [H] 8S, ii) CH,CONH, —S# iii) CH,CN+H —* (iv) C,H,Br+KCN —S2Hs0it + CH,COC] 8 K—1—T—8054B2 120Total No. of Questions (Total No. of Printed Pages—7 T—8054C2 CHEMISTRY (Hindi & English Versions) ‘Time : 3-Hours Maximum Marks : 76 wat get eo Fifa Wer mabe 1 a 6 eR WA 2 She HS eT Ne We OSE aT aT 30 8H # 1H pein 7 Aya Tee 3 se aE cen Wee ee Se eT 50 uz EI) TH gute 13 4017 cH yee ea 4 ee a Bae Wee ee So ee am 75 we Zi wee atin 1s 3 22 a% Wels yes 5 se are nen vee Ger Hate a ve AM 150 WZ 2 yeaa wa & aa sae sia auc a 71 Instructions = Attempt all questions From Question Nos. 1 to 6 each question carrics 2 marks. Answer cach question in masimum of 30 words. From Question Nos. 7 to 12 each question carries 8 marks. Answer cach question in maximum of 50 word K-1-T$054C2 P.T.0.(2) (4) From Question Nos. 13 10 17 each question carries + mark question in maximum of 75 words. (5) From Question Nos. 18 to 22 each question carries 3 marks. Answer each question in maximum of 150 words. 6) Marks have been shown against each question. pid? 7 opid Teie sae ar Safes fora a daa Write the geometrical orientation and bond angle of orbitals. ‘ and sp'd hybridised 2. fra gfe an £7 2 What is Frankel defect 7 TW? NaOH 250 faeteter wet ¥ us get 2 | fae at ae art aif) 2 gm of NaOH is dissolved in 250 ml of water, Find out the normality of the solution: 4, ei aan ena tae 9 or dh aa ' 2 Write any two differences between acidic and basic dy vipien ud qias Pfedielsefaet Foc sar fetes 2 Write two differences between Natural and Artificial radioactivity. fen wa ca fer seat Wh afaien st sone Hoan wera F? 2 o What is the relation between heat of reaction at constant pressure and at constant volume ? 7. GF Ta wert at ang an ete How is the age of minerals and rocks determined ? K-1—T—805402(3) aria ser fafeets 4 fereroi arr cee Explain diagonal rélationship between Boron’ and Silicon. af A fest de feaenpt @1 fafan) see rsa a oe fafa Rive their constitution and uses. Write any three alloys of Copper. ( aatta & 4 Se atest one Hg, ae @ ate aren fora Write formula, name and oxidation state of any three oxyacids of chlorine. aa aio 8 fe adit wr were iets S alee F? What is the reason that boiling point of Ammonia is higher than Phosphine saat (Or) aa aren & fe CCl, Fa aes ae aa, Ta SICL, A sa aTEeA ara A amt 2? What is the rea hydrolised easily ? adage des wa 2? sae oa vie a ? What is Lanthanide contraction ? What are its consequences ? azar (Or) apes an Uaeags at ger Fe! mpare Lanthanide and Actinide. yet a arerrat a wefan CT aT sane faaas Write the factor: ing the electrolytic conductance of electrolytes. afiien at aepiem ser athe a ste 8 ser or site Give the difference between Molecularity and order of a Reaction. a that CCL, does not undergo hydrolysis, whereas SiCl, gets K-1-T_g05402 P.O,(4) 1s, Fre age st aaa at fay, qm ai seein ferftan @ ors é (ii) FAEN. 4 Write the method of preparation, properties and uses of the following polymers (0) Buna-S: (ii) Buna-N. amat (Or) What is the difference between Addition polymerisation and Condensation polymerisation ? 1s. Re suse ait % TUPAC am fefae : (i) Na, INiCEDTA)] (ii) NafAuiCN),] Gil) NH{CrONH,), NCS), (iv) K,INWCN),] + Write the IUPAC names of the following coordination compounds (i) Na, NX EDTA)| (ii) NalAw(CN),| (iii) NH, |CrNH,), NCS), (iy) KINK(CN),). V7. ee ot tere th S a, se aad ee are oe & am a eri fafa 4 Write names of any two peptide hormone glands by which it is secreted and its functions. K-1—T—8084€2(59 (Or) sesh ware see What are Carbohydrates ? Throw light on the biological importance of carbohydrates 18. HER Sa aq 27 WT a ame st aec-ede fate a sem ary aif) = What is Osmotic pressure ? Give Berkley-Hertley process of determination of osmotic pressure and its advantages. 19. fag Sifae fe fear am ue fee ee ea ad va & fee qe eal a aa Free om fra] ayer ard acer = 5 Prove that in a process taking place at constant temperature and constant pre sure the lowering in free energy is equal te thé non-expansion work done by the system. 20, TRieeeee FAR ST Wan fale apis fa aise aTarET) 8 Explain laboratory preparation of Acetaldehyde with the help of a labelled diagram agat (Or) Gi) sa safeties Gin ase Fer Gv) rs orf v) Bhatt mage ature KI T—805402 P.T.O,Explain the following reactions (i) Rosenmund’s reaction (ii) Claisen’s reaction (iii) Benzoin condensation (iv) Perkiin’s reaction (v) Hofmann’s bromamide reaction. 2 anit cen Reeabht seer er sere GeT ARTE 3 What is Catal with the help of an example. is ? Explain Homogenous catalysis and Heterogenous catalysis seat (Or) sitar cen Terafe afasin Yo ae ow sfc) Differentiate between physical adsorption and chemical adsorption. fra ois ors a HE? (@) Wm eis Solas OF Gi ufae Gin S Fiat GF Gi) Wes aes 3 cr TA Gy) aegiads & afer Cea 5 How will you perform the following conversions ? (i) Methylamine to Ethylamine (i) Bthylamine to Methylamine (iii) Propanoie acid to Ethylamine (éy) Nitroethane to Ethylamine. K-1—T—8054C2(7) sant (Or) i varreven fate fein) oa cape eam ar aHifaa far aaTeE ara Bian ase eae as si A ora safe a alta aT aan pe atin (i) Tera Describe the laboratory method fer the preparation of Ethylamine. Give the labelled diagram of the apparatus and chemical equations of the reaction involved. Also give the reactions of ethylamine with : (i) Acetyl chloride (ii) Nitrous acid. K—1—T 80542 27,120