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1/7/2016

Selectionofcorrosioninhibitors

SelectionofCorrosionInhibitors
Rules,equationsortheoriestoguideinhibitordevelopmentoruseareverylimited.Asynergism,orcooperation,is
oftenpresentbetweendifferentinhibitorsandtheenvironmentbeingcontrolled,andmixturesaretheusualchoicein
commercialformulations.Thefirststepinselectinganinhibitorsystemistoconsiderwasisusuallyadopted.
Somecorrosivesystemsandtheinhibitorsusedtoprotectthem(reference)
System
Acids
HCl
..
..
..
Sulfuric
Phosphoric
Others
..
..
..
Water

Inhibitor

Metals

Concentration

Ethylaniline
Mercaptobenzotriazole
Pyridine+phenylhydrazine
Rosinamine+ethyleneoxide
Phenylacridine
Sodiumiodide
Thiourea
Sulfonatedcastoroil
ArsenicOxide
Sodiumarsenate

Fe
..
..
..
..
..
..
..
..
..

0.5%
1%
0.5%+0.5%
0.2%
0.5%
200ppm
1%
0.51.0%
0.5%
0.5%

Potable

Calciumbicarbonate

..

Polyphosphate

..
..

Calciumhydroxide
Sodiumsilicate

Cooling

Calciumbicarbonate

..
..
..
..
Boilers
..
..
..
..
..

Sodiumchromate
Sodiumnitrite
Sodiumphosphatemonobasic
Morpholine
Sodiumphosphatemonobasic
Polyphosphate
Morpholine
Hydrazine
Ammonia
Octadecylamine

Enginecoolants

Sodiumchromate

..
..
Glycol/water
Oilfieldbrines
..
..
Seawater
..
..
..

Sodiumnitrite
Borax
Borax+MBT
Sodiumsilicate
Quaternaries
Imidazoline
Sodiumsilicate
Sodiumnitrite
Calciumbicarbonate
Sodiumphosphatemonobasic+Sodiumnitrite

http://corrosiondoctors.org/Inhibitors/Selection.htm

Steel,cast
iron
Fe,Zn,Cu,
Al
Fe,Zn,Cu
..
Steel,cast
iron
Fe,Zn,Cu
Fe
..
..
Fe,Zn,Cu
..
Fe
..
..
..
Fe,Pb,Cu,
Zn
Fe
..
All
Fe
..
..
Zn
Fe
All
Fe

10ppm
510ppm
10ppm
1020ppm
10ppm
0.1%
0.05%
1%
0.2%
10ppm
10ppm
variable
O2scavenger
neutralizer
variable
0.11%
0.11%
1%
1%+0.1%
0.01%
1025ppm
1025ppm
10ppm
0.5%
pHdependent
10ppm+0.5%
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1/7/2016

http://corrosiondoctors.org/Inhibitors/Selection.htm

Selectionofcorrosioninhibitors

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