Beruflich Dokumente
Kultur Dokumente
FULL TEST I
Paper 1
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Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part is further divided into three sections: Section-A, Section-B & Section-C
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
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Useful Data
PHYSICS
Acceleration due to gravity
g = 10 m/s2
Planck constant
Charge of electron
e = 1.6 1019 C
Mass of electron
me = 9.1 1031 kg
Density of water
Atmospheric pressure
Pa = 105 N/m2
Gas constant
R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant
Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV
=
=
=
=
=
=
=
=
=
=
8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
6.023 1023
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
1.6 1019 J
Atomic No:
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Physics
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PART I
SECTION A
Straight Objective Type
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1.
A particle strikes a horizontal frictionless floor with a speed u at an angle with the vertical and
rebounds with a speed v at an angle with the vertical. The co-efficient of restitution between
the particle and floor is e. The angle is equal to
(A)
2.
3.
(D) 1 e
Disc
Ring
0.2
R
R
F = 10N
0.2
C1
R
R
C2
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4.
The capacitor of an oscillatory circuit of frequency 104Hz is enclosed in a container. When the
container is evacuated, the frequency changes by 50 Hz, the dielectric constant of the gas is
(A) 1.1
(B) 1.01
(C) 1.001
(D) 1.0001
5.
6.
3 0i
4R
B
A
i
30
i
o
30
(D) None
The organ pipes, both closed at one end, have lengths and vibrates in fundamental
mode. Neglect end correction. If the velocity of sound in air is v, then the number of beats/sec is
assume
(A)
7.
v
4
(B)
v
2
(C)
v
42
(D)
v
2 2
Liquid
60
30o
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A photon collides with a stationary H atom in ground state inelastically. Energy of the colliding
photon is 10.2 eV. Almost instantaneously, another photon collides with same H atom
inelastically with an energy of 15 eV. What will be observed by the detector?
(A) two photons of energy 10.2 eV
(B) two photons of energy 1.4 eV
(C) One electron having kinetic energy nearly 11.6 eV
(D) One photon of energy 10.2 eV and an electron of energy 1.4 eV
9.
An electron in H atom is excited from ground state level to first excited level. Select the correct
statements:
(A) Kinetic energy of electron is decreased
(B) Potential energy is increased while kinetic energy of electron is decreased
(C) Time period of rotation and angular momentum both are increased
(D) Total energy is increased while angular speed is decreased
10.
R
3V
L
8V
C
4V
Vs
11.
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Comprehension Type
This section contains 2 paragraphs. Based upon one of the paragraphs 2 multiple choice questions
and based on the other paragraph 3 multiple choice question have to be answered. Each of these
questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Questions 12 & 13
A disc having radius R is rolling without slipping on a horizontal plane
as shown. Centre of the disc has a velocity v and acceleration a as
shown.
P
(x, y)
v
a
0
(0, 0)
12.
13.
(B)
V x2 y R
2
2
(C) V x y R
(D) None
(C) tan1 2
(D) tan1 1
2
15.
16.
(C) 15J / o C
(D) 20J / o C
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SECTION - B
Matrix Match Type
This section contains 2 questions. Each question contains statements given in
two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r, A
s and t. Any given statement in Column I can have correct matching with B
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as C
illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following:
1.
2.
Column II
Zero gravity
k
of a spring
m
(p)
SHM
(q)
A
2
(C)
KE = PE
(r)
(D)
y sin 3t
(s)
1
rd the time period of y sin t
3
writst watch can give correct time
(t)
Per second
Column I
Nuclear fusion
Nuclear fission
(p)
(q)
decay
(C)
(D)
(r)
Exothermic nuclear reaction
(s)
(t)
Column II
Stratifies E = mc2
Generally possible for nuclei with
low atomic number
Generally possible for nuclei with
higher atomic number and
instability
Essentially proceeds by weak
nuclear force
Significant momentum
conservation
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SECTION C
(Integer Answer Type)
This section contains 6 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
1.
20 m/s
5m
2.
A solid cylinder is made of radius R and height 3R having mass density . Now two half spheres
of radius R are removed from both ends. The moment of intertia of remaining portion about axis
29
ZZ can be calculated as
R5 . Find K.
6K
Z
3R
Z'
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3.
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Two particles each of mass m are connected by a string of length 1m. The particles are kept on a
smooth horizontal plane. The initial separation between the particles is 0.5 m. One of the
particles is given a velocity 18 m/s as shown. Find the magnitude of angular velocity of one
particle with respect to the other particle just after the string becomes taut (in m/s).
18 ms-1
m
0.5 m
4.
