7/7/2015

QuestionRevision

Question1.
100mLofasampleofhardwaterrequires25.1mLof
Thehardnessofwater(density1g/mL)basedon
[A]
[B]
[C]
[D]

forcompletereaction.
is:

200ppm
251ppm
261ppm
288ppm

Question2.
Anelectroniscontinuouslyacceleratedinvacuumtubebyapplyingpotentialdifference.IfthedeBroglie'swavelengthisdecreasedby
10%,thenchangeinthekineticenergyofelectronisnearly:
[A]
[B]
[C]
[D]

Decreasedby11%
Increasedby23.4%
Increasedby10%
Increasedby11.1%

Question3.
Inanequilibriumreaction,xmolesofthereactantAdecomposetogive1moleeachofCandD.IfthefractionofAdecomposedat
equilibriumisindependentofinitialconcentration,thenthevalueofxwouldbe:
[A]
[B]
[C]
[D]

1
2
3
4

Question4.
Onelitreofasaturatedsolutionof
Thesolubilityproductof

(Molecularweight100)isevaporatedtodrynessduetowhich7.0mgofresidueisleft.
is:

[A]
[B]
[C]
[D]

Question5.
Whichifthefollowingisnottrueaboutexpansionofanidealgas?
[A]
[B]
[C]
[D]

Totalentropychangeinirreversibleisothermalexpansionisgreaterthaninreversibleisothermalexpansion
Thetotalentropychangeinreversibleadiabaticexpansioniszeroandsameasinreversibleisothermalexpansion
Inirreversibleadiabaticexpansion,theincreaseinentropyduetovolumechangeislessthanthedecreaseinentropydueto
temperaturechange
Themagnitudeofworkinvolvedinareversibleisothermalexpansionisgreaterthanthatinanirreversibleisothermalexpansion
againstaconstantpressure

Question6.
Enoughsolid

and

areheatedinaclosedvesselat100oCandthefollowingequilibriaareestablished:

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

1/22

7/7/2015

If

QuestionRevision

forthefirstequilibriumat100oCis

andthetotalpressureofthesystemis12atm,thenthe

forsecond

equilibriumwouldbe:
[A]
[B]
[C]
[D]

Question7.
Theentropychangeproducedinuniversewhen3.5kgwaterat77oCloose42Jheattothesurroundingsat27oCis:
[A]
[B]
[C]
[D]

Question8.
Howmanymlof1MKOHand

solutionsbemixedforatotalvolumeof100mltoproducethehighestrisein

temperature?ExpressyouranswerastheratioofvolumeofKOH:volumeof
[A]
[B]
[C]
[D]

67:33
33:67
40:60
50:50

Question9.
Thestatementwhichrepresentsthecorrectorderofsolubilityofthecompoundsinwateris:
[A]
[B]
[C]
[D]

Question10.
Considerthefollowingstatements:
I.

isastrongerLewisacidthan

II.Thepartialdoublebondcharacterof
III.StrongerLewisacidcharacterof

bondin

islostintheadduct

isduetothepresenceofhighlyelectronegativefluorineatoms

Whichofthestatementsgivenaboveis/arecorrect?
[A]
[B]
[C]
[D]

IIandIII
IIIonly
IandII
Ionly

Question11.
http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

2/22

7/7/2015

QuestionRevision

Bondlengthistheaveragedistancebetweenthenucleioftheatomsheldbyabond.Thisrepresentstheinternucleardistance
correspondingtominimumpotentialenergyforthesystem.Thefactors,whichaffectthebondlengthare:
I.Multiplebondsareshorterthancorrespondingsinglebonds
II.Sometimessinglebonddistancesaresomewhatshorterthanthesumoftheirrespectivecovalentradiibecausebondsacquire
somepartialdoublebondcharacter.Thisgenerallyhappenswhenoneatomhasavacantorbitalandshorterduetohighioniccharacter
inthecovalentbond.

Whichofthefollowingisnottrueaboutthe
I.

II.

bondlengthamongthefollowingspecies?

III.

[A]

bondlengthisshortestin(II)

[B]

bondlengthin(I)isshorterthanthatin(III)

[C]

bondlengthin(III)isshorterthanthatin(I)

[D]

bondlengthin(IV)isintermediatebetween

IV.

bondlengthin(I)and(II)

Question12.
Bondlengthistheaveragedistancebetweenthenucleioftheatomsheldbyabond.Thisrepresentstheinternucleardistance
correspondingtominimumpotentialenergyforthesystem.Thefactors,whichaffectthebondlengthare:
I.Multiplebondsareshorterthancorrespondingsinglebonds
II.Sometimessinglebonddistancesaresomewhatshorterthanthesumoftheirrespectivecovalentradiibecausebondsacquire
somepartialdoublebondcharacter.Thisgenerallyhappenswhenoneatomhasavacantorbitalandshorterduetohighioniccharacter
inthecovalentbond.

