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NH 3 , CO2
and
CH 4 CO2 NH 3
CH 4
2)
NH 3 CO2 CH 4
NH 3 CH 4 CO2
CO2 NH 3 CH 4
3)
4)
2. In an experiment, 200ml of 0.5 M oxalic acid is shaken with 10 g of
activated charcoal and filtered the filtrate is reduced to 0.4M. The amount of
adsorption
1) 0.9
x
m
is
2) 1.8
log
3. Graph between
x
m
3) 0.18
4) 0.09
log P
and
1g / g
1)
450
1.5 g / g
adsorbent
2.5 g / g
2)
adsorbent
0.25 g / g
3)
adsorbent
4)
adsorbent
4. Lyophilic sols are more stable than lyophobic sols because
1) The colloidal particles have positive charge
2) The colloidal particles have no charge
3) The colloidal particles are solvated
4) There are strong electrostatic repulsions between the negatively charged
colloidal particles
Which of the following statements is not correct?
1) Peptization is the process by which certain substances are converted into
the colloidal state
2) Metal sols of gold, silver and platinum can be prepared by Bredigs arc
method
3) Impurities present in a solution makes it more stable
Ba 2 ,1.0
Cl , 2.5
1)
2)
3)
4)
8. At CMC, the surfactant molecules does not undergoes
1) Association
2) Aggregation
3) Micelle formation
4) Coagulation
Cl , 2.0
As2 S3
2) Gelatin
3) Au
4)
Fe OH 3
10.A weak acid HA (0.5 molar) is 20% dissociated in water. If molal elevation
constant of acid in water is 0.325 the B.Pt of solution is
1)
1000 C
2)
100.1250 C
3)
100.1950 C
4)
100.50 C
11.The correct expression relating molality (m), molarity (M), density (d) and
molar mass
MB
of solute is
1)
M
d MM B
2)
M
d MM B
3)
d MM B
M
4)
d MM B
M
12.To a 4L of 0.2M solution NaOH, 2L of 0.5M NaOH are added. The molarity
of resulting solution is
1) 0.9 M
2) 0.3 M
3) 1.8 M
4) 0.18 M
13.A 0.2 molal aqueous solution of a weak acid (HX) is 20 per cent ionized.
The freezing point of this solution is (Given
1)
0.450 C
2)
0.900 C
3)
0.310 C
4)
for water)
0.530 C
14.Benzene and toluene form an ideal solution. 3 mole benzene and 2 mole
toluene are added. V.P. of pure benzene and toluene are 300 & 200 mm of
Hg respectively. The V.P. of the solution is (in mm of Hg)
1) 500
2) 250
3) 260
4) 440
PTotal 120 75 X B
2) 120, 195
3) 120, 45
4) 75, 45
16.The correct relationship between the boiling points of very dilute solutions
of
1)
AlCl3 t1
t1 t2
and
CaCl2 t2
2)
t1 t2
3)
t2 t1
4)
t2 t1
2) 0.6
3) 0.4
4) 0.2
2) 0.88
3) 0.96
4) 0.52
20.The boiling point of an azeotropic mixture of water ethanol is less than that
of both water and ethnol. Then
1) The mixture will show negative deviation form Raoults
2) The mixture will shows positive deviation from Raoults law
3) The mixture will show no deviation from Raoults law
4) This mixture cannot be considered as true solution
21.The amount of urea to be dissolved in 500 mL of water (
solvent) to produce a depression of
1) 5g
2) 3g
0.1860 C
3) 6g
in freezing point is
4) 8g
25.Kb of solvent X is 0.42 and Kf of solvent Y is 1.62, match the following for
possible values :
Column I
Column II
(A)
Kf of solvent X
P)
0.62
(B)
Kb of solvent Y
Q)
1.82
(C)
Boiling point of X
R)
48C
(D)
Boiling point of Y
S)
55C
(B) Chemical adsorption first increases and then decreases with increase in
temperature.
(C) In some cases, solvent may be adsorbed in preference to the solute on
the surface of the adsorbent.
(D) As a result of adsorption, there is increase of surface energy.
28.A solution of palmitic acid (M = 256) in benzene contains 4.24 g acid per
litre. When this solution is dropped on the water surface, benzene evaporates
and palmitic acid forms monomolecular film of the solid type. If we wish to
cover an area of 500 cm2 with a monolayer, the volume of solution should be
used is y 10x cm3. The area occupied by one palmitic acid molecule may
be taken to be
21 10 20 m 2 .
The value of x is
(B) K2SO4
(C) The curve showing the variation of adsorption with pressure at a constant
temperature.
(D) A line parallel to x-axis.
32. The protective power of a lyophilic colloid is measured by the property called
(A) flocculation value
(B)
gold number
(D)
peptization
K Mg2 Ca2
Al3 Mg2 K
(A)
(B)
(C)
(D)
100ml
(B) 0.25
(C) 2.5
(D) 25
36.
Column I
Column II
(A)
Adsorption
(B)
Desorption
(C)
Charcoal
(r)
(D)
For humidity
(s
)
KEY
1.3
2.3
3.3
4.3
5.4
6.1
7.2
14.3 15.3 16.2 17.2 18.1 19.3
25. (Ap,q); (Bp); (Ct,r); (Dr,s)
26.B
31.B 32.B 33.C 34.BC 35.D 36. A p
SOLUTIONS
2. Mass of oxalic acid adsorbed by 10g charcoal
200 10 3 0.5 0.4 90 1.8g
8.4
20.2
9.2
21.2
27.ABC
B r C s
x 1.8
0.18
m 10
W (4.24 V) g
W
Avogadro ' s number
Atomic mass
Number of molecules
4.24V 6.023 10 23
256
500 10 4 m 2 4.24V 6.023 10 23 21 10 20
256
Area =
V 0.0000239 litre
0.0239 cm 3
= 2.39 102 cm3
10.3
22.C
11.2 12.2
23.B,C
28.2
29.ABD
D q, s
13.1
24.AD
30.D