Two thin symmetrical lenses of different nature have equal radii of curvature of all faces R = 20
cm. The lenses are put close together and immersed in water. The focal length of the system is
5
24 cm. The difference between refractive indices of the lenses is . Find n. The refractive
n
4
index of water is .
3
5.
A 10 m long nichrome wire having 80 resistance has current carrying capacity of 5 A. This wire
can be cut into equal parts and equal parts can be connected in series or parallel. What is the
maximum power which can be obtained as heat by the wire from a 200 V mains supply (in KW).
6.
In the given figure, a potential of +12 volt is given to point A, and point B is earthed. What is the
potential at point P in volt?
4F
3F
B
A
2F
Space for Rough work
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Chemistry
10
PART II
SECTION A
2.
H (excess)
HO
OH
(B)
(C)
(D)
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3.
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1
4 2
Z3 /2 2 Zr e
Zr
2
Given that the radius is in , then which of the following is radius for nodal surface for He+ ion
(A) 1
4.
(B) 2
(C) 2.5
(D) 4
Cyclopentadiene + Na C + H2
2C + FeCl2 D + 2NaCl
Which one of the following in not true about D.
(A) D is an organometalic compound
(B) D is an optically inactive compound
(C) EAN of Fe+2 in D is 34
(D) All C C bonds in D are of identical length
5.
Toluene +
AlCl3
Zn(Hg)
HCl
B
SOCl2
C
H
AlCl3
NaOEt/EtOH, heat
NBS
CCl4, hv
H2SO4
NaBH4
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6.
NaOD, D 2O
NaOH, H2O
D
D
(C)
(D)
NaOD, D 2O
D
D
D
7.
D
D
O
NaOH, H2O
D
D
D
D
(I) Co(CO)6
(II) Co(CO)5NH3
(III) Co(CO)4(NH3)2
(IV) Co(CO)3(NH3)3
(V) Co(CO)2(NH3)4
(VI) Co(CO)(NH3)5
Which statement is correct for these compounds?
(A) order of Co C bond length in complexes is I > II > III > IV > V > VI
(B) order of Co C bond length in complexes is VI > V > IV > III > II > I
(C) order of Co C bond strength in complexes is I = II = III = IV = V = VI
(D) order of C O bond length in complexes is I = II = III = IV = V = VI
Which of the following is/are correct for the reaction with equilibrium constant K?
Kf
C g D g ; Ho 20J
A g B g
Kb
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9.
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Which of the following reaction is incorrect regarding the formation of major product (alkene)?
Me
H3C
Me
H3C
(B)
OH
CH 2 CH 2
(A)
CH3
Me
+
H3C
OH
CH 2 CH 2
N
H3C
Me
CH3
Me
+
(C)
Ph
Me
OH
Ph CH 2 CH 2
CH3
Me
+
(D)
H3C
10.
Me
OH
CH 2 CH 2 Cl
Cl
4.5 g of Al (atomic mass = 27) is deposited at cathode from Al+3 solution by certain quantity of
charge. The correct statement/s is/are:
(A) The volume of H2 produced at 0oC and 1 atm pressure from H+ ions in solution by the same
quantity of charge will be 5.6 .
(B) The volume of H2 produced at 0oC and 1 atm pressure from H+ ions in solution by the same
quantity of charge will be 22.4 .
(C) The number of moles of Al deposited will be 0.166 moles
3
(D) The number of faraday used for reduction of 1 mole of Al+3 is
F.
18
Space for Rough work
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14
Comprehension Type
This section contains 2 paragraphs. Based upon the first paragraph 2 multiple choice questions and
based upon the second paragraph 3 multiple choice questions have to be answered. Each of these
questions has four choices A), B), C) and D) out of WHICH ONLY ONE IS CORRECT.
Paragraph for Question Nos. 12 to 13
On the basis of aromaticity, there are three types of compounds i.e. aromatic, non-aromatic and antiaromatic. The increasing order of stability of these compounds are is under:
Anti-aromatic compound non-aromatic compound aromatic compounds. Compounds to be aromatic
follow the following conditions (according to valence bond theory)
(i) The compounds must be be cyclic in structure having (4n + 2) e, where n = Hckels number = 0, 1,
2, 3 et.c
(ii) The each atoms of the cyclic structure must have unhybridised p-orbital i.e. the atoms of the
compounds have unhybridised p-orbital i.e. usually have sp2 hybrid or planar.
(iii) There must be a ring current of electrons in the ring or cyclic structure i.e. cyclic structure must
undergo resonance .
Compounds to be anti-aromatic, it must have 4ne where n = 1, 2 and it must be planar and undergo
resonance. Non-aromatic compounds the name itself spells that compounds must be non-planar
irrespective of number of electrons. Either it has 4ne or (4n + 2) electrons it does not matter.