Inwhichofthefollowingmolecule,centralatomFbondhaspartialdoublebondcharacter?
[A]
[B]
[C]
[D]

Question13.
Whenasparinglysolublesaltisaddedtowater,adynamicequilibriumisestablishedwhentherateofdissolutionofthesaltequalsthe
rateofprecipitationofsaltfromthesaturatedsolution.Sincethesolubilityofasaltvarieswithtemperature,thenumericalvalueof
forasaltchangeswithtemperature.Thenumericalvalueof

canbedeterminedfromitsmolarsolubilityandviceversa.Factors

suchascommonion,complexformation,hydrolysisetc.affectthesolubilityofmostofthesalts.

Pure

isaddedto

shakenwell.Whatistheratioofthe

solutionand0.025MKClsolutiontakenseparatelyandbothsuspensionsare
inthefirstsolutiontothe

inthesecondsolution?(Given:

ofAgClis

).
[A]
[B]
[C]
[D]

2.5
2.0
3.0
1.5

Question14.
Whenasparinglysolublesaltisaddedtowater,adynamicequilibriumisestablishedwhentherateofdissolutionofthesaltequalsthe
rateofprecipitationofsaltfromthesaturatedsolution.Sincethesolubilityofasaltvarieswithtemperature,thenumericalvalueof
http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

3/22

7/7/2015

QuestionRevision

forasaltchangeswithtemperature.Thenumericalvalueof

canbedeterminedfromitsmolarsolubilityandviceversa.Factors

suchascommonion,complexformation,hydrolysisetc.affectthesolubilityofmostofthesalts.

Asolutioncontains
additionof

ion,towhichsolid

doesnotchangethevolume,thecorrectstatementregardingthegivensolutionis(Given:

AgBrandAgIare
[A]
[B]
[C]
[D]

isgraduallyadded.Assumingthe
of

respectively)

AgIwillbeprecipitatedfirst,followedbyAgBrandthenAgCl
AgClwillbeprecipitatedfirst,followedbyAgBrandthenAgI
AgIandAgClwillsimultaneouslygetprecipitatefollowedbyAgBr
AgClandAgBrwillsimultaneouslygetprecipitatefollowedbyAgI

Question15.
Asampleconsistingof1molofamonoatomicperfectgas

istakenthroughthecycleasshown.

Temperatureatpoints(1),(2)and(3)arerespectively:
[A]
[B]
[C]
[D]

Question16.
Asampleconsistingof1molofamonoatomicperfectgas

fortheprocess

istakenthroughthecycleasshown.

is:

[A]
[B]
http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

4/22

7/7/2015

QuestionRevision

[C]
[D]

Zero

Question17.
MATCHTHEFOLLOWINGLISTS:

[A]
[B]
[C]
[D]

Question18.

[A]
[B]
[C]
[D]

Question19.
MATCHTHEFOLLOWINGLISTS:

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

5/22

7/7/2015

QuestionRevision

[A]
[B]
[C]
[D]

Question20.
MATCHTHEFOLLOWINGLISTS:

[A]
[B]
[C]
[D]

Question21.
Aparticle(P)isprojectedatanangleof
angleofinclination

fromhorizontalwithavelocity

fromthebottomofaninclinedplane,have

.Atthesameinstant,anotherparticleQisreleasedfromaheighthonsmoothinclineplane.Ifaftersometime

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

6/22

7/7/2015

QuestionRevision

bothparticlescollide,thenthevalueofhis:

[A]
[B]
[C]
[D]

3m
4.5m
5.5m
3.5m

Question22.
Asemicircularwireofmassmishingedatitstoponaverticalwall.Whatisthehorizontalforceexertedbywallonthelowerend?

[A]
[B]
[C]
[D]

Question23.
AnannularringwithinnerandouterradiiR1andR2isrollingwithoutslippingwithauniformangularspeed.Theratiooftheforces
experiencedbythetwoparticlesofsamemasssituatedontheinnerandouterpartsofthering,

is:

[A]

[B]
[C]

[D]

Question24.
Inthefigureshown,thepistonsinterconnectedbyaninextensiblethreadcanslidewithoutfriction.Theendsofthecylinderareopento
theatmosphere.Thegasenclosedwithinthepistonsisbeingheatedataconstantratesothatthepistonsaremovingwithaconstant
speed.Then,whichofthefollowingisnottrue:

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

7/22

7/7/2015

[A]
[B]
[C]
[D]

QuestionRevision

Thepistonsshifttotheleft
Workdonebygas>0
Threadtensionis>0
Threadtensioniszero

Question25.
FindthedistanceofCMoftheuniformrodoflength

ifitisbentintocirculararcofradiusRfromthecentreCasshown.