The rate of reaction of any aromatic compounds depends upon the following factors:
(i) Electron density
(ii) stability of carbocation produced
Higher the amount of electron density of the ring, higher will be its rate towards aromatic electrophilic
substitution and vice-versa. Similarly, higher will be the stability of the produced carbocation after the
attack of electrophile, higher will be its rate towards aromatic electrophilic substitution. There is a great
effect of kinetic labelling on the rate of aromatic electrophilic substitution. As we known that higher the
atomic weight or, molecualr weight, higher will be the van der Waals force of attraction or, bond energy.
Since there will be effect of kienetic labelling if the 2nd step of the reaction will be the slow step, (r.d.s.)
otherwise there will be no effect of kinetic labelling.
12.
Which of the following is correct order of the rate of reaction of C6H6, C6D6 and C6T6 towards
sulphonation?
(A) Same rate of reactions of C6H6, C6D6 and C6T6
(B) C6T6 C6D6 C6H6
(C) C6H6 C6D6 C6T6
(D) C6H6 C6D6 = C6T6
Space for Rough work
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13.
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Which of the following is the correct order of rate of reaction of C6H6, C6D6 and C6T6 towards
nitrations?
(A) C6H6 C6D6 C6T6
(B) C6H6 = C6D6 = C6T6
(C) C6H6 C6D6 = C6T6
(D) C6T6 C6D6 C6H6
Paragraph for Question Nos. 14 to 16
The Bertholets equation of state for 1 mole real gas is given as under:
a
P TV (V b) RT
Where a and b are van der Waals constants. van der Waals constant a signifies, the force of attraction
among the gas molecules. van der Waals constant b signifies incompressible volume i.e. volume
having no effect of compression and expansion. It is also known as co-volume. Thereby the volume
having effect of compression and expansion i.e. compressible volume = V b (for 1 mole real gas).
One of the form of van der Waals equation of state is virial equation. The virial equation for 1 mole real
gas is as under:
C
A B
PV RT 1 2 3 to higher power of n
V
V V
where A, B, C are known as 2nd, 3rd and 4th virial coefficients respectively. The temperature at which real
gases obey ideal gas equation (PV = RT), is known as Boyles temperature i.e. TB.
14.
2a
, where Ti is the inversion temperature, then which of the following is the correct
Rb
relation of the Boyles temperature TB obtained by the Bertholets equation
If Ti =
(A) Ti = 2TB2
(B) Ti = 2TB
(C) 2Ti = TB
(D) Ti2 = TB
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16
15.
If the value of a and b increases by 8 times and 2 times respecively, then new Boyles
temperature will increases by how many times and what will be effect on the ease of
liquification ?
(A) 2 times, ease of liquification will increase
(B) 4 times, the ease of liquification will increase
1
(C)
times, the ease of liquification will decrease
4
1
(D)
times, the ease of liquification will decrease
2
16.
If the third virial coefficient of 4 moles of mono-atomic as is 0.04 (lit/mol)2 at NTP, then what will
be the real gas at NTP?
(A) 88.8 liters
(B) 80 liters
(C) 89 liters
(D) 90.4 liters
SECTION-B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following:
1.
Column II
(Hydrolysis of compound in Column I)
(A)
SiC
(p)
(B)
Al4 C3
(q)
(C)
CaC2
(r)
No hydrocarbon produced
(D)
Mg2 C3
(s)
(t)
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2.
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Match the solution given in column I with the properties given in column II.
Column I
Column - II
(A)
0.1 M Al2(SO4)3
(p)
(B)
0.1 M AlPO4
(q)
(C)
0.1 M Urea
(r)
(D)
0.1 M MgCl2
(s)
(t)
SECTION C
Integer Answer Type
This section contains 6 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
1.
The number of bicarbonates that do not exist in solid form among the following is....................
LiHCO3 , NaHCO3 , Ca HCO3 2 ,KHCO3 ,NH4HCO 3 ,Ba HCO 3 2 ,Mg HCO3 2 .
2.
In Borax
(i) Number of B O B bond is x
(ii) Number of B B bond is y
(iii) Number of sp2 hybridized B atom is z
Calculate the value of x + y + z
3.
Examine the structural formulas of following compounds and find out number of compounds
which show
O
higher rate of nucleophilic addition than
O
C
CH3
OCH3
H3C
CHO
CHO
CHO
CHO
Cl
NO2
N(CH3) 2
OH
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4.
Examine the structural fromuals shown below and identify how many compounds will show
coupling reaction with diazonium salt faster than anisole
O
CH3
OCH3
OCH3
OCH3
Cl
OCH3
OCH3
5.
6.