[A]
[B]
[C]
[D]

Question26.
IfblockAismovingwithanaccelerationof5m/s 2,theaccelerationofBw.r.t.groundis:

[A]

5m/s 2

[B]
[C]
[D]

10m/s 2

Question27.
A5.0kgblockwithaspeedof8.0m/stravels2.0malongahorizontalsurfacewhereitmakesaheadon,perfectlyelasticcollisionwitha
15.0kgblockwhichisatrest.Thecoefficientofkineticfrictionbetweenbothblockandthesurfaceis0.35.Howfardoesthe15.0kg
blocktravelbeforecomingtorest?
[A]

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

8/22

7/7/2015

QuestionRevision

[B]

[C]
[D]

Question28.
Thefigurebelowshowsasmallmassconnectedtoastring,whichisattachedtoaverticalpost.Ifthemassisreleasedwhenthestring
ishorizontalasshown,themagnitudeofthetotalaccelerationofthemassasafunctionoftheangle
is:

[A]
[B]
[C]
[D]

Question29.
Asystemreceiveheatfromaheatercontinuouslyattherateof10W.thetemperatureofthesystembecomesconstantat
whenthetemperatureofthesurroundingis

.Aftertheheaterisswitchedoff,thesystemcools

in1

minute.Theheatcapacityofthesystemisnearly:
[A]
[B]
[C]
[D]

Question30.
Acylindricalvesselcontainsaliquidofdensity
uptoheighth.Theliquidisclosedbyapistonofmassmandareaofcrosssection
A.Thereisasmallholeatthebottomofthevessel.Thespeedvwithwhichtheliquidcomesoutoftheholeis:

[A]

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%20

9/22

7/7/2015

QuestionRevision

[B]

[C]

[D]

Question31.
Atankofsize

fullofnonviscousfluidofdensity

.Asmallmetalcubicalblockofvolumeb3andofdensity

isattachedthroughuppersurfaceoftankandfromrightsidewallofthetankbymeansofstringOP&RQasshownin
figure.Nowtankhasgivenanaccelerationinrightwarddirectionofmagnitude1m/s 2(Takeg=10m/s 2)

Ifaccelerationisgivenatt=0.TheworkdonebytensioninstringRQontheblockbetweentimeintervalt=0to2s.
[A]

Zero

[B]
[C]
[D]

Question32.
Atankofsize

fullofnonviscousfluidofdensity

.Asmallmetalcubicalblockofvolumeb3andofdensity

isattachedthroughuppersurfaceoftankandfromrightsidewallofthetankbymeansofstringOP&RQasshownin
figure.Nowtankhasgivenanaccelerationinrightwarddirectionofmagnitude1m/s 2(Takeg=10m/s 2)

Aspressureisdifferentatdifferentpoints.LetPmax ismaximumpressureandPminisminimumpressureinthetank.Then
isequalto:
[A]
[B]
[C]
[D]
http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

10/22

7/7/2015

QuestionRevision

Question33.
ConsideracylinderofmassM=1kgandradiusR=1mlyingonaroughhorizontalplane.Ithasaplankofmassm=1kglyingonitstop
asshowninthefigure.AforceF=22NonPlankcausesthecylindertoroll.Theplankalwaysremainshorizontal.Thereisnoslippingat
anypointofcontact.

Calculatetheaccelerationofcylinder
[A]
[B]
[C]
[D]

20m/s 2
4m/s 2
5m/s 2
Noneofthese

Question34.
ConsideracylinderofmassM=1kgandradiusR=1mlyingonaroughhorizontalplane.Ithasaplankofmassm=1kglyingonitstop
asshowninthefigure.AforceF=22NonPlankcausesthecylindertoroll.Theplankalwaysremainshorizontal.Thereisnoslippingat
anypointofcontact.

FindthevalueoffrictionalforceatA
[A]
[B]
[C]
[D]

7.5N
5.0N
3N
Noneofthese

Question35.
TherodofmassmisconstrainedtomovealongtherigidguidesandalwaysincontactwiththewedgeofmassMasshowninfigure.
Assumethatthereisnofrictionanywhere.

Findtheaccelerationofthewedge
[A]

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

11/22

7/7/2015

QuestionRevision

[B]

[C]
[D]

Noneofthese

Question36.
TherodofmassmisconstrainedtomovealongtherigidguidesandalwaysincontactwiththewedgeofmassMasshowninfigure.
Assumethatthereisnofrictionanywhere.

Findthenormalreactionbetweentherodandthewedge:
[A]

[B]

[C]
[D]

Noneofthese

Question37.

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

12/22

7/7/2015

[A]
[B]
[C]
[D]

QuestionRevision

PQRS
3213
3244
4213
4233

Question38.
Abodyinitially,movingtowardsrightexplodesintotwopieces1and2.DirectionofmotionofthepiecesisshowninList1andpossible
massratioareshowninList2.