H
Pt CN4
,
CN
SH
,
OH
Cl
Cl
C C
OCH3
Cl
OH
HS
CN
CHO
OCH3
H3CO
NO 2
NH2
C
H
Cl
I3 , XeF4
C
H
,
Cl
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Mathematics
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PART III
SECTION A
If P be a point on unit circle with centre at point O. If Q is another point inclined at angle
to
3
is,
OP and OT OQ r, then the interval in which r lies, so that 2 AT PQ , and OA a,
7 13
(A)
,
7 13 7 13
(B)
,
6
6
7 13
(C) ,
2.
If a bag contains five balls. Two balls are drawn and are found to be white. What is the probability
that all the balls are white?
1
1
1
2
(A)
(B)
(C)
(D)
4
3
2
3
3.
4.
(B) f x g x , for no x x 0
If z1 and z2 are two variable complex numbers such that, z1 169 & z 2 3 4i 25 . Then the
maximum value of z1 z2 ,is
(A) 23
(B) 13
(C) 5
(D) 18
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5.
If S
20
4
5
6
7
2n 5
(A) K 1
4
(B) K 1
2
(C) K 3
4
(D) K 5
4
6.
The perpendicular from origin to the tangent at any point on a curve is equal to the obscissa of
the point of contact. If the curve passes through point (1, 2), then it also passes through point,
(A) 1, 2
(B) 1,3
(C) 2,3
(D) 2,1
7.
For an ellipse
x2 y 2
1, with vertices A & A, tangent drawn at the point P in the first quadrant
9
4
meets the y axis in Q and the chord AP meets the y axis in M. If O is the centre of ellipse,
then OQ2 MQ2 is equal to,
(A) 9
(B) 13
(C) 4
(D) 5
9.
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10.
If
tan
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cos 2x
1 sin 2x dx g x c,then
If , are the roots of equation, x 2 2x a2 1 0 and , are the roots of the equation,
x 2 2 a 1 x a a 1 0 such that , , , then the interval in which a lies,
1
(A) a ,1
4
1 1
(B) a ,
8 2
(C) a ,1
(D) a , 2
Comprehension Type
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and
based on the other paragraph 3 multiple choice questions have to be answered. Each of these questions
has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct
Paragraph for Question Nos. 12 to 13
Consider the curves,
1 1
C1 y 2 4K1x , K1 ,
8 4
1
C2 x 2 4K 2 y 2 , K 2 1,
4
C3 x 0
12.
13.
(D) 1
(D) 1
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15.
16.
9R 2
4
R2
sin A cos B C
8
R2
(D)
sin2B sin 2C
2
(B)
(C) R sin2A
(D) 2Rcos A
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AITS-FT-I-(Paper-1)-PCM-JEE(Advanced)/16
SECTION-B
(Matrix-Match Type)
This section contains 2 questions. Each question contains statements given
in two columns, which have to be matched. The statements in Column I are
labelled A, B, C and D, while the statements in Column II are labelled p, q, r,
s and t. Any given statement in Column I can have correct matching with
ONE OR MORE statement(s) in Column II. The appropriate bubbles
corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s
and t; then the correct darkening of bubbles will look like the following:
1.
Column II
2
(A)
x2 y 2
(p)
(B)
and
area of circle Circumscribing PQR is K then K is equal to,
12x 5y
(q)
(r)
(s)
(t)
(C)
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AITS-FT-I-(Paper-1)-PCM-JEE(Advanced)/16
2.
24
(A)
Column I
x
The solution of 1 + secx = cot2
2
Is given by x K , then K is/are
Column II
(p)
(q)
(r)
(s)
(t)
A 2 2 A C 22 3 is/are equal to
m
(C)
5
3
m is positive integer lies between 200 and 400 & the term
(D)
SECTION C
(Integer Answer Type)
This section contains 6 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
1.
A line makes an angle of ,, , with the four diagonals of a cube then the value of
cos 2 cos 2 cos2 cos2 is, where . denotes the GIF ...............
2.
Tangents drawn from any point P on the curve xy 2x y 2 0 intersect the asymptotes at A
& B. Then the area of triangle QAB, is 4K (where Q is centre of the curve). Then value of
K is
Space for Rough work
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25
3.
AITS-FT-I-(Paper-1)-PCM-JEE(Advanced)/16
Consider a triangle ABC whose sides length are AB = 4, BC = 2 & CA = 3. If the bisector of the
angle C cuts AB in D and the circumcircle in E, then the value of CE is(where, [.]
DE
denotes the GIF)
10
4.
If
10
5.
If the number of ways in which four distinct balls can be put into two identical boxes so that no
box remains empty is equal to K, then K =.
6.
K 1 x K 3 y K 3
K 1 x K 2 y K 3
xy 1
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