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

13/22

7/7/2015

[A]
[B]
[C]
[D]

QuestionRevision

PQRS
3321
4411
4413
3322

Question39.
OnemoleofamonoatomicidealgasiskeptinacontainerofvolumeV0atpressureP0andtemperatureT0.Theconductingwallhas
surfaceareaA,thicknessdandthermalconductivityK.AssumethatsurroundingBataconstanttemperature3T0.Tistemperatureof
gasatanyinstant.[Given

].

MATCHTHEFOLLOWINGLISTS:

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

14/22

7/7/2015

[A]
[B]
[C]
[D]

QuestionRevision

PQRS
1,21,243
1,21,234
12,334
214,23

Question40.

Codes:
[A]
[B]
[C]
[D]

PQRS
3342,4
4322
322,41
331,42

Question41.
Thevertexofrightangleofarightangledtriangleliesonthestraightline
and

andthetwoothervertices,atpoints

thentheareaoftriangleinsq.unitsis:

[A]
[B]
[C]
[D]

3
33/5
11

Question42.

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

15/22

7/7/2015

QuestionRevision

,thenxmustlieintheinterval:

[A]

[B]

[C]
[D]

Noneofthese

Question43.
ConsiderthewordW="COMMISSIONER".Thenumberof5letteredwordscontainingtwovowelsandthreeconsonants.
[A]
[B]
[C]
[D]

6720
6520
6820
Noneofthese

Question44.
Themostgeneralsolutionfortheequation

isx=

[A]
[B]
[C]
[D]

Noneofthese

Question45.
If

and10H.M.'s

numbers2and3.Then

[A]

areinsertedbetweenthe

,isequalto:

25

[B]
[C]
[D]

625
525

Question46.
Ifthereexistspreciselyone'x'between1and2,whichsatisfiestheequation

,then

shouldliein

theinterval:
[A]

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

16/22

7/7/2015

QuestionRevision

[B]

[C]

[D]

Question47.
Letf(x)=x 2+2ax+b,g(x)=cx 2+2dx+1bequadraticexpressionswhosegraphisasshowninthefigure.Hereitisgiventhat
.

Whichofthefollowingstatementsiscorrect?
[A]
[B]
[C]
[D]

a2+d=d2+c
a+d=b+c
a2+d2=c+b
bc+c=a2c+d2

Question48.
Thesumoftheseries

is:

[A]

[B]

[C]

[D]

Question49.
If

and

then:

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

17/22

7/7/2015

QuestionRevision

[A]
[B]
[C]
[D]

Question50.
Consider

Sumofinfinitetermsofaboveserieswillbe:
[A]
[B]
[C]
[D]

0
1/2
2
Noneofthese

Question51.
Consider

ThevalueofS16mustbe:
[A]
[B]
[C]
[D]

Noneofthese

Question52.
Let

haverealroots

Theareaofthequadrilateralformedbypoints

haverealroots

takeninorderis:

[A]
[B]
[C]
[D]

Question53.

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

18/22

7/7/2015

QuestionRevision

Let

haverealroots

haverealroots

Thecentreofthecirclepassingthroughthepointsofintersectionofpairsoflines

and

is:

[A]

[B]

[C]

[D]

Question54.
Let

haverealroots

Equationofthedirectorcircleofthecircle

haverealroots

is:

[A]
[B]

f(x)+g(y)=q2+s 2

[C]

[D]

Question55.
Let

arethreedistinctrootsof

and

and

isequalto:
[A]
[B]
[C]
[D]

0
1
5

Question56.
Let

arethreedistinctrootsof

isequalto:

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

19/22

7/7/2015

[A]
[B]
[C]
[D]

QuestionRevision

390
400
420
421

Question57.

[A]
[B]
[C]
[D]

PQRS
2431
2143
2134
1243

Question58.

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

20/22

7/7/2015

[A]
[B]
[C]
[D]

QuestionRevision

PQRS
4132
1433
4123
4213

Question59.
ConsidertwocirclesC1ofradius'a'andC2ofradius'b'(b>a)bothlyinginfirstquadrantandtouchingthecoordinateaxesthen

is

givenas:

[A]
[B]
[C]
[D]

PQRS
3412
4213
4312
4321

Question60.
MATCHTHEFOLLOWINGLISTS:
http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

21/22

7/7/2015

If

[A]
[B]
[C]
[D]

QuestionRevision

aretherootsoftheequation

then:

PQRS
3243
2432
4213
1342

http://www.vidyamandir.com/questionRevision.do?actionName=displayQuestionList&testIds=ff8080814b3aa9c2014b43cd5e121ffb&tName=2016%20JEE%2

22/22